Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Global Market Analysis of Metal-Organic Frameworks and Their Industrial Applications

Document Type : Review Article

Authors
Fatemeh Shahrab
Kamran Akhbari
Department of Inorganic Chemistry, Faculty of Chemistry, School of Science, University of Tehran, Tehran, I.R. IRAN
Abstract
Metal-Organic Frameworks (MOFs) are highly versatile materials with tunable properties, making them suitable for various industrial applications. In recent decades, advancements in MOF technology have enabled their potential use in fields such as gas storage, carbon capture, catalysis, drug delivery, and sensors. The rise in patents, particularly in China and the U.S., reflects growing commercial interest. Key challenges for industrial-scale production include optimizing synthesis conditions, solvent selection, and reducing costs. This review explores the synthesis, applications, and future directions of MOFs, focusing on scalability, cost-efficiency, and sustainability in large-scale production. The transformative impact of MOFs on industrial processes and materials science is emphasized.
Keywords
Metal-Organic Frameworks (MOFs)
Industrial applications
Large-scale
Industrial production
[1] Parsaei M., Akhbari K., Kawata S., Computational Simulation of CO2/CH4 Separation on a Three-Dimensional Cd-Based Metal–Organic Framework, Crystal Growth & Design, 23: 5705-5718 (2023).
[2] Parsaei M., Akhbari K., Tylianakis E., Froudakis G.E., White J.M., Kawata S., Computational Study of Two Three-Dimensional Co (II)-Based Metal–Organic Frameworks as Quercetin Anticancer Drug Carriers, Crystal Growth & Design, 22: 7221-7233 (2022).
[3] Salimi S., Akhbari K., Farnia S.M.F., Tylianakis E., Froudakis G.E., White J.M., Solvent‐Directed Construction of a Nanoporous Metal‐Organic Framework with Potential in Selective Adsorption and Separation of Gas Mixtures Studied by Grand Canonical Monte Carlo Simulations, ChemPlusChem, 89: e202300455 (2024).
[4] Bieniek A., Terzyk A.P., Wiśniewski M., Roszek K., Kowalczyk P., Sarkisov L., Keskin S., Kaneko K., MOF Materials as Therapeutic Agents, Drug Carriers, Imaging Agents and Biosensors in Cancer Biomedicine: Recent Advances and Perspectives, Progress in Materials Science, 117:100743 (2021).
[5] Ma Y., Qu X., Liu C., Xu Q., Tu K., Metal-Organic Frameworks and Their Composites Towards Biomedical Applications, Frontiers in molecular biosciences, 8: 805228 (2021).
[6] Ge X., Wong R., Anisa A., Ma S., Recent Development of Metal-Organic Framework Nanocomposites for Biomedical Applications, Biomaterials, 281: 121322 (2022).
[7] Parsaei M., Akhbari K., Tylianakis E., Froudakis G.E., Computational Simulation of a Three-Dimensional Mg-based Metal–Organic Framework as Nanoporous Anticancer Drug Carrier, Crystal Growth & Design, 23: 8396-8406 (2023).
[8] Alavijeh R.K., Akhbari K., Cancer Therapy by Nano MIL-n Series of Metal-Organic Frameworks, Coordination Chemistry Reviews, 503: 215643 (2024).
[9] Alavijeh R.K., Beheshti S., Akhbari K., Morsali A., Investigation of Reasons for Metal–Organic Framework’s Antibacterial Activities, Polyhedron, 156: 257-278 (2018).
[10] Parsaei M., Akhbari K., Magnetic UiO-66-NH2 Core–Shell Nanohybrid as a Promising Carrier for Quercetin Targeted Delivery toward Human Breast Cancer Cells, ACS omega, 8: 41321-41338 (2023).
[11] Mohammadi Amidi D., Akhbari K., Soltani S. , Loading of ZIF‐67 on Silk with Sustained Release of Iodine as Biocompatible Antibacterial Fibers, Applied Organometallic Chemistry, 37: e6913 (2023).
[12] Arshadi Edlo A., Akhbari K., Modulated Antibacterial Activity in ZnO@ MIL‐53 (Fe) and CuO@ MIL‐53 (Fe) Nanocomposites Prepared by Simple Thermal Treatment Process, Applied Organometallic Chemistry, 38: e7326 (2024).
[13] Davoodi A., Akhbari K., Alirezvani M., Prolonged Release of Silver and Iodine from ZIF-7 Carrier with Great Antibacterial Activity, CrystEngComm, 25: 3931-3942 (2023).
[14] Alavijeh R.K., Akhbari K., White J.M., A Ca-Based Nano Bio-Coordination Polymer Providing Reversible Structural Conversion with Ability to Enhance Cytotoxicity of Curcumin and Induce Apoptosis in Human Gastric Cancer AGS Cells, CrystEngComm, 24: 7125-7136 (2022).
[15] Nakhaei M., Akhbari K., Davoodi A., Biocompatible MOF-808 as an Iodophor Antimicrobial Agent with Controlled and Sustained Release of Iodine, CrystEngComm, 23: 8538-8545 (2021).
[16] Edlo A.A., Akhbari K., Modulating the Antibacterial Activity of a CuO@ HKUST-1 Nanocomposite by Optimizing Its Synthesis Procedure, New Journal of Chemistry, 47: 20770-20776 (2023).
[17] Kermanshahi P.K., Akhbari K., The Antibacterial Activity of Three Zeolitic-Imidazolate Frameworks and Zinc Oxide Nanoparticles Derived from Them, RSC advances, 14: 5601-5608 (2024).
[18] Liu J., Chen C., Zhang K., Zhang L., Applications of Metal–Organic Framework Composites in CO2 Capture and Conversion, Chinese Chemical Letters, 32: 649-659 (2021).
[19] Ding M., Flaig R.W., Jiang H.-L., Yaghi O.M., Carbon Capture and Conversion using Metal–Organic Frameworks and MOF-Based Materials, Chemical Society Reviews, 48: 2783-2828 (2019).
[20] Gebremariam S.K., Dumée L.F., Llewellyn P.L., AlWahedi Y.F., Karanikolos G.N., Metal-Organic Framework Hybrid Adsorbents for Carbon Capture–A Review, Journal of Environmental Chemical Engineering, 11: 109291 (2023).
[21] Liu K.-G., Sharifzadeh Z., Rouhani F., Ghorbanloo M., Morsali A., Metal-Organic Framework Composites as Green/Sustainable Catalysts, Coordination Chemistry Reviews, 436: 213827 (2021).
[22] Murtaza S.Z., Alqassem H.T., Sabouni R., Ghommem M., Degradation of Micropollutants by Metal Organic Framework Composite-Based Catalysts: A Review, Environmental Technology & Innovation, 29: 102998 (2023).
[23] Wang H., Zheng F., Xue G., Wang Y., Li G., Tang Z., Recent Advances in Hollow Metal-Organic Frameworks and Their Composites for Heterogeneous Thermal Catalysis, Science China Chemistry, 1-21 (2021).
[24] Shahrab F., Tadjarodi A., Novel Magnetic Nanocomposites BiFeO3/Cu (BDC) for Efficient Dye Removal, Heliyon, 9: (2023).
[25] Ghasemzadeh R., Akhbari K., Band Gap Engineering of MOF-801 via Loading of γ-Fe2O3 Quantum Dots Inside It as a Visible Light-Responsive Photocatalyst for Degradation of Acid Orange 7, Crystal Growth & Design, 23: 6359-6368 (2023).
