نشریه شیمی و مهندسی شیمی ایران

نشریه شیمی و مهندسی شیمی ایران

مروری بر پیشرفت در فرآیندهای کپسوله‏ سازی و مکانیسم‏ های خودترمیم‏ شوندگی برای محافظت در برابر خوردگی فعال

نوع مقاله : مروری

نویسندگان
1 گروه پژوهشی مواد غیرفلزی، پژوهشگاه نیرو، تهران، ایران
2 گروه شیمی، دانشگاه کاشان، کاشان، ایران
چکیده
استفاده از پوشش‏ های آلی، رایج ترین و به صرفه ترین روش برای حفاظت در برابر خوردگی و افزایش عمر مفید بسیاری از سازه های فلزی در محیط‏ های خورنده است. با این حال، پس از ایجاد آسیب در پوشش محافظ، فرآیندهای تخریب به سرعت گسترش می‏ یابد. برای دستیابی به عملکرد طولانی مدت پوشش در محیط خورنده، حفاظت فعال به کارگرفته شده همراه  با عیوب خود ترمیم شونده ضروری است. در مقاله مروری حاضر ابتدا ویژگی مواد خودترمیم برای کاربردهای ضد خوردگی بیان شده، سپس به طبقه‏ بندی فرآیند کپسوله‏ سازی که شامل کپسوله سازی فیزیکی و شیمیایی بوده پرداخته شده و درنهایت خلاصه‌ای از کارهای اخیر در زمینه سیستم‌های حفاظتی چند سطحی جدید ارائه شده که بر اساس رهاسازی کنترل‌شده گونه‌های ضد‏خوردگی از میکرو و نانو حامل هوشمند، در یک زمینه پوشش پلیمری است. همچنین این مقاله یک رویکرد خودترمیمی که شامل چندین مکانیسم پیشگیری و ترمیم آسیب را بوده را مورد بررسی قرار می‏ دهد، که شامل به دام افتادن یون‌های خورنده، مهار خوردگی و جابجایی آب از نقص‌های فعال می باشد. در بخش دیگر مقاله مروری بر روش های ارزیابی عملکرد پوشش‏ های خود‏ترمیم‏شونده با استفاده از تکنیک های الکتروشیمیایی، سطحی و میکروسکوپی شده است و همچنین پیشنهادهایی برای تکنیک های الکتروشیمیایی جایگزین برای ارزیابی پوشش خود ترمیم شونده بررسی می شوند. در انتها در بحث مدلینگ، به تحقیقات محاسباتی در مورد مواد خود ترمیم شونده پرداخته می شود.
کلیدواژه‌ها

موضوعات


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