Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Fabrication of NiTiO3 Electrocatalyst to Removal of Azo Dye Using Anodic Oxidation Process

Document Type : Research Article

Authors
Mohammadreza Mehralizadeh 1
Bahman Abdollahi 1, 2
1 Department of Physical Chemistry, Faculty of Chemistry, Tabriz University, Tabriz, Iran
2 Quality monitoring and supervision center of water and sewage company of East Azarbaijan province, Iran
Abstract
In this research, NiTiO3 electrocatalyst was prepared by sol-gel method and coated on graphite surface by electrophoretic method. Several analyzes were performed in order to investigate the microscopic morphology and structural characteristics of NiTiO3. The NiTiO3 particles were obtained in spherical form and in nano size. In addition, the cyclic voltammetry results demonstrated that the NiTiO3/G electrode exhibited superior electrocatalytic activity when compared to the G electrode. The oxidation potential of the NiTiO3/G electrode, 0.3 mV, indicated improved involvement in the anodic oxidation reaction. Conversely, the impedance results revealed a decreased charge transfer resistance for the NiTiO3/G electrode in comparison to the G electrode, thereby accelerating the degradation process. The prepared electrocatalyst was used to remove reactive black 5 (RB5) pollutant from aqueous solution by anodic oxidation process. For this purpose, the reaction reactor with NiTiO3/G anode electrode and graphite cathode electrode was used. The effect of current, initial pH, initial concentration of RB5 and process time on the removal efficiency of RB5 was investigated and the response surface method was used to optimize the anodic oxidation process. The results showed that the maximum removal efficiency of RB5 was observed in applied current, pH, initial concentration of RB5 and process time of, 500 mA, 6, 20 mg/L and 200 minutes, respectively. Based on this, such a method can be used to remove RB5 from polluted water.
Keywords
Electrocatalyst
Anodic oxidation
Reactive black
Response surface methodology
NiTiO3

Subjects

[1] Ansari Ouzi Z., Aber S., Nofouzi K., Khajeh R. T., Rezaei A., Carbon Paste/LDH/Bacteria Biohybrid for the Modification of the Anode Electrode of a Microbial Fuel Cell, J. Taiwan Inst. Chem. Eng., 142: 104668 (2023).
[2] Zafar S., Bukhari D. A., Rehman A., Azo Dyes Degradation by Microorganisms – An Efficient and Sustainable Approach, Saudi J. Biol. Sci., 29(12): 103437 (2022).
[3] Shokri A., Using Mn Based on Lightweight Expanded clay Aggregate (LECA) as an Original Catalyst for the Removal of NO2 Pollutant in Aqueous Environment, Surf. Interfaces, 21: 100705 (2020).
[4] Rajendran S., Priya T.A.K., Khoo K. Sh., Hoang T. K.A., Ng H.S., Halimatul Munawaroh H. S., Karaman C., Orooji Y., Show P. L., A Critical Review on Various Remediation Approaches for Heavy Metal Contaminants Removal from Contaminated Soils, Chemosphere, 287: 132369 (2022).
[5] Amali S., Zarei M., Ebratkhahan M., Khataee A., Preparation of Fe@Fe2O3/3D Graphene Composite Cathode for Electrochemical Removal of Sulfasalazine, Chemosphere, 273: 128581 (2021).
[6] Padervand M., Ghasemi Sh., Hajiahmadi S., Rhimi B., Ghobadi Nejad Z., Karima S., Shahsavari Z., Wang Ch., Multifunctional Ag/AgCl/ZnTiO3 Structures as Highly Efficient Photocatalysts for the Removal of Nitrophenols, CO2 Photoreduction, Biomedical Waste Treatment, and Bacteria Inactivation, Appl. Catal. Gen., 643: 118794 (2022).
[7] Pezhhanfar S., Farajzadeh M. A., Abdollahi B., Hosseini-Yazdi S. A., Ashar Mogaddam M. R., Development of an Extraction Method Based on a Zirconium-based Metal Organic Framework for the Detection and Determination of some Pesticides in Juice Samples Using GC-FID, Anal. Bioanal. Chem. Res., 9(4): 319–330 (2022).