[26] Ghasemzadeh R., Akhbari K., Embedding of Copper (i) Oxide Quantum Dots in MOF-801 for the Photocatalytic Degradation of Acid Yellow 23 Under Visible Light, New Journal of Chemistry, 47: 15760-15770 (2023).
[27] Ghasemzadeh R., Akhbari K., Heterostructured Ag@ MOF-801/MIL-88a (Fe) Nanocomposite as a Biocompatible Photocatalyst for Degradation of Reactive Black 5 Under Visible Light, Inorganic Chemistry, 62: 17818-17829 (2023).
[28] Ghasemzadeh R., Akhbari K., Templated Synthesis of ZnO Quantum Dots Via Double Solvents Method Inside MOF-801 as Emerging Photocatalyst for Photodegradation of Acid Blue 25 under UV Light, Journal of Photochemistry and Photobiology A: Chemistry, 448: 115306 (2024).
[29] Ahmed I., Jhung S.H., Composites of Metal–Organic Frameworks: Preparation and Application in Adsorption, Materials today, 17: 136-146 (2014).
[30] Paitandi R.P., Wan Y., Aftab W., Zhong R., Zou R., Pristine Metal–Organic Frameworks and Their Composites for Renewable Hydrogen Energy Applications, Advanced Functional Materials, 33: 2203224 (2023).
[31] Chuhadiya S., Suthar D., Patel S., Dhaka M., Metal Organic Frameworks as Hybrid Porous Materials for Energy Storage and Conversion Devices: A Review, Coordination Chemistry Reviews, 446: 214115 (2021).
[32] Salimi S., Akhbari K., Farnia S.M.F., Tylianakis E., Froudakis G.E., White J.M., Nanoporous Metal–Organic Framework Based on Furan-2, 5-Dicarboxylic Acid with High Potential in Selective Adsorption and Separation of Gas Mixtures, Crystal Growth & Design, 24: 4220-4231 (2024).
[33] Hu Y., Ye Z., Peng X., Metal-Organic Frameworks for Solar-Driven Atmosphere Water Harvesting, Chemical Engineering Journal, 452 :139656 (2023).
[34] Gordeeva L.G., Tu Y.D., Pan Q., Palash M., Saha B.B., Aristov Y.I., Wang R.Z., Metal-Organic Frameworks for Energy Conversion and Water Harvesting: A Bridge Between Thermal Engineering and Material Science, Nano Energy, 84 :105946 (2021).
[35] Mohan B., Kumar S., Chen Q., Obtaining Water from Air using Porous Metal–Organic Frameworks (MOFs), Topics in Current Chemistry, 380: 54 (2022).
[36] Chen Z., Wasson M.C., Drout R.J., Robison L., Idrees K.B., Knapp J.G., Son F.A., Zhang X., Hierse W., Kühn C., The State of the Field: from Inception to Commercialization of Metal–Organic Frameworks, Faraday discussions, 225: 9-69 (2021),
[37] He Q., Zhan F., Wang H., Xu W., Wang H., Chen L., Recent Progress of Industrial Preparation of Metal–Organic Frameworks: Synthesis Strategies and Outlook, Materials Today Sustainability, 17: 100104 (2022).
[38] Yaghi O.M., O'Keeffe M., Ockwig N.W., Chae H.K., Eddaoudi M., Kim J., Reticular Synthesis and the Design of New Materials, Nature, 423: 705-714 (2003).
[39] Feng L., Wang K.-Y., Willman J., Zhou H.-C., Hierarchy in Metal–Organic Frameworks, ACS Central Science, 6 :359-367 (2020).
[40] Seo Y.-K., Yoon J.W., Lee J.S., Lee U.-H., Hwang Y.K., Jun C.-H., Horcajada P., Serre C., Chang J.-S., Large Scale Fluorine-Free Synthesis of Hierarchically Porous Iron (III) Trimesate MIL-100 (Fe) with a Zeolite MTN Topology, Microporous and Mesoporous Materials, 157 :137-145 (2012).
[41] Mueller U., Puetter H., Hesse M., Schubert M., Wessel H., Huff J., Guzmann M., Method for Electrochemical Production of a Crystalline Porous Metal Organic Skeleton Material, Google Patents, (2011).
[42] Rubio‐Martinez M., Hadley T.D., Batten M.P., Constanti‐Carey K., Barton T., Marley D., Mönch A., Lim K.S., Hill M.R., Scalability of Continuous Flow Production of Metal–Organic Frameworks, ChemSusChem, 9: 938-941 (2016).
[43] Gaab M., Trukhan N., Maurer S., Gummaraju R., Müller U., The Progression of Al-Based Metal-Organic Frameworks–from Academic Research to Industrial Production and Applications, Microporous and mesoporous materials, 157: 131-136 (2012).
[44] Oh H., Maurer S., Balderas-Xicohtencatl R., Arnold L., Magdysyuk O.V., Schütz G., Müller U., Hirscher M., Efficient Synthesis for Large-Scale Production and Characterization for Hydrogen Storage of Ligand Exchanged MOF-74/174/184-M (M= Mg2+, Ni2+), International Journal of Hydrogen Energy, 42: 1027-1035 (2017).
[45] Chakraborty D., Yurdusen A., Mouchaham G., Nouar F., Serre C., Large‐Scale Production of Metal–Organic Frameworks, Advanced Functional Materials, 2309089 (2023).
[46] Ren J., Dyosiba X., Musyoka N.M., Langmi H.W., Mathe M., Liao S., Review on the Current Practices and Efforts Towards Pilot-Scale Production of Metal-Organic Frameworks (MOFs), Coordination Chemistry Reviews, 352: 187-219 (2017).
[47] Silva P., Vilela S.M., Tome J.P., Paz F.A.A., Multifunctional Metal–Organic Frameworks: from Academia to Industrial Applications, Chemical Society Reviews, 44: 6774-6803 (2015).
[48] Reinsch H., Waitschat S., Chavan S.M., Lillerud K.P., Stock N., A Facile “Green” Route for Scalable Batch Production and Continuous Synthesis of Zirconium MOFs, European Journal of Inorganic Chemistry, 4490-4498 (2016).
[49] Quan Y., Parker T.F., Hua Y., Jeong H.-K., Wang Q., Process Elucidation and Hazard Analysis of the Metal–Organic Framework Scale-Up Synthesis: A Case Study of ZIF-8, Industrial & Engineering Chemistry Research, 62: 5035-5041 (2023).
[50] Deacon A., Briquet L., Malankowska M., Massingberd-Mundy F., Rudić S., Hyde T.L., Cavaye H., Coronas J., Poulston S., Johnson T., Understanding the ZIF-L to ZIF-8 Transformation from Fundamentals to Fully Costed Kilogram-Scale Production, Communications Chemistry, 5: 18 (2022).
[51] Polyzoidis A., Altenburg T., Schwarzer M., Löbbecke S., Kaskel S., Continuous Microreactor Synthesis of ZIF-8 With High Space–Time-Yield and Tunable Particle Size, Chemical Engineering Journal, 283: 971-977 (2016).
[52] He Y., Fu T., Wang L., Liu J., Liu G., Zhao H., Self-Assembly of MOF-801 Into Robust Hierarchically Porous Monoliths for Scale-Up Atmospheric Water Harvesting, Chemical Engineering Journal, 472: 144786 (2023).
