Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Synthesis of Chromenes from Benzyl Alcohol Derivatives Using Schiff Base Cobalt (II) Catalyst Bonded to Crown Ether and Supported on Cellulose Nanoparticles

Document Type : Research Article

Author
Reza Sandaroos
Department of Chemistry, Faculty of Science, University of Birjan, Birjand, I.R. IRAN
Abstract
this research, a Schiff base-cobalt (II) catalyst containing crown ether, stabilized on cellulose nanoparticles (Crowned Imine-Co (II)@CNC) was prepared. This catalyst was identified by SEM, IR, TGA, XRD, EDX and TEM techniques. This compound was used as a heterogeneous catalyst in the synthesis of chromenes. Chromenes were synthesized with good efficiency (77% to 99%) and within a short time of 20 minutes through the reaction between diketones, malononitrile and various benzyl alcohol derivatives in water solvent. Reusing the recycled catalyst (up to 4 times) did not change the reaction efficiency. The difference between this method and other methods of synthesizing chromenes is by using benzyl alcohol derivatives instead of benzaldehyde.
Keywords
Schiff base
Crown ether
Cellulose nanoparticles
Chromene
Benzyl alcohol

Subjects

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