Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

A Review on the Effect of Coordinated solvent Molecules, Guest, Pillar Ligand and Dicarboxylate Linkers in Synthesis of Zinc(II) Oxide Nanoparticles from Nanoporous Metal-Organic Frameworks

Document Type : Review Article

Authors
Maryam Moeinian
fatemeh Shahangi Shirazi
Kamran Akhbari
School of Chemistry, College of Science, University of Tehran, Tehran, I.R. IRAN
Abstract
Metal-organic frameworks due to their unique properties have many applications. Before using, metal-organic frameworks should be activated and there pores should become empty. ZnO nanoparticles can be prepared by calcination of non-active or activated metal-organic frameworks. In this paper, we wish to have a review on our recent research results in the field of using metal-organic frameworks as new precursors for the preparation of ZnO nanostructures. The results show that non-active metal-organic frameworks are appropriate precursors for the preparation of spherical ZnO nanoparticles but in their active forms, they tend to form agglomerated nanostructures. It can be said that if the number of organic components used in the structure of a metal-organic framework is greater; ZnO nanoparticles with a smaller size will result from it.
Keywords
Metal-organic framework
Nanoporous
Nanoparticle
Zinc(II) oxide
Subjects
[1] Zhou H.-C. ‘‘J’’., Kitagawa S., Metal–Organic Frameworks (MOFs), Chemical Society Reviews, 43: 5415-5418 (2014).
[2] Li J.-R., Sculley J., Zhou H.-C., Metal–Organic Frameworks for Separations, Chemical Reviews, 112: 869-932 (2012).
[3] Furukawa H., Cordova K.E., O’Keeffe M., Yaghi O.M., The Chemistry and Applications of Metal-Organic Frameworks, Science, 341: 974-986 (2013).
[4] Schneemann A., Henke S., Schwedler I., Fischer R.A., Targeted Manipulation of Metal–Organic Frameworks To Direct Sorption Properties, Chem. Phys. Chem., 15: 823-839 (2014).
[5] Schneemann A., Bon V., Schwedler I., Senkovska I., Kaskel S., Fischer R.A., Flexible Metal–Organic Frameworks, Chemical Society Reviews, 43: 6062-6096 (2014).
[6] Akhbari K., Morsali A., Modulating Methane Storage in Anionic Nano-Porous MOF Materials via Post-Synthetic Cation Exchange Process, Dalton Transactions, 42: 4786-4789 (2013).
[7] Tong X.-L., Lin H.-L., Xin J.-H., Liu F., Li M., Zhu X.-P., Recent Advances as Materials of Functional Metal-Organic Frameworks, Journal of Nanomaterials, 2013: 1-11 (2013).
[8] Kim K.S., Jeong H., Jeong M.S., Jung G.Y., Polymer-Templated Hydrothermal Growth of Vertically Aligned Single-Crystal ZnO Nanorods and Morphological Transformations Using Structural Polarity, Advanced Functional Materials, 20: 3055–3063 (2010).
[9] خانی، وجیهه؛ شریفی، لیلا؛ پیامی، آرش ؛ کوهانی، حسین ؛ میرحسینی، سید حسین؛ تهیه نانوپودر روی اکسید به روش سوختن ژل و استفاده از آن در ساخت پوشش­های مقاوم به خوردگی کامپوزیتی پلیمر/روی اکسید، نشریه شیمی و مهندسی شیمی ایران، (2)34: 1 تا 12 (1394).
[10] Ghaffarian H.R., Saiedi M., Sayyadnejad M.A., Rashidi A.M., Synthesis of ZnO Nanoparticles by Spray Pyrolysis Method, Iran. J. Chem. Chem. Eng. (IJCCE), 30(1): 1-6 (2011).
[11] Xu F., Dai M., Lu Y., Sun L., Hierarchical ZnO Nanowire-Nanosheet Architectures for High Power Conversion Efficiency in Dye-Sensitized Solar Cells, The Journal of Physical Chemistry C, 114: 2776–2782 (2010).