[53] Zhao T., Jeremias F., Boldog I., Nguyen B., Henninger S.K., Janiak C., High-Yield, Fluoride-Free and Large-Scale Synthesis of MIL-101 (Cr), Dalton Transactions, 44: 16791-16801 (2015).
[54] McKinstry C., Cathcart R.J., Cussen E.J., Fletcher A.J., Patwardhan S.V., Sefcik J., Scalable Continuous Solvothermal Synthesis of Metal Organic Framework (MOF-5) Crystals, Chemical Engineering Journal, 285: 718-725 (2016).
[55] Lenzen D., Bendix P., Reinsch H., Fröhlich D., Kummer H., Möllers M., Hügenell P.P., Gläser R., Henninger S., Stock N., Scalable Green Synthesis and Full‐Scale Test of the Metal–Organic Framework CAU‐10‐H for use in Adsorption‐Driven Chillers, Advanced Materials, 30: 1705869 (2018).
[56] Nature Chemistry (Nat. Chem.), Frameworks for Commercial Success, (2016).
[57] MOF Technologies Ltd - an Exciting New Venture Created by Queen’s. https://www.qub.ac.uk/ Business/Case-studies/MOFTechnologiesLtd anexcitingnewventurecreatedbyqueens-1.html
[58] Casaban J., Zhang Y., Pacheco R., Coney C., Holmes C., Sutherland E., Hamill C., Breen J., James S.L., Tufano D., Towards MOFs’ Mass Market Adoption: MOF Technologies’ Efficient and Versatile One-Step Extrusion of Shaped MOFs Directly From Raw Materials, Faraday Discussions, 231: 312-325 (2021).
[59] Mottillo C., Friščić T., Carbon Dioxide Sensitivity of Zeolitic Imidazolate Frameworks, Angewandte Chemie, 126: 7601-7604 (2014).
[60] Chemical & Engineering News, )2017(. https://cen.acs.org/articles/95/i24/Round-two-MOF-commercialization.html.
[61] Oktavian R., Goeminne R., Glasby L.T., Song P., Huynh R., Qazvini O.T., Ghaffari-Nik O., Masoumifard N., Cordiner J.L., Hovington P., Gas Adsorption and Framework Flexibility of CALF-20 Explored Via Experiments and Simulations, Nature Communications, 15: 3898 (2024).
[62] BASF Company. https://www.basf.com
[63] Numat Technologies raises. https://www.pehub.com/numat-technologies-raises-12-4-mln/
[64] GOOSE Portfolio Co NuMat Receives $9M contract with US Army. https://goosesocietyoftexas.com/goose-portfolio-co-numat-receives-9m-contract-with-us-army/
[65] NuMat Technologies. https://pubs.acs.org/doi/pdf/10.1021/cen-09443-cover8
[66] NuMat Technologies Company. https://www.numat.com
[67] Yue T., Xia C., Liu X., Wang Z., Qi K., Xia B.Y., Design and Synthesis of Conductive Metal‐Organic Frameworks and Their Composites for Supercapacitors, ChemElectroChem, 8: 1021-1034 (2021).
[68] Kirchon A.A., Developing Commercially Scalable Iron and Titanium Metal-Organic Frameworks for Gas Storage and Water Purification, (2020).
[69] Lin R., Chai M., Zhou Y., Chen V., Bennett T.D., Hou J., Metal–Organic Framework Glass Composites, Chemical Society Reviews, 52: 4149-4172 (2023).
[70] Prajapati M., Singh V., Jacob M.V., Kant C.R., Recent Advancement in Metal-Organic Frameworks and Composites for High-Performance Supercapatteries, Renewable and Sustainable Energy Reviews, 183: 113509 (2023).
[71] Ryu U., Jee S., Rao P.C., Shin J., Ko C., Yoon M., Park K.S., Choi K.M., Recent Advances in Process Engineering and Upcoming Applications of Metal–Organic Frameworks, Coordination Chemistry Reviews, 426: 213544 (2021).
[72] Zhang K., Huo Q., Zhou Y.-Y., Wang H.-H., Li G.-P., Wang Y.-W., Wang Y.-Y., Textiles/Metal–Organic Frameworks Composites as Flexible air Filters for Efficient Particulate Matter Removal, ACS Applied Materials & Interfaces, 11: 17368-17374 (2019).
[73] Kim J.-O., Kim J.Y., Lee J.-C., Park S., Moon H.R., Kim D.-P., Versatile Processing of Metal–Organic Framework–Fluoropolymer Composite Inks with Chemical Resistance and Sensor Applications, ACS Applied Materials & Interfaces, 11: 4385-4392 (2019).
[74] Industry Analysis Metal-Organic-Frameworks-Market. https://www.gminsights.com/de/industry -analysis/metal-organic-frameworks-market.
[75] Teo W.L., Zhou W., Qian C., Zhao Y., Industrializing Metal–Organic Frameworks: Scalable Synthetic Means and Their Transformation Into Functional Materials, Materials Today, 47: 170-186 (2021).
[76] Severino M.I., Gkaniatsou E., Nouar F., Pinto M.L., Serre C., MOFs Industrialization: A Complete Assessment of Production Costs, Faraday Discussions, 231: 326-341 (2021).
[77] Metal-Organic-Framework-Market. https://www.coherentmarketinsights.com/industry-reports/ metal-organic-framework-market
[78] Ajdari F.B., Kowsari E., Shahrak M.N., Ehsani A., Kiaei Z., Torkzaban H., Ershadi M., Eshkalak S.K., Haddadi-Asl V., Chinnappan A., A Review on the field patents and Recent Developments Over the Application of Metal Organic Frameworks (MOFs) in Supercapacitors, Coordination Chemistry Reviews, 422: 213441 (2020).
[79] Global Metal-Organic Frameworks (MOF) Industry Research Report, Growth Trends and Competitive Analysis 2022-2028. https://www.giiresearch.com/report/qyr1175661-global-metal-organic-frameworks-mof-industry.html
[80] R&d Expenditure Ecosystem India. https://www.indiascienceandtechnology.gov.in/sites/default/ files/file-uploads/roadmaps/1571900991_R%26D%20book%20expenditure%20ecosystem.pdf
[81] Aritech Chemazone Pvt. Ltd. https://www.metalspowders.com/metal-organic-framework.htm
[82] Nik Zaiman N.F.H., Shaari N., Harun N.A.M., Developing Metal‐Organic Framework‐Based Composite for Innovative Fuel Cell Application: An Overview, International Journal of Energy Research, 46: 471-504 (2022).
[83] Insights G.M., Metal Organic Frameworks Market - By Product (Aluminum, Copper, Iron, Zinc, Magnesium), By Synthetic market (Hydrothermal, Microwave, ultrasonic, mechanochemical, electrochemical), By Application (catalyst, carbon capture) - Global Forecast to 2032, April 2023. https://www.gminsights.com/industry-analysis/metal-organic-frameworks-market.
[84] Metal-organic frameworks (MOF) market regional insights. https://www.businessresearchinsights.com/ market-reports/metal-organic-frameworks-mof-market-106717.
[85] Kianimehr A., Akhbari K., White J., Phuruangrat A., The Mechanochemical Conversion of Potassium Coordination Polymer Nanostructures to Interpenetrated Sodium Coordination Polymers with Halogen Bond, Metal–Carbon and Metal–Metal Interactions, CrystEngComm, 22: 888-894 (2020).
