توسعه حسگر پتانسیومتری کروم (III) با استفاده از یونوفور2-بنزامیدوپروپانوئیک اسید

نوع مقاله : علمی-پژوهشی

نویسندگان

گروه شیمی، دانشکده علوم پایه، واحدیادگار امام خمینی(ره) شهرری، دانشگاه آزاد اسلامی، تهران ، ایران

چکیده

در این مطالعه، یک الکترود یون گزین غشای مایع حساس و گزینش پذیر بر پایه یونوفور 2-بنزامیدوپروپانوئیک اسید برای اندازه گیری یون کروم (III) تهیه شد. بهترین عملکرد از غشای دارای 29% پلی وینیل کلرید، 2% سدیم تترا فنیل بورات، 56% دی بوتیل فتالات و 13% یونوفور به دست آمد. این الکترود پاسخ نرنستی با شیب mV/Decade)3/22) در گستره غلظتی1-10×3/0 تاM  5-10× 1 برای یون ­های کروم (III) از خود نشان داد. حد تشخیص این الکترود  mol/L6-10× 8 بود. حسگر  زمان پاسخ دهی به نسبت تند (کم ­تر از 10 ثانیه) و گستره pH کاری مفید 5/3 تا0/8 دارد. مزاحمت برخی کاتیون ها ارزیابی شد. عملکرد حسگر پیشنهادی به عنوان الکترود شاخص در تیتراسیون پتانسیومتری کروم (III) با EDTA و همچنین اندازه گیری کروم (III) در چای و پودر کاکائو به عنوان نمونه حقیقی مورد بررسی قرار گرفت. سرانجام تأثیر مایع یونی 1- متیل-3- پنتیل ایمیدازولیوم برمید به عنوان افزودنی یونی بررسی شد

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