Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

High-pressure viscosities of fatty acid esters and biodiesels from a new thermodynamic model

Document Type : Research Article

Authors
Seyed Mostafa Hosseini 1
Mahsa Taghizadehfard 2
mohammad mehdi alavianmehr 2
1 Department of Chemistry, University of Hormozgan, Bandar Abbas, Iran
2 Department of Chemistry, Shiraz University of Technology, Shiraz, Iran
Abstract
This work deals with the modeling of dynamic viscosities of several fatty acid esters (FAEs) and biodiesels based on the friction theory (FT) along with a perturbed hard-dimer-chain equation of state (PHDC EOS). The model used three molecular parameters (ε, σ, m) and liquid density as well, all of which were estimated from the PHDC EOS. The PHDC EOS could predict the density and isothermal compressibility coefficients in 278.15-393.15 K range and pressures up to 210 MPa with the average absolute relative deviations (AARDs) of 0.52% and 4.77%, respectively. Then, the proposed FT-based model has been employed for predicting the dynamic viscosities of several FAEs and biodiesels in 293.15-393.15 K and pressures up to 200 MPa. The model predicted 892 experimental data points for dynamic viscosities of 10 FAEs and 3 biodiesels with the AARD of 1.70%.
Keywords
Dynamic viscosity
Friction Theory
Fatty acid esters
Biodiesels

Subjects

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