Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Preparation of Aluminum Pillared Interlayered Clays (Al-PILC) and Investigation of the Effect of pH During Intercalation

Document Type : Research Article

Authors
Majid Tahmooresi
Fariba Jafari
Department of New Materials, Research Institute of Materials, Graduate University of Advanced Technology, Kerman, I.R. IRAN
Abstract
In this study, firstly bentonite from Tang-e Quchan mine was collected, and its montmorillonite content was mostly separated from impurities. Montmorillonite was used in the synthesis of Al-PILC to investigate the influence of pH during the intercalation process on properties of pillared clays. The pH of intercalation was initially 4.1, and Al/Clay ratio was determined 4 mmole/g clay. The pH of the intercalation stage was changed by adding some droplets of dilute hydrochloric acid. Al-PILCs were heated at 400 °C and were characterized using X-ray diffraction and adsorption/desorption isotherms of nitrogen. The results showed that at pH values between 3.7 and 4.1, Al-PILCs had an acceptable basal spacing and surface area. The highest surface area and the basal spacings were 18.04 0A and 160 m2/g, respectively which was obtained for pillared interlayered clay with intercalated pH of 3.8
Keywords
Bentonite
Montmorillonite
Al-pillared clay
pH
Intercalation

Subjects

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