[8] Bilińska L. and Gmurek M., Novel Trends in AOPs for Textile Wastewater Treatment. Enhanced Dye by-Products Removal by Catalytic and Synergistic Actions, Water Resour. Ind., 26: 100160 (2021).
[9] Ismail G. A.and Sakai H., Review on Effect of Different Type of Dyes on Advanced Oxidation Processes (AOPs) for Textile Color Removal, Chemosphere, 291: 132906 (2022).
[10] Saghi M., Shokri A., Arastehnodeh A., Khazaeinejad M., Nozari A., The Photo Degradation of Methyl red in Aqueous Solutions by α-Fe2O3/SiO2 Nano Photocatalyst, J. Nanoanalysis, 5(3): 163–170 (2018).
[11] Habibi R., Gilani N., Pasikhani J. V., Pirbazari A. E., Improved Photoelectrocatalytic Activity of Anodic TiO2 Nanotubes by Boron in Situ Doping Coupled with Geometrical Optimization: Application of a Potent Photoanode in the Purification of Dye Wastewater, J. Solid State Electrochem., 25)2): 545–560 (2021).
[12] Najafidoust A., Abdollahi B., Asl E. A., Karimi R., Synthesis and Characterization of Novel M@ZnO/UiO-66 (M = Ni, Pt, Pd and Mixed Pt&Pd) as an Efficient Photocatalyst Under Solar Light, J. Mol. Struct., 1256: 132580 (2022).
[13] Liu L., Chen Z., Zhang J., Shan D., Wu Y., Bai L., Wang B., Treatment of Industrial dye Wastewater and Pharmaceutical Residue Wastewater by Advanced Oxidation Processes and Its Combination with Nanocatalysts: A Review, J. Water Process Eng., 42: 102122 (2021).
[14] Dihom H. R., Al-Shaibani M. M., Radin Mohamed R. M. S., Al-Gheethi A. A., Sharma A., Khamidun M. H. B., Photocatalytic Degradation of Disperse azo Dyes in Textile Wastewater Using Green Zinc Oxide Nanoparticles Synthesized in Plant Extract: A Critical Review, J. Water Process Eng., 47: 102705 (2022).
[15] Rezaei A., Karami Z., Feli F., Aber S., Oxygen Reduction Reaction Enhancement in Microbial Fuel Cell Cathode using Cesium Phosphomolybdate Electrocatalyst, Fuel, 352: 129040 (2023).
[16] Khataee A., Arefi-Oskoui S., Abdollahi B., Hanifehpour Y., Joo S. W., Synthesis and Characterization of PrxZn1−xSe Nanoparticles for Photocatalysis of Four Textile Dyes with Different Molecular Structures, Res. Chem. Intermed., 41(11): 8425–8439 (2015).
[17] Honarmandrad Z., Sun X., Wang Z., Naushad M., Boczkaj G. Activated Persulfate and Peroxymonosulfate Based Advanced Oxidation Processes (AOPs) for Antibiotics Degradation – A Review, Water Resour. Ind., 29: 100194 (2023).
[18] Abdollahi B., Zarei M., Salari D., Synthesis, Characterization, and Application of Diethylenetriamine Functionalized MIL-53(Fe) Metal-Organic Framework for Efficient As(V) Removal from Surface and Groundwater, J. of Solid State Chem., 311: 123132 (2022).
]19[ عبدالمحمدی، شهرزاد؛ جانی تبار درزی، سیمین؛ ایران فر، شیدا، کاربرد نانوذره‌های ZnO آلاییده شده با رنگ رز بنگال در تخریب فوتوکاتالیستی آلاینده‌هاى فنلى با تابش نور مرئى، نشریه شیمی و مهندسی شیمی ایران، (3)39: 47-53، (1399).