[12] Das R., Pachfule P., Banerjee R., Poddar P., Metal and Metal Oxide Nanoparticle Synthesis from Metal Organic Frameworks (MOFs): Finding the Border of Metal and Metal Oxides, Nanoscale, 4: 591-599 (2012).
[13] Hyuk Im J., Kang E., Yang S.J., Park H.J., Kim J., Park Ch.R., Simple Preparation of Anatase Titanium Dioxide Nanoparticles by Heating Titanium-Organic Frameworks, Bulletin of the Korean Chemical Society, 35: 2477-2480 (2014).
[14] Nasihat Sheno N., Morsali A., Joo S.W., Synthesis CuO Nanoparticles from a Copper(II) Metal-Organic Framework Precursor, Materials Letters, 117: 31–33 (2014).
[15] Alavi M.A., Morsali A., Joo S.W., Min B.-K., Ultrasound and Modulation Assisted Synthesis of {[Cu2(BDC-NH2)2(dabco)]DMF.3H2O} Nanostructures; New Precursor to Prepare Nanorods and Nanotubes of Copper(II) Oxide, Ultrasonics Sonochemistry, 22: 349-358 (2015).
[16] Liu B., Zhang X., Shioyama H., Mukai T., Sakai T., Xu Q., Converting Cobalt Oxide Subunits in Cobalt Metal-Organic Framework into Agglomerated Co3O4 Nanoparticles as an Electrode Material for Lthium Ion Battery, Journal of Power Sources, 195: 857–861 (2010).
[17] Luo B., Gladfelter W.L., On the Way to Monodispersed ZnO Nanocrystals: Structure of a Zinc Dimer Bearing Primary Amido Ligands, Journal of Coordination Chemistry, 64: 82-92 (2011).
[18] Rashidi Ranjbar Z., Morsali A., Sonochemical Synthesis of a Novel Nano-Rod Two-Dimensional Zinc(II) Coordination Polymer; Preparation of Zinc(II) Oxide Nanoparticles by Direct Thermolyses, Ultrasonics Sonochemistry, 18: 644-651 (2011).
[19] Khanpour M., Morsali A., Retailleau P., Sonochemical Syntheses of a Straw-Like Nano-Structure Two-Dimensional Mixed-Ligand Zinc(II) Coordination Polymer as Precursor for Preparation of Nano-Sized ZnO, Polyhedron, 29: 1520-1524 (2010).
[20] Shahangi Shirazi F., Akhbari K., Preparation of Zinc Oxide Nanoparticles from Nanoporous Metal–Organic Framework with One-Dimensional Channels Occupied with Guest Water Molecules, Inorganica Chimica Acta, 436: 1-6 (2015).
[21] Moeinian M., Akhbari K., How the Guest Molecules in Nanoporous Zn(II) Metal-Organic Framework can Prevent Agglomeration of ZnO Nanoparticles, Journal of Solid State Chemistry, 225: 459-463 (2015).
[22] Akhbari K., Morsali A., Effect of the Guest Solvent Molecules on Preparation of Different Morphologies of ZnO Nanomaterials from the [Zn2(1,4-bdc)2(dabco)] Metal-Organic Framework, Journal of Coordination Chemistry, 64(20): 3521–3530 (2011).
[23] Shahangi Shirazi F., Akhbari K., Linkers and Coordinated Solvent Molecules; The Two Effective Factors on Formation of Zinc Oxide Nanoparticles from Metal–Organic Frameworks, Inorganic Chemistry Communications, 63: 5–10 (2016).
[24] Moeinian M., Akhbari K., Effect of the Pillar Ligand on Preventing Agglomeration of ZnO Nanoparticles Prepared from Zn(II) Metal-Organic Frameworks, Nano Chemistry Research, 1(1): 57-62 (2016).
[25] Moeinian M., Akhbari K., Solid‑State Synthesis of Zinc Oxide Nano-Structures with Similar Morphologies to Their Precursors and Metal–Organic Frameworks Topology, Journal of the Iranian Chemical Society, 13: 547–552 (2016).