Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Sonochemical Synthesis of New Nano Lead(II) Coordination Polymer and Investigating the Effect of Concentration on Size of Nanoparticles

Document Type : Research Article

Authors
Elham Ghavdelaghdam 1
Gholam Hossein Shahverdizadeh 2
Javad Motamenitabatabaie 1
Babak Mirtamizdoust 3
1 Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN
2 Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN
3 Department of Chemistry, Qom University, Qom, I.R. IRAN
Abstract
In this paper, nanostructure of new 1D Pb(II) coordination polymers, [pb2 (C2Cl3O2)2(NO3)2 (Cl2H8N2)2] n were synthesized by a sonochemical method in different concentrations. Coordination polymers Lead (II) include a chain made of interlocking metal formed with ligands that are Cl3COO- and NO3-. The coordination geometry is based on a pentagonal–bipyramidal geometry defined by an N2O5 donor set with no obvious stereochemical role for the lead-bound lone pair of electrons. The new nanostructure was characterized by Scanning Electron Microscopy (SEM), IR spectroscopy, X-Ray powder Diffraction (XRD), and elemental analyses. The average size of the nanoparticles 80 nm. The concentration of  initial reagents effects on the size and morphology of nano-structured compound 1 have been studied and show that low concentrations of initial reagents decreased particle size and led to uniform nanoparticle morphology.
Keywords
Coordination polymer
Lead (II)
Sonochemical
Nanostructure
Subjects
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