جهاد دانشگاهی-پژوهشکده توسعه صنایع شیمیایی ایران نشریه شیمی و مهندسی شیمی ایران 1022-7768 44 4 2026 02 01 Copper and Cobalt-Based Bimetallic-Porous Coordination Polymers as an Efficient Electrocatalyst for Urea Oxidation پلیمرهای کوئوردیناسیونی متخلخل دو فلزی برپایه مس و کبالت به عنوان یک الکتروکاتالیست کارآمد برای اکسایش اوره 49 62 732880 FA رضا اباذری گروه شیمی، دانشکده علوم پایه، دانشگاه مراغه، مراغه، ایران جعفر شریعتی گروه مهندسی شیمی، واحد داراب، دانشگاه آزاد اسلامی، داراب، ایران Journal Article 2025 08 04 <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; background: white; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">In the current study, Cu-PCP, Co-PCP, and bimetallic CuCo-PCPs were synthesized through a single-step hydrothermal method utilizing <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: SimSun; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">4,4-oxybis(benzoic acid) and N,N-bis-(4-pyridylformamide)-1,4-benzenediamine<span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; background: white; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;"> linkers.<span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;"> Excellent electrocatalytic activity toward the urea oxidation reaction was reported for the synthesized bimetallic CuCo-PCPs, achieving a high current density of 10 mA/cm2 at a potential of 1.495 V, a Tafel slope of 128 mV /dec, and a significant turnover frequency (TOF) of 0.068 s−1. Urea electrolysis achieved a current density of 10 mA/cm<span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; background: white; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">² at a low cell voltage of 1.53 V, approximately 200 mV lower than that required for conventional water electrolysis, while maintaining stability over 48 hours at 50 mA/cm<span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; background: white; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">² with no noticeable performance decline. The 3D structures of bimetallic CuCo-PCPs can illustrate their exceptional catalytic performance, which is attributed to abundant accessible molecular active sites and efficient mass transport arising from their unique architecture. The synergistic interaction between Cu and Co within the PCP configuration facilitates faster electron transport, giving <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Mitra'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">the newly developed bimetallic CuCo-PCPs more potential for water electrolysis and advanced energy storage applications. <span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">در مطالعه حاضر، سنتز <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">Cu-PCP<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">، <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">Co-PCP<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> و پلیمرهای کوئوردیناسیونی متخلخل دو فلزی-آلی<span dir="RTL" lang="FA" style="font-size: 11.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">CuCo-PCP<span dir="RTL" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> از طریق یک روش هیدروترمال تک مرحله‌ای با استفاده از اتصال‌دهنده‌های ۴،۴-اکسی‌بیس (بنزوئیک اسید) و <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">N<span dir="RTL" lang="FA" style="font-size: 11.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">،<span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">N<span style="font-size: 12.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">-<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> بیس-(۴-پیریدیل‌فرمامید)-۱و۴-بنزن‌دی‌آمین انجام شد. فعالیت الکتروکاتالیستی عالی نسبت به اکسیداسیون اوره برای پلیمرهای کوئوردیناسیونی متخلخل دو فلزی-آلی<span dir="RTL" lang="FA" style="font-size: 11.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.3pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.3pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">CuCo-PCP<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.3pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> سنتز شده<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> گزارش شد که دست یابی به چگالی جریان بالای <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">mA /cm2<span dir="RTL" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> <span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 10 در پتانسیل <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">V<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 495/1، شیب تافل <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">mV/dec<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.4pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 128<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> و فرکانس گردش قابل توجه <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">s-1<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 068/0را نشان می دهد. الکترولیز اوره در ولتاژ سلول کم <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">V<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 53/1 به چگالی جریان <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">mA /cm2 <span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 10 دست یافت، که نشان دهنده مقادیری تقریباً<span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">mV<span dir="RTL" style="font-size: 11.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> <span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">200 کمتر از مقادیر مورد نیاز برای الکترولیز آب معمولی است. این موضوع در حالی است که پایداری را بیش از ۴۸ ساعت در <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">mA/cm2<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> 50 بدون کاهش قابل توجه عملکرد، حفظ می کند. ساختارهای سه بعدی پلیمرهای کوئوردیناسیونی متخلخل دو فلزی-آلی<span dir="RTL" lang="FA" style="font-size: 11.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">CuCo-PCP<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">، منجر به عملکرد کاتالیستی فوق العاده خوب آنها می شود که این موضوع به دلیل در دسترس بودن مکان های فعال مولکولی زیاد و همچنین انتقال جرم موثر (به دلیل معماری منحصر به فرد آنها)، می باشد. برهمکنش هم‌افزایی بین مس و کبالت در پیکربندی <span dir="RTL" lang="AR-SA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; letter-spacing: -.1pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: AR-SA;">پلیمرهای کوئوردیناسیونی متخلخل<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; letter-spacing: -.1pt; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">، انتقال سریع‌تر الکترون را تسهیل کرده<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> و به پلیمرهای کوئوردیناسیونی متخلخل دو فلزی-آلی<span dir="RTL" lang="FA" style="font-size: 11.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> <span style="font-size: 11.0pt; line-height: 107%; font-family: 'Times New Roman',serif; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-theme-font: major-bidi; mso-bidi-font-family: 'B Zar'; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;">CuCo-PCP<span dir="RTL" lang="FA" style="font-size: 12.0pt; line-height: 107%; font-family: 'B Zar'; mso-ascii-font-family: 'Times New Roman'; mso-ascii-theme-font: major-bidi; mso-fareast-font-family: Calibri; mso-fareast-theme-font: minor-latin; mso-hansi-font-family: 'Times New Roman'; mso-hansi-theme-font: major-bidi; color: black; mso-themecolor: text1; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language: FA;"> تازه توسعه‌یافته، پتانسیل بیشتری برای کسایش اوره و کاربردهای پیشرفته ذخیره‌سازی انرژی می‌دهد.

https://www.nsmsi.ir/article_732880_df952d72dfbc2ae348f2711bfd3de2b7.pdf