[86] Akhbari K., Karami S., Phuruangrat A., Saedi Z., Irreversible Replacement of Sodium with Thallium in Sodium Coordination Polymer Nanostructures by Solid-State Mechanochemical Cation Exchange Process, Journal of the Iranian Chemical Society, 15: 1327-1335 (2018).
[87] Mirzadeh E., Akhbari K., White J., Mechanochemical Conversion of Nano Potassium Hydrogen Terephthalate to Thallium Analogue Nanoblocks with Strong Hydrogen Bonding and Straight Chain Metalophillic Interactions, Applied Organometallic Chemistry, 32: e4313 (2018).
[88] Hasheminezhad M., Akhbari K., Phuruangrat A., Solid–Solid and Solid–Liquid Conversion of Sodium and Silver Nano Coordination Polymers, Polyhedron, 166: 115-122 (2019).
[89] Moeinian M., Akhbari K., Boonmak J., Youngme S., Similar to What Occurs in Biological Systems; Irreversible Replacement of Potassium with Thallium in Coordination Polymer Nanostructures, Polyhedron, 118: 6-11 (2016).
[90] Shirazi F.S., Akhbari K., Kawata S., Kanazashi K., Reversible Liquid Assisted Mechanochemical Conversion of Sodium Coordination Polymer Nanorods to Organosilver Coordination Polymer Nanosheets, Inorganic Chemistry Communications, 74: 31-34 (2016).
[91] Karimi Alavijeh R., Akhbari K., Tylianakis E., Froudakis G.E., White J.M., Two-Fold Homointerpenetrated Metal–Organic Framework with the Potential for Anticancer Drug Loading using Computational Simulations, Crystal Growth & Design, 21: 6402-6410 (2021).
[92] Karimi Alavijeh R., Akhbari K., Bernini M.C., Garcia Blanco A.A., White J.M., Design of Calcium-Based Metal–Organic Frameworks by the Solvent Effect and Computational Investigation of Their Potential as Drug Carriers, Crystal Growth & Design, 22: 3154-3162 (2022).
[93] Munn A., Dunne P.W., Tang S., Lester E., Large-Scale Continuous Hydrothermal Production and Activation of ZIF-8, Chemical Communications, 51: 12811-12814 (2015).
[94] Karadeniz B., Howarth A.J., Stolar T., Islamoglu T., Dejanović I., Tireli M., Wasson M.C., Moon S.-Y., Farha O.K., Friščić T., Benign by Design: Green and Scalable Synthesis of Zirconium UiO-Metal–Organic Frameworks by Water-Assisted Mechanochemistry, ACS Sustainable Chemistry & Engineering, 6: 15841-15849 (2018).
[95] Mueller U., Schubert M., Teich F., Puetter H., Schierle-Arndt K., Pastre J., Metal–Organic Frameworks—Prospective Industrial Applications, Journal of Materials Chemistry, 16: 626-636 (2006).
[96] Taddei M., Steitz D.A., van Bokhoven J.A., Ranocchiari M., Continuous‐Flow Microwave Synthesis of Metal–Organic Frameworks: A Highly Efficient Method for Large‐Scale Production, Chemistry–A European Journal, 22: 3245-3249 (2016).
[97] Cho H.-Y., Kim J., Kim S.-N., Ahn W.-S., High Yield 1-L Scale Synthesis of ZIF-8 via a Sonochemical Route, Microporous and Mesoporous Materials, 169: 180-184 (2013).
[98] Metal-Organic-Frameworks-Market. https://www.gminsights.com/de/industry-analysis/metal-organic-frameworks-market.
[99] Cortés P.H., Macías S.R., “Metal-Organic Frameworks in Biomedical and Environmental Field”, Springer, (2021).
[100] Bayliss P.A., Ibarra I.A., Pérez E., Yang S., Tang C.C., Poliakoff M., Schröder M., Synthesis of Metal–Organic Frameworks by Continuous Flow, Green Chemistry, 16: 3796-3802 (2014).
[101] Dunne P.W., Lester E., Walton R.I., Towards Scalable and Controlled Synthesis of Metal–Organic Framework Materials using Continuous Flow Reactors, Reaction Chemistry & Engineering, 1: 352-360 (2016).
[102] Batten M.P., Rubio-Martinez M., Hadley T., Carey K.-C., Lim K.-S., Polyzos A., Hill M.R., Continuous flow Production of Metal-Organic Frameworks, Current Opinion in Chemical Engineering, 8: 55-59 (2015).
[103] Freitas C.T., Severino M.I.S., Mohtar A.A., Kolmykov O., Pimenta V., Nouar F., Serre C., Pinto M., Metal–Organic Frameworks Polyurethane Composite Foams for the Capture of Volatile Organic Compounds, ACS Materials Letters, 6: 174-181 (2023).
[104] Cui X., Sun X., Liu L., Huang Q., Yang H., Chen C., Nie S., Zhao Z., Zhao Z., In-Situ Fabrication of Cellulose Foam HKUST-1 and Surface Modification with Polysaccharides for Enhanced Selective Adsorption of Toluene and Acidic Dipeptides, Chemical Engineering Journal, 369: 898-907 (2019).
[105] Li D., Xu H.-Q., Jiao L., Jiang H.-L., Metal-Organic Frameworks for Catalysis: State of the Art, Challenges, and Opportunities, EnergyChem, 1: 100005 (2019).
[106] Shen Y., Pan T., Wang L., Ren Z., Zhang W., Huo F., Programmable Logic in Metal–Organic Frameworks for Catalysis, Advanced Materials, 33: 2007442 (2021).
[107] Hou C.-C., Wang H.-F., Li C., Xu Q., From Metal–Organic Frameworks to Single/Dual-Atom and Cluster Metal Catalysts for Energy Applications, Energy & Environmental Science, 13: 1658-1693 (2020).
[108] Wei Y.-S., Zhang M., Zou R., Xu Q., Metal–Organic Framework-Based Catalysts with Single Metal Sites, Chemical Reviews, 120: 12089-12174 (2020).
[109] Akbarian M., Sanchooli E., Oveisi A.R., Daliran S., Choline Chloride-Coated UiO-66-Urea MOF: A Novel Multifunctional Heterogeneous Catalyst for Efficient One-Pot Three-Component Synthesis of 2-Amino-4H-Chromenes, Journal of Molecular Liquids, 325: 115228 (2021).
[110] Farshchi M.E., Bozorg N.M., Ehsani A., Aghdasinia H., Chen Z., Rostamnia S., Ni B.-J., Green Valorization of PET Waste into Functionalized Cu-MOF Tailored to Catalytic Reduction of 4-Nitrophenol, Journal of Environmental Management, 345: 118842 (2023).
[111] Akhbari K., Morsali A., Modulating Methane Storage in Anionic Nano-Porous MOF Materials Via Post-Synthetic Cation Exchange Process, Dalton Transactions, 42: 4786-4789 (2013).
[112] Akhbari K., Morsali A., Needle-Like Hematite Nano-Structure Prepared by Directed Thermolysis of MIL-53 Nano-Structure with Enhanced Methane Storage Capacity, Materials Letters, 141: 315-318 (2015).
[113] Osterrieth J.W., Fairen‐Jimenez D., Metal–Organic Framework Composites for Theragnostics and Drug Delivery Applications, Biotechnology Journal, 16: 2000005 (2021).
