معرفی (متیلن‌بیس (4،1-فنیلن)) بیس سولفامیک اسید به عنوان کاتالیست نوین اسیدی بدون هالوژن و استفاده از آن در سنتز ترکیب های هتروسیکل بر پایه زانتن

نوع مقاله : علمی-پژوهشی

نویسندگان

گروه شیمی، دانشگاه گیلان، رشت، ایران

چکیده

در این پژوهش کاتالیست نوینی از خانواده سولفامیک اسیدها که قابلیت استفاده در فاز جامد را دارا می ­باشد از واکنش بین کلروسولفونیک اسید و متیلن­دی­آنیلین به روشی ساده سنتز شد و پس از شناسایی و تأیید ساختار برای ارزیابی قابلیت کاتالیستی در واکنشی که به منظور سنتز ترکیب ­های هتروسیکل نوین فعال زیستی از خانواده زانتن ­ها (بیس زانتن ­ها) طراحی شده بود، مورد استفاده قرار گرفت. کاتالیست یادشده از نظر قابلیت استفاده در فاز جامد، سنتز آسان و همچنین نداشتن یون هالید به عنوان آلاینده محیط زیست نسبت به بسیاری از کاتالیست­ های اسیدی فاز جامد برتری دارد. نتیجه­ های به دست آمده از ارزیابی قدرت کاتالیستی کاتالیست یادشده نیز مؤید توانایی بالای آن برای استفاده در واکنش­ هایی است که نیازمند کاتالیست اسیدی می­ باشند. در همان حال ترکیب­ هایی که از سنتز آن ها برای ارزیابی قابلیت کاتالیستی کاتالیست یادشده استفاده شده، نوین هستند که برای اولین بار با بازده ­های خوب سنتز شده اند. ساختار فراورده­ ها نیز به وسیله طیف سنجی FT-IR، 1H NMR و 13C NMR تأیید شد.

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مراجع

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