Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Synthesis of Fe3O4/Graphene Nanocomposite and Investigation of Their Catalytic Activity on Thermal Decomposition of Ammonium Perchlorate Particles

Document Type : Research Article

Authors
Seyed Ghorban Hosseini
Zahra Khodadaipoor
Department of Chemistry, Malek Ashtar University of Technology, P.O. Box 16765-3454 Tehran, I.R. IRAN
Abstract
In this study, Fe3O4/ graphene nanocomposite was prepared by a gas/liquid interface reaction and characterized by XRD, IR and SEM techniques. Transmission electron microscope images revealed that the ultrafine Fe3O4 NPs are homogeneously deposited on the supporting G-O sheets and graphene oxide sheets could hinder the aggregation of Fe3O4 NPs. Then, the catalytic performance of the synthesized material on the thermal decomposition of ammonium perchlorate (AP) was investigated by ThermoGravimetry Analysis (TGA) and differential scanning calorimetry (DSC) techniques. The results of the thermal analysis showed that the composites exhibit better catalytic effect for the thermal decomposition of ammonium perchlorate than Fe3O4 NPs due to the combination of graphene sheets and Fe3O4 NPs.
Keywords
Fe3O4
Graphene
Ammonium perchlorate
Thermal decomposition

Subjects

[1] Berger C., Song Z., Li X., Wu X., Brown N., Naud C., Mayou D., Li T., Hass J., Marchenkov A.N., Electronic Confinement and Coherence in Patterned Epitaxial Graphene, Science, 312: 1191-1196 (2006).
[2] Geim A.K., Novoselov K.S., The Rise of Graphene, Nat. Mater., 6(3): 183-191 (2007).
[3] Naseri A., Barati R., Rasoulzadeh F., Bahram M., Studies on Adsorption of Some Organic Dyes from Aqueous Solution onto Graphene Nanosheets, Iran. J. Chem. Chem. Eng. (IJCCE), 34(2): 51-60 (2015). 
[4] lake P. B, Brimicombe P.D., Nair R.R., Booth T.J., Jiang D., Schedin F., Ponomarenko L.A., Morozov S.V., Gleeson H.F., Hill E.W., Graphene-Based Liquid Crystal Device, Nano Lett., 8(6): 1704-1708 (2008).
[5]  Arsat R., Breedon M., Shafiei M., Spizziri P., Gilje S., Kaner R., Kalantar-zadeh K., Wlodarski W., Graphene-Like Nano-Sheets for Surface Acoustic Wave Gas Sensor Applications, Chem. Phys. Lett., 467 (4): 344-347(2009).
[6]  Zhao J., Liu Z., Qin Y., Hu W., Fabrication of Co3O4/Graphene Oxide Composites Using Supercritical Fluid and Their Catalytic Application for the Decomposition of Ammonium Perchlorate, Cryst. Eng. Comm., 16 (10): 2001-2008 (2014).
[7]  Zh J.i, Tian-Fang W., Shu-Fen L., Feng-Qi Z., Zi-Ru L., Cui-Mei, Y. Yang L., Shang-Wen L., Gang-Zhui Z., Thermal Behavior of Ammonium Perchlorate and Metal Powders of Different Grades, J. Therm. Anal. Calorim., 85 (2): 315-320 (2005).
[8] Zarrin Ghalam Moghaddam A., Hashemi Pour Rafsanjani A.A., The Role of Boron in Thermal Decomposition of Ammonium Perchlorate, Iran. J. Chem. Chem. Eng. (IJCCE), 19(1): 40-42 (2000).
[9]  Hosseini S.G., Ahmadi R., Ghavi A., Kashi A., Synthesis and Characterization of α-Fe2O3 Mesoporous Using SBA-15 Silica as Template and Investigation of Its Catalytic Aactivity for Thermal Decomposition of Ammonium Pperchlorate Particles, Powder Technol., 278: 316-322 (2015).
[10]  Ayoman E., Hosseini S.G., Synthesis of CuO Nanopowders by High-Energy Ball-Milling Method and Investigation of Their Catalytic Activity on Thermal Decomposition of Ammonium Perchlorate Particles, J. Therm. Anal. Calorim., 123(2): 1213-1224 (2016).
[11]  Zhang Y., Wang  N., Huang Y., Wu W., Huang  C., Meng  C., Fabrication and Catalytic Activity of Ultra-Long V2O5 Nanowires on the Thermal Decomposition of Ammonium Perchlorate, Ceram. Int., 40 (7): 11393-11398 (2014).