[114] Xiang S., He Y., Zhang Z., Wu H., Zhou W., Krishna R., Chen B., Microporous Metal-Organic Framework with Potential for Carbon Dioxide Capture at Ambient Conditions, Nature Communications, 3: 954 (2012).
[115] Hu Z., Wang Y., Shah B.B., Zhao D., CO2 Capture in Metal–Organic Framework Adsorbents: An Engineering Perspective, Advanced Sustainable Systems, 3: 1800080 (2019).
[116] Zhang L., Song Y., Shi J., Shen Q., Hu D., Gao Q., Chen W., Kow K.-W., Pang C., Sun N., Frontiers of CO2 Capture and Utilization (CCU) Towards Carbon Neutrality, Advances in Atmospheric Sciences, 39: 1252-1270 (2022).
[117] Yan X.-W., Bigdeli F., Abbasi-Azad M., Wang S.-J., Morsali A., Selective Separation of CO2/CH4 Gases by Metal-Organic Framework-Based Composites, Coordination Chemistry Reviews, 520: 216126 (2024).
[118] Cheng L., Dang Y., Wang Y., Chen K., Recent Advances in Metal-Organic Frameworks for Water Absorption and their Applications, Materials Chemistry Frontiers, (2024).
[119] Daliran S., Oveisi A.R., Kung C.-W., Sen U., Dhakshinamoorthy A., Chuang C.-H., Khajeh M., Erkartal M., Hupp J.T., Defect-Enabling Zirconium-Based Metal–Organic Frameworks for Energy and Environmental Remediation Applications, Chemical Society Reviews, (2024).
[120] Chen Y., Lv D., Wu J., Xiao J., Xi H., Xia Q., Li Z., A new MOF-505@ GO Composite with High Selectivity for CO2/CH4 and CO2/N2 Separation, Chemical Engineering Journal, 308: 1065-1072 (2017).
[121] Chen Y., Wu H., Xiao Q., Lv D., Li F., Li Z., Xia Q., Rapid Room Temperature Conversion of Hydroxy Double Salt to MOF-505 for CO2 Capture, CrystEngComm, 21: 165-171 (2019).
[122] Ren Y.-B., Xu H.-Y., Gang S.-Q., Gao Y.-J., Jing X., Du J.-L., An Ultra-Stable Zr (IV)-MOF for Highly Efficient Capture of SO2 from SO2/CO2 and SO2/CH4 Mixtures, Chemical Engineering Journal, 431: 134057 (2022).
[123] Kaur G., Bhardwaj H., Kamal, Sharma A., Sud D., Review on Functionalized Metal–Organic Framework as Potential Candidate for Carbon Control Technologies for Climate Change: Current Status and Future Prospective, Clean Technologies and Environmental Policy, 1-25 (2024).
[124] Piscopo C.G., Loebbecke S., Strategies to Enhance Carbon Dioxide Capture in Metal‐Organic Frameworks, ChemPlusChem, 85: 538-547 (2020).
[125] Alavijeh R.K., Akhbari K., White J., Solid–Liquid Conversion and Carbon Dioxide Storage in a Calcium-Based Metal–Organic Framework with Micro-and Nanoporous Channels, Crystal Growth & Design, 19: 7290-7297 (2019).
[126] Salimi S., Akhbari K., Farnia S.M.F., White J.M., Multiple Construction of a Hierarchical Nanoporous Manganese (II)-Based Metal–Organic Framework with Active Sites for Regulating N2 and CO2 Trapping, Crystal Growth & Design, 22: 1654-1664 (2022).
[127] Parsaei M., Akhbari K., White J., Modulating Carbon Dioxide Storage by Facile Synthesis of Nanoporous Pillared-Layered Metal–Organic Framework with Different Synthetic Routes, Inorganic Chemistry, 61: 3893-3902 (2022).
[128] Salimi S., Farnia S.M.F., Akhbari K., Tavasoli A., Engineered Catalyst Based on MIL-68 (Al) with High Stability for Hydrogenation of Carbon Dioxide and Carbon Monoxide at Low Temperature, Inorganic Chemistry, 62: 17588-17601 (2023).
[129] NETL Project Review Includes Updates on Carbon Capture, 2021. https://netl.doe.gov/sites/ default/files/publication/NETL-September-2021-Carbon-Capture-Newsletter.pdf
[130] Case Study: Carbon Capture, https://info.novomof.com/cs-carbon-capture.
[131] Heymans N., Duprez M.-E., De Weireld G., MOF4AIR Project (H2020): Metal Organic Frameworks for Carbon Dioxide Adsorption Processes in Power Production and Energy Intensive Industries, (2021).
[132] MOF4AIR Project, https://www.mof4air.eu/.
[133] Mosaic Materials Capturing CO2 directly from the atmosphere, https://pubs.acs.org/ doi/10.1021/cen-09744-cover6.
[134] Lin J.-B., Nguyen T.T., Vaidhyanathan R., Burner J., Taylor J.M., Durekova H., Akhtar F., Mah R.K., Ghaffari-Nik O., Marx S., A Scalable Metal-Organic Framework as a Durable Physisorbent for Carbon Dioxide Capture, Science, 374: 1464-1469 (2021).
[135] Lively R.P., Sholl D., Walton K., Realff M., Kawajiri Y., DeWitt S., Park J., Rubiera Landa H., Carter E., Enabling 10mol/kg Swing Capacity via Heat Integrated Sub-ambient Pressure Swing Adsorption, Georgia Institute of Technology, Atlanta, GA (United States), (2019).
[136] Squair Tech-Solve Indoor Air Quality Problems, https://squair.tech/.
[137] Zhao D., Wang X., Yue L., He Y., Chen B., Porous Metal–Organic Frameworks for Hydrogen Storage, Chemical Communications, 58: 11059-11078 (2022).
[138] Chen Z., Li P., Anderson R., Wang X., Zhang X., Robison L., Redfern L.R., Moribe S., Islamoglu T., Gómez-Gualdrón D.A., Balancing Volumetric and Gravimetric Uptake in Highly Porous Materials for Clean Energy, Science, 368: 297-303 (2020).
[139] Bakuru V.R., DMello M.E., Kalidindi S.B., Metal‐Organic Frameworks for Hydrogen Energy Applications: Advances and Challenges, ChemPhysChem, 20: 1177-1215 (2019).
[140] Ahmed A., Seth S., Purewal J., Wong-Foy A.G., Veenstra M., Matzger A.J., Siegel D.J., Exceptional Hydrogen Storage Achieved by Screening Nearly Half a Million Metal-Organic Frameworks, Nature communications, 10: 1568 (2019).
[141] Musyoka N.M., Ren J., Langmi H.W., North B.C., Mathe M., Bessarabov D., Synthesis of rGO/Zr-MOF Composite for Hydrogen Storage Application, Journal of Alloys and Compounds, 724: 450-455 (2017).
[142] Molefe L.Y., Musyoka N.M., Ren J., Langmi H.W., Mathe M., Ndungu P.G., Effect of Inclusion of MOF-Polymer Composite Onto a Carbon foam Material for Hydrogen Storage Application, Journal of Inorganic and Organometallic Polymers and Materials, 31: 80-88 (2021).
[143] DeSantis D., Mason J.A., James B.D., Houchins C., Long J.R., Veenstra M., Techno-Economic Analysis of Metal–Organic Frameworks for Hydrogen and Natural Gas Storage, Energy & Fuels, 31: 2024-2032 (2017).