[20] Shokri A. and Mahanpoor K., Removal of Ortho-Toluidine from Industrial Wastewater by UV/TiO2 Process, J. Chem. Health Risks, 6(3): (2016).
[21] M'Arimi M. M., Mecha C. A., Kiprop A. K., Ramkat R., Recent Trends in Applications of Advanced Oxidation Processes (AOPs) in Bioenergy Production: Review, Renew. Sustain. Energy Rev., 121: 109669 (2020).
[22] Mohammadi R., Masoumi B., Mashayekhi R., Hosseinian A., Fe3O4/Polystyrene-Alginate Nanocomposite as a Novel Adsorbent for Highly Efficient Removal of Dyes, Iran. J. Chem. Chem. Eng., 41(11): 3632-3645 (2022).
[23] Giannakis S., Lin K.-Y. A., Ghanbari F., A Review of the Recent Advances on the Treatment of Industrial Wastewaters by Sulfate Radical-Based Advanced Oxidation Processes (SR-AOPs), Chem. Eng. J., 406: 127083 (2021).
[24] Najafidoust A., Abdollahi B., Abbasi Asl E., Karimi R., Synthesis and Characterization of Novel M@ZnO/UiO-66 (M = Ni, Pt, Pd and Mixed Pt&Pd) as an Efficient Photocatalyst Under Solar Light, J. of Mole. Str., 1256: 132580 (2022).
[25] Fu R., Zhang P.-S., Jiang Y.-X., Sun L., Sun X.-H., Wastewater Treatment by Anodic Oxidation in Electrochemical Advanced Oxidation Process: Advance in Mechanism, Direct and Indirect Oxidation Detection Methods, Chemosphere, 311: 136993 (2023).
[26] Shokri A. and Karimi S., Treatment of Aqueous Solution Containing Acid Red 14 using an Electro Peroxone Process and a Box-Behnken Experimental Design, Muq-Hyg., 9(1): 48–57 (2020).
[27] Luna Y. De and Bensalah N., Review on the Electrochemical Oxidation of Endocrine-Disrupting Chemicals using BDD Anodes, Curr. Opin. Electrochem., 32: 100900 (2022).
[28] Shokri A., Employing Electro-Peroxone Process for Degradation of Acid Red 88 in Aqueous Environment by Central Composite Design: A New Kinetic Study and Energy Consumption, Chemosphere, 296: 133817 (2022).
[29] Padervand M., Rhimi B., Wang C., One-pot Synthesis of Novel Ternary Fe3N/Fe2O3/C3N4 Photocatalyst for Efficient Removal of Rhodamine B and CO2 Reduction, J. Alloys Compd., 852: 156955 (2021).
[30] Padervand M., Lammel G., Bargahi A., Mohammad-Shiri H., Photochemical Degradation of the Environmental Pollutants Over the Worm-Like Nd2CuO4-Nd2O3 Nanostructures, Nano-Struct. Nano-Objects, 18: 100258 (2019).
[31] Hodges B. C., Cates E. L., Kim J.-H., Challenges and Prospects of Advanced Oxidation Water Treatment Processes using Catalytic Nanomaterials, Nat. Nanotechnol., 13(8): 642–650 (2018).
[32] Lin N., Gong Y., Wang R., Wang Y., Zhang X., Critical Review of Perovskite-Based Materials in Advanced Oxidation System for Wastewater Treatment: Design, Applications and Mechanisms, J. Hazard. Mater., 424: 127637 (2022).
[33] Zhang H., Ji X., Xu H., Zhang R., Zhang H., Design and Modification of Perovskite Materials for Photocatalytic Performance Improvement, J. Environ. Chem. Eng., 11(1): 109056 (2023).
[34] Gao P., Tian X., Nie Y., Yang C., Zhou Z., Wang Y., Promoted Peroxymonosulfate Activation Into Singlet Oxygen Over Perovskite for Ofloxacin Degradation by Controlling the Oxygen Defect Concentration, Chem. Eng. J., 359: 828–839 (2019).