[12] حسینی، سید قربان; ایومن، اسماعیل; بررسی فعالیت کاتالیست نانوذره­های CuO در تجزیه گرمایی آمونیوم پرکلرات، نشریه شیمی و مهندسی شیمی ایران، (2) 34: 13 تا 23 (1394).
[13] Liu E., Zhang W., Zheng J. G., Hu X., Ou H., Du R., Kou C., Zhai Y., Xu Q., Du J., Inverse Magnetoresistance in Textured Fe3O4 Film, J. Alloys Compd., 649: 239-243 (2015).
[14]  Urbanova V., Magro M., Gedanken A., Baratella D., Vianello F., Zboril R., Nanocrystalline Iron oxides, Composites, and Related Materials as a Platform for Electrochemical, Magnetic, and Chemical Biosensors, Chem. Mater., 26 (23): 6653-6673 (2014).
[15] Wang W., Yao J., Catalytic Activity of Magnetite with Different Shapes for the Thermal Decomposition of Ammonium Perchlorate, Chem. Lett., 43 (10): 1554-1556 (2014).
[16] Stankovich S., Dikin D.A., Dommett G.H., Kohlhaas K.M., Zimney E.J., Stach E.A., Piner R.D., Nguyen S.T., Ruoff R.S., Graphene-Based Composite Materials, Nature, 442: 282-286 (2006). 
[17]  Zhao Y., Song X., Song Q., Yin Z., A Facile Route to the Synthesis Copper Oxide/Reduced Graphene Oxide Nanocomposites and Electrochemical Detection of Catechol Organic Pollutant, Cryst. Eng. Comm., 14 (20): 6710-6719 (2012).
[18]  Becerril H.A., Mao J., Liu Z., Stoltenberg R.M., Bao Z., Chen Y., Evaluation of Solution-Processed Reduced Graphene Oxide Films as Transparent Conductors, ACS Nano., 2(3): 463-470 (2008).
[19] Lu A.H., Salabas E.e.L., Schüth F., Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application, Angew. Chem. Int. Ed., 46: 1222-1244 (2007).
[20] Cui Z. M., Jiang  L. Y., Song W. G., Guo Y. G., High-Yield Gas− Liquid Interfacial Synthesis of Highly Dispersed Fe3O4Nanocrystals and Their Application in Lithium-Ion Batteries, Chem. Mater., 21 (6): 1162-1166 (2009).
[21] Shi R., Yan L., Xu T., Liu D., Zhu Y., Zhou J., Graphene Oxide Bound Silica for Solid-Phase Extraction of 14 Polycyclic Aromatic Hydrocarbons in Mainstream Cigarette Smoke, J. Chromatogr. A., 1375: 1-7 (2015).
[22] Zaitsev V.S., Filimonov D.S., Presnyakov I.A., Gambino R.J., Chu B., Physical and Chemical Properties of Magnetite and Magnetite-Polymer Nanoparticles and Their Colloidal Dispersions, J. Colloid Interface Sci., 212 (1): 49-57(1999).
[23]  Hosseini S.G., Abazari R., Gavi A., Pure CuCr2O4 Nanoparticles: Synthesis, Characterization and Their Morphological and Size Effects on the Catalytic Thermal Decomposition of Ammonium Perchlorate, Solid State Sci., 37: 72-79 (2014).
[24] Li N., Cao M., Wu Q., Hu C., A Facile One-Step Method to Produce Ni/Graphene Nanocomposites and Their Application to the Thermal Decomposition of Ammonium Pperchlorate. Cryst. Eng.Comm., 14 (2): 428-34 (2012).
[25] Li N., Geng  Z., Cao M., Ren L., Zhao X., Liu B., Tian Y., Hu C., Well-Dispersed Ultrafine Mn3 O4 Nanoparticles on Graphene as a Promising Catalyst for the Thermal Decomposition of Ammonium Perchlorate, Carbon, 54: 124-132 (2013).
[26] Yuan Y., Jiang W., Wang Y., Shen P., Li F., Li P., Zhao F., Gao H, Hydrothermal Preparation of Fe2 O3/Graphene Nanocomposite and Its Enhanced Catalytic Activity on the Thermal Decomposition of Ammonium Perchlorate, Appl. Surf. Sci, 303 (1): 354-359 (2014).
[27] Zhu J., Zeng G., Nie F., Xu X., Chen S., Han Q., Wang X, Decorating Graphene Oxide with CuO Nanoparticles in a Water–Isopropanol System. Nanoscale., 2(6): 988-994 (2010).
[28] Dey A., Athar J., Varma P., Prasant H., Sikder AK., Chattopadhyay S, Graphene-Iron Oxide Nanocomposite (GINC): an Efficient Catalyst for Ammonium Perchlorate (AP) Decomposition and Burn Rate Enhancer for AP Based Composite Propellant, RSC Adv., 5(3):1950-60 (2015).