نشریه شیمی و مهندسی شیمی ایران

نشریه شیمی و مهندسی شیمی ایران

استفاده از مخلوط حلال اتکتیک N, N-دی‌متیل‌اِتیلن‌دی‌آمین و تترابوتیل‌آمونیم برومید با عملکرد سه گانه در واکنش جفت شدن کربن-کربن اولمن در حضور کمپلکس ترپیریدین مس (I) به عنوان کاتالیست

نوع مقاله : علمی-پژوهشی

نویسندگان
اکبر مبارکی 1
ژیلا حسین زاده 2
علی روستایی 3
1 گروه شیمی آلی و پلیمر، دانشکده شیمی، دانشگاه خوارزمی، تهران، ایران
2 گروه شیمی، دانشگاه صنعتی خواجه نصیرالدین طوسی، تهران، ایران
3 گروه تجهیزات و فناوری پلیس، پژوهشکده تجهیزات و فناوری‌های انتظامی، پژوهشگاه علوم انتظامی و مطالعات اجتماعی، فراجا، تهران، ایران
چکیده
در این پژوهش روشی کارآمد جهت انجام واکنش اولمن و تشکیل پیوند کربن-کربن برای سنتز ترکیبات بی آریل مختلف با بازده خوب تا عالی ارائه شده است. به این منظور، از ′4-(4-متوکسی‌فنیل)-2,′2:′6،″2-ترپیریدین (Mtpy) به عنوان لیگاند و از CuI به عنوان مراکز فعال کاتالیستی استفاده شده است. در واکنش مورد مطالعه، از مخلوطی از N,N-دی‌متیل‌اِتیلن‌دی‌آمین (DMED) و تترابوتیل‌آمونیم­ برمید (TBAB) به عنوان حلال اتکتیک ژرف (DES) سبز و جدید با عملکرد سه­ گانه به عنوان باز، افزودنی و پیش­برنده واکنش جفت ­شدن کربن-کربن و همچنین نقش اصلی آن یعنی به عنوان حلال استفاده شده است. نتایج حاصل با دیگر گزارش ­های موجود در مراجع مقایسه و کارایی روش به وضوح نشان داده شده است. علاوه بر عملکرد سه­ گانه حلال اتکتیک ژرف، بازیابی آن تا سه مرحله در واکنش نشان از پایداری نسبی آن در محیط واکنش بوده و مورد توجه شیمی سبز می­ باشد.
کلیدواژه‌ها
حلال‌های اتکتیک ژرف
واکنش اولمن
کاتالیست
شیمی سبز
مشتقات بی‌فنیل

موضوعات

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