[35] Barman S. and Sahu P. P., NiTiO3 Perovskite Nanoparticles for Highly Durable Hydrogen and Oxygen Evolution in Water Splitting, in 2022 IEEE Global Conference on Computing, Power and Communication Technologies (GlobConPT),  (2022).
[36] Rezaei A., Aber S., Roberts D. J., Javid GA A., Synthesis and Study of CuNiTiO3 as an ORR Electrocatalyst to Enhance Microbial Fuel Cell Efficiency, Chemosphere, 307: 135709 (2022).
[37] Pavithra C. and Madhuri W., Electrical and Magnetic Properties of NiTiO3 Nanoparticles Synthesized by the Sol-Gel Synthesis Method and Microwave Sintering, Mater. Chem. Phys., 211: 144–149 (2018).
[38] Yuvaraj S., Nithya V.D., Saiadali Fathima K., Sanjeeviraja C., Kalai Selvan G., Arumugam S., Kalai Selvan R., Investigations on the Temperature Dependent Electrical and Magnetic Properties of NiTiO3 by Molten Salt Synthesis, Mater. Res. Bull., 48(3): 1110–1116 (2013).
[39] Kim S.-R. and Jo W.-K., Application of a Photostable Silver-Assisted Z-Scheme NiTiO3 Nanorod/g-C3N4 Nanocomposite for Efficient Hydrogen Generation, Int. J. Hydrog. Energy, 44(2): 801–808 (2019).
[40] Du X., Oturan, M. A., Minghua Z., Belkessa N., Su P., Cai J., Trellu C., Mousset E., Nanostructured Electrodes for Electrocatalytic Advanced Oxidation Processes: From Materials Preparation to Mechanisms Understanding and Wastewater Treatment Applications, Appl. Catal. B Environ., 296: 120332 (2021).
[41] Yang X., Zou R., Huo F., Cai D., Xiao D., Preparation and Characterization of Ti/SnO2–Sb2O3–Nb2O5/PbO2 Thin Film as Electrode Material for the Degradation of Phenol, J. Hazard. Mater., 164(1): 367–373 (2009).
[42] Babaei T., Zarei M., Hosseini M. G., Hosseini M. M., Electrochemical Advanced Oxidation Process of Phenazopyridine Drug Waste Using Different Ti-Based IrO2-Ta2O5 Anodes, J. Taiwan Inst. Chem. Eng., 117: 103–111 (2020).
[43] Jamal Sisi A., Fathinia M., Khataee A., Orooji Y., Systematic Activation of Potassium Peroxydisulfate with ZIF-8 Via Sono-Assisted Catalytic Process: Mechanism and Ecotoxicological Analysis, J. Mol. Liq., 308: 113018 (2020).
[44] Azzaz A. A., Jellali S., Akrout H., Assadi A. A., Bousselmi L., Dynamic Investigations on Cationic Dye Desorption from Chemically Modified Lignocellulosic Material Using a Low-Cost Eluent: Dye Recovery and Anodic Oxidation Efficiencies of the Desorbed Solutions, J. Clean. Prod., 201: 28–38 (2018).
[45] Zhang L., Xu L., He J., Zhang J., Preparation of Ti/SnO2-Sb Electrodes Modified by Carbon Nanotube for Anodic Oxidation of Dye Wastewater and Combination with Nanofiltration, Electrochimica Acta, 117: 192–201 (2014).
[46] Abdel-Aziz M. H., Bassyouni M., Zoromba M. S., Alshehri A. A., Removal of Dyes from Waste Solutions by Anodic Oxidation on an Array of Horizontal Graphite Rods Anodes, Ind. Eng. Chem. Res., 58(2): 1004–1018 (2019).
[47] Li J., Zheng L., Li L., Xian Y., Jin L., Fabrication of TiO2/Ti Electrode by Laser-Assisted Anodic Oxidation and Its Application on Photoelectrocatalytic Degradation of Methylene Blue, J. Hazard. Mater., 139(1): 72–78 (2007).