[144] Staffell I., Scamman D., Abad A.V., Balcombe P., Dodds P.E., Ekins P., Shah N., Ward K.R., The Role of Hydrogen and Fuel Cells in the Global Energy System, Energy & Environmental Science, 12: 463-491 (2019).
[145] Gómez-Gualdrón D.A., Wang T.C., García-Holley P., Sawelewa R.M., Argueta E., Snurr R.Q., Hupp J.T., Yildirim T., Farha O.K., Understanding Volumetric and Gravimetric Hydrogen Adsorption Trade-Off in Metal–Organic Frameworks, ACS applied Materials & Interfaces, 9: 33419-33428 (2017).
[146] Jun Yang A.P., Hirano S., Hydrogen Storage Materials in: L. Assigned to Ford global technologies (Ed.), )2011(.
[147] Andrea Pulskamp J.Y., Siegel D.J., Veenstra M.J., Hybrid Hydrogen Storage System and Method Using the Same, in: L. Assigned to Ford global technologies (Ed.), (2010).
[148] Hydrogen Production MOF Technologies Company, https://www.coherentmarketinsights.com/ industry-reports/metal-organic-framework-market.
[149] Tu T.N., Ngo L.H., Nguyen T.T., Metal-Organic Frameworks as Adsorbents for Onboard Fuel Storage, Reticul. Chem. Appl. De Gruyter, 721-008 (2023).
[150] Peng Y., Krungleviciute V., Eryazici I., Hupp J.T., Farha O.K., Yildirim T., Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges, Journal of the American Chemical Society, 135: 11887-11894 (2013).
[151] Chen S., Li X., Duan J., Fu Y., Wang Z., Zhu M., Li N., Investigation of Highly Efficient Adsorbent Based on Ni-MOF-74 in the Separation of CO2 from Natural Gas, Chemical Engineering Journal, 419: 129653 (2021).
[152] Atomis, Inc, 2022, https://www.atomis.co.jp/en/.
[153] In Japan, Start-Up Culture is Starting to Emerge, C&EN Global Enterprise, 100: 23-24 (2022).
[154] Green Science Alliance Co., Ltd, https://www.gsalliance.co.jp/?lang=en.
[155] Dhakshinamoorthy A., Alvaro M., Garcia H., Commercial Metal–Organic Frameworks as Heterogeneous Catalysts, Chemical Communications, 48: 11275-11288 (2012).
[156] Ascensus Specialties Acquires Strem Chemicals, https://www.ascensusspecialties.com/news-article/ascensus-specialties-acquires-strem-chemicals.
[157]  Adamas Tech, https://adamastech.in/our-services/technology-architecture/.
[158] Persistence: Metal-organic Frameworks Market, https://www.persistencemarketresearch.com/ market-research/metal-organic-frameworks-market.asp.
[159] Shinde P.A., Abdelkareem M.A., Sayed E.T., Elsaid K., Olabi A.G., Metal Organic Frameworks (MOFs) in Supercapacitors, Encyclopedia of Smart Materials, Elsevier, 414-423 (2021).
[160] Sundriyal S., Kaur H., Bhardwaj S.K., Mishra S., Kim K.-H., Deep A., Metal-Organic Frameworks and Their Composites as Efficient Electrodes for Supercapacitor Applications, Coordination Chemistry Reviews, 369: 15-38 (2018).
[161] Zhao W., Yan G., Zheng Y., Liu B., Jia D., Liu T., Cui L., Zheng R., Wei D., Liu J., Bimetal-Organic Framework Derived Cu (NiCo)2S4/Ni3S4 Electrode Material with Hierarchical Hollow Heterostructure for High Performance Energy Storage, Journal of Colloid and Interface Science, 565: 295-304 (2020).
[162] Wang L., Han Y., Feng X., Zhou J., Qi P., Wang B., Metal–Organic Frameworks for Energy Storage: Batteries and Supercapacitors, Coordination Chemistry Reviews, 307: 361-381 (2016).
[163] Tan B., Wu Z.-F., Xie Z.-L., Fine Decoration of Carbon Nanotubes with Metal Organic Frameworks for Enhanced Performance in Supercapacitance and Oxygen Reduction Reaction, Science Bulletin, 62: 1132-1141 (2017).
[164] Arnó J., Farha O.K., Morris W., Siu P.W., Tom G.M., Weston M.H., Fuller P.E., Dopant Gas Purity and Adsorbent Stability, MRS Advances, 7: 1426-1430 (2022).
[165] Arnó J., Farha O., Morris W., Siu P., Tom G., Weston M., Fuller P., ION-X Dopant Gas Delivery System Performance Characterization at Axcelis, 2018 22nd International Conference on Ion Implantation Technology (IIT), IEEE, 227-230 ( 2018).
[166] Arnó J., Farha O., Morris W., Siu P., Tom G., Weston M., Fuller P., McCabe J., Ameen M., Next Generation Dopant Gas Delivery System for Ion Implant Applications, Solid State Technology, 27-30 (2018).
[167] Kerkel K., Arnó J., Reichl G., Feicht J., Winzig H., Farha O., Morris W., Siu P., Tom G., Weston M., Evaluation of ION-X® Hydride Dopant Gas Sources on a Varian VIISion High Current Implanter, 22nd International Conference on Ion Implantation Technology (IIT), IEEE, 223-226 (2018).
[168] EnergyX and ProfMOF, Companies, 2020, https://www.greyb.com/blog/battery-recycling-startups/.
[169] Gordeeva L., Aristov Y., Adsorbent Coatings For Adsorption Heat Transformation: From Synthesis To Application, Energies, 15: 7551 (2022).
[170] Basolite M050, https://www.coherentmarketinsights.com/industry-reports/metal-organic-framework-market/market-news.
[171] Parsaei M., Akhbari K., Tylianakis E., Froudakis G.E., Effects of Fluorinated Functionalization of Linker on Quercetin Encapsulation, Release and Hela Cell Cytotoxicity of Cu‐Based MOFs as Smart pH‐Stimuli Nanocarriers, Chemistry–A European Journal, 30: e202301630 (2024).
[172] Alavijeh R.K., Akhbari K., Improvement of Curcumin Loading Into a Nanoporous Functionalized Poor Hydrolytic Stable Metal-Organic Framework for High Anticancer Activity Against Human Gastric Cancer AGS Cells, Colloids and Surfaces B: Biointerfaces, 212: 112340 (2022).
[173] Soltani S., Akhbari K., Phuruangrat A., Improved Antibacterial Activity by Incorporation of Silver Sulfadiazine on Nanoporous Cu-BTC Metal-Organic-Framework, Inorganica Chimica Acta, 543: 121182 (2022).
[174] Parsaei M., Akhbari K., MOF-801 as a Nanoporous Water-Based Carrier System for in Situ Encapsulation and Sustained Release of 5-FU for Effective Cancer Therapy, Inorganic Chemistry, 61: 5912-5925 (2022).
[175] Parsaei M., Akhbari K., Smart Multifunctional UiO-66 Metal–Organic Framework Nanoparticles with Outstanding Drug-Loading/Release Potential for the Targeted Delivery of Quercetin, Inorganic Chemistry, 61: 14528-14543 (2022).
[176] Karimi Alavijeh R., Akhbari K., Biocompatible MIL-101 (Fe) as a Smart Carrier with High Loading Potential and Sustained Release of Curcumin, Inorganic Chemistry, 59: 3570-3578 (2020).
