Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

A Review of Recent Advances in Water and Wastewater Treatment Using Catalytic Ozonation Process

Document Type : Review Article

Authors
Seyed Behnam Bagherzadeh 1
Niyaz Mohammad Mahmoodi 2
1 Department of Chemical, Materials and Polymer Engineering, Buein Zahra Technical University, Buein Zahra, Qazvin, I.R. IRAN
2 Department of Environmental Research, Institute for Color Science and Technology, Tehran, I.R. IRAN
Abstract
Ozone (O3) is a strong oxidizing agent that breaks down refractory organic contaminants (ROCs) into smaller, less hazardous molecules. Ozonation has been widely used in water and wastewater treatment for disinfection and for the destruction of toxic organic pollutants. However, the efficiency of ozone utilization is low, the mineralization of organic pollutants by ozone oxidation is less effective, and some toxic disinfection byproducts (DBPs) are likely to be formed during the ozonation process. Catalytic ozonation can overcome these problems to some extent. During catalytic ozonation, catalysts can increase the efficiency of O3 decomposition and generate active free radicals. These active species can enhance the degradation and mineralization of organic pollutants. In heterogeneous catalytic ozonation (HCO), ozone is injected into the wastewater stream as a gas or as O3-enriched air. A solid catalyst improves ozonation efficiency by increasing the decomposition of O3 and the production of reactive oxygen species (ROS) that are capable of oxidizing ROCs. Metal oxides are the most commonly used catalysts. However, the type of catalyst used in the HCO process and how it reacts with O3 determine how much ROS is produced. The production of reactive oxygen species by different catalysts in the heterogeneous catalytic ozonation process is enhanced through different mechanisms that may affect the efficiency and selectivity of the process. The present study presents and discusses a comprehensive summary of research and developments in the catalytic ozonation process in the form of various sections including history, types of catalytic ozonation processes, homogeneous and heterogeneous catalysts widely used in this process, mechanisms of homogeneous and heterogeneous catalytic ozonation processes, the effect of operating parameters (initial pollutant concentration, catalyst loading amount, solution pH, and temperature) on the process, and finally the application of catalytic ozonation process for the destruction of toxic organic pollutants.
Keywords
Ozone
Catalytic ozonation
Heterogeneous catalytic ozonation process
Water and wastewater treatment
Destruction of toxic organic pollutants

Subjects

[1]    Malato S., Fernández-Ibáñez P., Maldonado M.I., Blanco J., Gernjak W., Decontamination and Disinfection of Water by Solar Photocatalysis: Recent Overview and Trends, Catalysis Today, 147(1): 1-59 (2009).
[2]    Mahmoodi N.M., Manganese Ferrite Nanoparticle: Synthesis, Characterization, and Photocatalytic Dye Degradation Ability, Desalination and Water Treatment, 53(1): 84-90 (2015).
[3]    Mahmoodi N.M., Arami M., Modeling and Sensitivity Analysis of Dyes Adsorption onto Natural Adsorbent From Colored Textile Wastewater, Journal of Applied Polymer Science, 109(6): 4043-4048 (2008).
[4]    Mahmoodi N.M., Arami M., Limaee N.Y., Gharanjig K., Ardejani F.D., Decolorization and Mineralization of Textile Dyes at Solution Bulk by Heterogeneous Nanophotocatalysis Using Immobilized Nanoparticles of Titanium Dioxide, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 290(1): 125-131 (2006).
[5]    Bagherzadeh S.B., Kazemeini M., Mahmoodi N.M., A Study of the DR23 Dye Photocatalytic Degradation Utilizing a Magnetic Hybrid Nanocomposite of MIL-53(Fe)/CoFe2O4: Facile Synthesis and Kinetic Investigations, Journal of Molecular Liquids, 301: 112427 (2020).
[6]    Bagherzadeh S.B., Kazemeini M., Mahmoodi N.M., Preparation of Novel and Highly Active Magnetic Ternary Structures (Metal-Organic Framework/Cobalt Ferrite/Graphene Oxide) for Effective Visible-Light-Driven Photocatalytic and Photo-Fenton-like Degradation of Organic Contaminants, Journal of Colloid and Interface Science, 602: 73-94 (2021).
[7]    Mahmoodi N.M., Bagherzadeh S.B., Synthesis of Binary and Ternary MOF/Carbon Based Composites (MOF/Carbon Nitride/Graphene Oxide) for the Visible-Light Assisted Destruction of Tetracycline and Textile dye, Nano Materials Science, 7(3): 359-376 (2025).
[8]    Akköz Y., Coşkun R., Cellulose- Supported Sulfated-Magnetic Biocomposite Produced from Hemp Biomass: Effective Removal of Cationic Dyes from Aqueous Solution, International Journal of Biological Macromolecules, 257: 128747 (2024).
[9]    Dehingia B., Lahkar R., Kalita H., Efficient Removal of Both Cationic and Anionic Dyes from Water Using a Single rGO/PSS Nanocomposite Membrane with Superior Permeability and High Aqueous Stability, Journal of Environmental Chemical Engineering, 12(2): 112393 (2024).
[10]    Zhang Q., Jiang L., Wang J., Zhu Y., Pu Y., Dai W., Photocatalytic Degradation of Tetracycline Antibiotics Using Three-Dimensional Network Structure Perylene Diimide Supramolecular Organic Photocatalyst Under Visible-Light Irradiation, Applied Catalysis B: Environmental, 277: 119122 (2020).
[11] Uğan M., Onac C., Kaya A., Köseoğlu D., Akdoğan A., Removal of Reactive Red 195 Dye from Textile Industry Wastewater with Deep Eutectic Solvent-Based Green Extraction, Journal of Molecular Liquids, 398: 124249 (2024).
[12] Rawat S., Ahammed M.M., Clay-Moringa Seedcake Composite for Removal of Cationic and Anionic Dyes, Chemosphere, 350: 141083 (2024).
[13] Nguyen N.Q., Jeong Y., Abelmann L., Ryu J., Sohn D., Enhanced Magnetic Halloysite Nanotubes for Dye Removal at Different pH Conditions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 680: 132631 (2024).
[14] