شیمی کئوردیناسیون، ویژگی‌های طیفی و ساختاری کمپلکس های جیوه (2+) با یک ایلید نوین فسفر و تأیید محل اتصال ایلید به فلز با روش های محاسباتی

نوع مقاله: علمی-پژوهشی

نویسندگان

1 گروه شیمی، دانشکده علوم، دانشگاه ارومیه، صندوق پستی 57153-165 ارومیه، ایران

2 گروه شیمی، واحد زنجان، دانشگاه آزاد اسلامی، صندوق پستی 49195-467 زنجان، ایران

3 گروه فیزیک، واحد ارومیه، دانشگاه آزاد اسلامی، ارومیه، ایران

چکیده

از واکنش 2- برمو- 1- (3- نیترو فنیل) اتان-1- ان با تری پاراتولیل فسفان در حلال استن، ایلید 1- (3-نیترو فنیل) -2- (تری پارا تولیل-λ5 فسفان ایلیدن) اتان 1- اون (NTPPY) (1)  با راندمان 79% به دست آمد. سپس از واکنش  ایلید نامبرده با هالیدهای جیوه ی (2+) به نسبت 1:1 در حضور حلال متانول خشک، کمپلکس های دو هسته ای (X = Cl, Br, I) 2[HgX2(ptolyl)3PCHCOC6H4NO2] تهیه شدند. ترکیب­های تهیه شده به کمک روش های طیف سنجی IR, 1H, 13C, 31P NMR  شناسایی شدند، همچنین ایلید (1) با مطالعات کریستالوگرافی و روش ­های محاسباتی در سطح نظری /6-31G*))DFT مورد بررسی بیش­تر قرار گرفت.

کلیدواژه‌ها

موضوعات


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