[177] Parsaei M., Akhbari K., Synthesis and Application of MOF-808 Decorated with Folic Acid-Conjugated Chitosan as a Strong Nanocarrier for the Targeted Drug Delivery of Quercetin, Inorganic Chemistry, 61: 19354-19368 (2022).
[178] Kalati M., Akhbari K., Optimizing the Metal Ion Release and Antibacterial Activity of ZnO@ ZIF-8 by Modulating Its Synthesis Method, New Journal of Chemistry, 45: 22924-22931 (2021).
[179] Soltani S., Akhbari K., Embedding an Extraordinary Amount of Gemifloxacin Antibiotic
in ZIF-8 Framework with One-Step Synthesis and Measurement of Its H2O2-Sensitive Release and Potency Against Infectious Bacteria, New Journal of Chemistry, 46: 19432-19441 (2022).
[180] Soltani S., Akhbari K., Cu-BTC metal–Organic Framework as a Biocompatible Nanoporous Carrier for Chlorhexidine Antibacterial Agent, Journal of Biological Inorganic Chemistry (JBIC), 1-7 (2022).
[181] Metal Organic Frameworks Market Forecast 2024 – 2032, https://www.gminsights.com/ industry-analysis/metal-organic-frameworks-market.
[182] Terzopoulou A., Nicholas J.D., Chen X.-Z., Nelson B.J., Pane S., Puigmarti-Luis J., Metal–Organic Frameworks in Motion, Chemical Reviews, 120: 11175-11193 (2020).
[183] Terzopoulou A., Wang X., Chen X.Z., Palacios‐Corella M., Pujante C., Herrero‐Martín J.,
Qin X.H., Sort J., de Mello A.J., Nelson B.J., Biodegradable Metal–Organic Framework‐Based Microrobots (MOFBOTs), Advanced Healthcare Materials, 9: 2001031 (2020).
[184] Zhang L.T., Zhou Y., Han S.T., The Role of Metal–Organic Frameworks in Electronic Sensors, Angewandte Chemie, 133: 15320-15340, (2021).
[185] Fang X., Zong B., Mao S., Metal–Organic Framework-Based Sensors for Environmental Contaminant Sensing, Nano-micro Letters, 10: 1-19 (2018).
[186] Kajal N., Singh V., Gupta R., Gautam S., Metal Organic Frameworks for Electrochemical Sensor Applications: A Review, Environmental Research, 204: 112320 (2022).
[187] Qiu Q., Chen H., Wang Y., Ying Y., Recent Advances in the Rational Synthesis and Sensing Applications of Metal-Organic Framework Biocomposites, Coordination Chemistry Reviews, 387: 60-78 (2019).
[188] Wang X., Wang Y., Ying Y., Recent Advances in Sensing Applications of Metal Nanoparticle/Metal–Organic Framework Composites, TrAC Trends in Analytical Chemistry, 143: 116395 (2021).
[189] Amini A., Kazemi S., Safarifard V., Metal-Organic Framework-Based Nanocomposites for Sensing Applications–A Review, Polyhedron, 177: 114260 (2020).
[190] Pal T.K., Metal–Organic Framework (MOF)-Based Fluorescence “Turn-on” Sensors, Materials Chemistry Frontiers, 7: 405-441 (2023).
[191] Sales M.B., Neto J.G.L., De Sousa Braz A.K., De Sousa Junior P.G., Melo R.L.F., Valério R.B.R., Serpa J.d.F., Da Silva Lima A.M., De Lima R.K.C., Guimarães A.P., Trends and Opportunities in Enzyme Biosensors Coupled to Metal-Organic Frameworks (MOFs): An Advanced Bibliometric Analysis, Electrochem, 4: 181-211 (2023).
[192] Metal-Organic-Framework-Market Industry Reports Avantama Nanotechnology, https://www.coherentmarketinsights.com/industry-reports/metal-organic-framework-market
[193] Matrixsensors, https://www.explorium.ai/manufacturing/companies/matrix-sensors
[194] Dalstein O., Ceratti D.R., Boissière C., Grosso D., Cattoni A., Faustini M., Nanoimprinted, Submicrometric, MOF‐Based 2D Photonic Structures: Toward Easy Selective Vapors Sensing by a Smartphone Camera, Advanced Functional Materials, 26: 81-90 (2016).
[195] Kim M.L., Otal E.H., Kimura M., Open Access Fluoride Sensor for Water Quality Assessment: Smartphone Based Sensor and Data Transfer using MOFs as Sensing Materials, IFAC-PapersOnLine, 56: 4657-4662 (2023).
[196] Zhong Y., Zheng X.T., Li Q.-l., Loh X.J., Su X., Zhao S., Antibody Conjugated Au/Ir@ Cu/Zn-MOF Probe for Bacterial Lateral flow Immunoassay and Precise Synergistic Antibacterial treatment, Biosensors and Bioelectronics, 224: 115033 (2023).
[197] Adeel M., Asif K., Rahman M.M., Daniele S., Canzonieri V., Rizzolio F., Glucose Detection Devices and Methods Based on Metal–Organic Frameworks and Related Materials, Advanced Functional Materials, 31: 2106023 (2021).
[198] Tu Y., Wang R., Zhang Y., Wang J., Progress and Expectation of Atmospheric Water Harvesting, Joule, 2: 1452-1475 (2018).
[199] Hanikel N., Prévot M.S., Yaghi O.M., MOF Water Harvesters, Nature Nanotechnology, 15: 348-355 (2020).
[200] WaHab, WaHa, a new Solution Selected by WEF-CAP to Extract Water from the Atmosphere, (2024), https://www.enicbcmed.eu/waha-new-solution-selected-wef-cap-extract-water-atmosphere.
[201] Xu W., Yaghi O.M., Metal–Organic Frameworks for Water Harvesting from Air, Anywhere, Anytime, ACS Central Science, 6: 1348-1354 (2020).
[202] Zheng Z., Nguyen H.L., Hanikel N., Li K.K.-Y., Zhou Z., Ma T., Yaghi O.M., High-Yield, Green And Scalable Methods For Producing MOF-303 For Water Harvesting From Desert Air, Nature Protocols, 18: 136-156 (2023).
[203] Solovyeva M.V., Shkatulov A.I., Gordeeva L.G., Fedorova E.A., Krieger T.A., Aristov Y.I., Water Vapor Adsorption on CAU-10-X: Effect of Functional Groups on Adsorption Equilibrium and Mechanisms, Langmuir, 37: 693-702 (2021).
[204] Water Harvesting, https://novomof.com/technology/water-harvesting.
[205] Almassad H.A., Abaza R.I., Siwwan L., Al-Maythalony B., Cordova K.E., Environmentally Adaptive MOF-Based Device Enables Continuous Self-Optimizing Atmospheric Water Harvesting, Nature Communications, 13: 4873 (2022).
[206] Berkeley M.P.U., Aluminium Makes Water-Harvesting MOF, https://www.chemistryworld.com/ news/aluminium-makes-water-harvesting-mof-10-times-thirstier/3010974.article
[207] Sani M.A., Khezerlou A., Tavassoli M., Abedini A.H., McClements D.J., Development of Sustainable UV-Screening Food Packaging Materials: A Review of Recent Advances, Trends in Food Science & Technology,104366 (2024).
