Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Determination of Cloxacillin by Using Co3O4 Nanoparticles-Enhanced Chemiluminescence Reaction

Document Type : Research Article

Authors
Mortaza Iranifam
Shirin Mikalili Haji Kandi
Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, I.R. IRAN
Abstract
In this work, the catalytic effect of Co3O4 NanoParticles (NPs) on the luminol-O2 chemiluminescence (CL) reaction in alkaline medium was presented. By using quick precipitation method, Co3O4 NPs were synthesized and then by using Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Fourier Transform InfraRed (FT-IR) spectroscopy were characterized. In the following, it was indicated that cloxacillin can increase the intensity of the luminol-O2 CL reaction. Based on these findings, a new, simple, and sensitive CL method for the determination of cloxacillin was presented. The liner range, correlation coefficient, limit of detection and reproducibility (RSD%) of the method for cloxacillin were 3.0 × 10-5 - 7.0 × 10-4 mol/L, 0.99, 2.9 × 10-5 mol/L and 2.2% respectively and analysis of each sample took about 1.0 minute. In addition, this proposed method was successfully used for the determination of cloxacillin in pharmaceutical formulation.
Keywords
Co3O4 nanoparticles
Chemiluminescence
Cloxacillin
Luminol

Subjects

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