[208] Zhang Y., Min T., Zhao Y., Cheng C., Yin H., Yue J., The Developments and Trends of Electrospinning Active Food Packaging: A Review and Bibliometrics Analysis, Food Control, 110291 (2024).
[209] Cheng J., Gao R., Zhu Y., Lin Q., Applications of Biodegradable Materials in Food Packaging: A Review, Alexandria Engineering Journal, 91: 70-83 (2024).
[210] Raveena, Kumari P., Nanocellulose@ Gallic Acid-Based MOFs: A Novel Material for Ecofriendly Food Packaging, ACS Omega, (2024).
[211] Rubio-Martinez M., Avci-Camur C., Thornton A.W., Imaz I., Maspoch D., Hill M.R., New Synthetic Routes Towards MOF Production at Scale, Chemical Society Reviews, 46: 3453-3480 (2017).
[212] First Commercial PCP/MOF Product, https://www.icems.kyoto-u.ac.jp/en/more/scope/pcp/
[213] Merck KGaA, Darmstadt, Germany Press Release, https://www.emdgroup.com/investors/ reports-and-financials/earnings-materials/2020-q1/us/2020-Q1-Press-Release-NA.pdf.
[214] Merck-KGaA-Darmstadt-Germany, https://www.selectscience.net/company/merck-kgaa-darmstadt- germany.
[215] Du Q., Peng J., Wu P., He H., Metal-Organic Framework Based Crystalline Sponge Method for Structure Analysis, TrAC Trends in Analytical Chemistry, 102: 290-310 (2018).
[216] Rosenberger L.A., Application of the Crystalline Sponge Method for Metabolite Structure Elucidation, (2022).
[217] Rosenberger L., von Essen C., Khutia A., Kühn C., Georgi K., Hirsch A.K., Hartmann R.W., Badolo L., Crystalline Sponge Affinity Screening: A Fast Tool for Soaking Condition Optimization Without the Need of X-Ray Diffraction Analysis, European Journal of Pharmaceutical Sciences, 164: 105884 (2021).
[218] RiMO Therapeutics, https://news.uchicago.edu/story/uchicago-rimo-therapeutics-complete-first-ucgo-startup-license.
[219] Julien P.A., Mottillo C., Friščić T., Metal–Organic Frameworks Meet Scalable and Sustainable Synthesis, Green Chemistry, 19: 2729-2747 (2017).
[220] Allendorf M.D., Schwartzberg A., Stavila V., Talin A.A., A Roadmap to Implementing Metal–Organic Frameworks in Electronic Devices: Challenges and Critical Directions, Chemistry–A European Journal, 17: 11372-11388 (2011).
[221] Hendon C.H., Rieth A.J., Korzynski M.D., Dinca M., Grand Challenges and Future Opportunities for Metal–Organic Frameworks, ACS Central Science, 3: 554-563 (2017).
[222] Bull O.S., Bull I., Amadi G.K., Odu C.O., Okpa E., A Review on Metal-Organic Frameworks (MOFs), Synthesis, Activation, Characterisation, and Application, Oriental Journal of Chemistry, 38: 490 (2022).
[223] Horcajada P., Gref R., Baati T., Allan P.K., Maurin G., Couvreur P., Férey G., Morris R.E., Serre C., Metal–Organic Frameworks in Biomedicine, Chemical Reviews, 112: 1232-1268 (2012).
[224] Assen A.H., Adil K., Belmabkhout Y., Lab-Scale Insights into Green Metal-Organic Framework Sorbents for Gas Separation or Purification, Current Opinion in Green and Sustainable Chemistry, 100948 (2024).
[225] Curran M.A., Life Cycle Assessment: A Review of the Methodology and Its Application to Sustainability, Current Opinion in Chemical Engineering, 2: 273-277 (2013).
[226] Reinsch H., “Green” Synthesis of Metal‐Organic Frameworks, European Journal of Inorganic Chemistry, 4290-4299 (2016).
[227] Vardhan H., Rummer G., Deng A., Ma S., Large-Scale Synthesis of Covalent Organic Frameworks: Challenges and Opportunities, Membranes, 13: 696 (2023).
[228] Chen J., Shen K., Li Y., Greening the Processes of Metal–Organic Framework Synthesis and Their use in Sustainable Catalysis, ChemSusChem, 10: 3165-3187 (2017).
[229] Liu X., Verma G., Chen Z., Hu B., Huang Q., Yang H., Ma S., Wang X., Metal-Organic Framework Nanocrystal-Derived Hollow Porous Materials: Synthetic Strategies and Emerging Applications, The Innovation, 3: (2022).
[230] Permyakova A., Skrylnyk O., Courbon E., Affram M., Wang S., Lee U.H., Valekar A.H., Nouar F., Mouchaham G., Devic T., Synthesis Optimization, Shaping, and Heat Reallocation Evaluation of the Hydrophilic Metal–Organic Framework MIL‐160 (Al), ChemSusChem, 10: 1419-1426 (2017).
[231] Damasceno Borges D., Normand P., Permiakova A., Babarao R., Heymans N., Galvao D.S., Serre C., De Weireld G., Maurin G., Gas Adsorption and Separation by the Al-Based Metal–Organic Framework MIL-160, The Journal of Physical Chemistry C, 121: 26822-26832 (2017).
[232] Dapaah M.F., Liu B., Recent Advances of Supercritical CO2 in Green Synthesis and Activation of Metal–Organic Frameworks, Journal of Inorganic and Organometallic Polymers and Materials, 30: 581-595 (2020).
[233] Matsuyama K., Supercritical Fluid Processing for Metal–Organic Frameworks, Porous Coordination Polymers, and Covalent Organic Frameworks, The Journal of Supercritical Fluids, 134: 197-203 (2018).
[234] He Y.-P., Tan Y.-X., Zhang J., Comparative Study of Activation Methods on Tuning Gas Sorption Properties of a Metal–Organic Framework with Nanosized Ligands, Inorganic Chemistry, 51: 11232-11234 (2012).
[235] Freund R., Zaremba O., Arnauts G., Ameloot R., Skorupskii G., Dincă M., Bavykina A., Gascon J., Ejsmont A., Goscianska J., The Current Status of MOF and COF Applications, Angewandte Chemie International Edition, 60: 23975-24001 (2021).
[236] Fu J., Wu Y.n., A Showcase of Green Chemistry: Sustainable Synthetic Approach of Zirconium‐Based MOF Materials, Chemistry–A European Journal, 27: 9967-9987 (2021).
[237] Mahmud R., Moni S.M., High K., Carbajales-Dale M., Integration of Techno-Economic Analysis and Life Cycle Assessment for Sustainable Process Design–A Review, Journal of Cleaner Production, 317: 128247 (2021).
[238] Shi Z., Yuan X., Yan Y., Tang Y., Li J., Liang H., Tong L., Qiao Z., Techno-Economic Analysis of Metal–Organic Frameworks for Adsorption Heat Pumps/Chillers: From Directional Computational Screening, Machine Learning to Experiment, Journal of Materials Chemistry A, 9: 7656-7666 (2021).
[239] Liu X.-M., Xie L.-H., Wu Y., Recent Advances in the Shaping of Metal–Organic Frameworks, Inorganic Chemistry Frontiers, 7: 2840-2866 (2020).
[240] Ma Q., Zhang T., Wang B., Shaping of Metal-Organic Frameworks, A Critical Step Toward Industrial Applications, Matter, 5: 1070-1091 (2022).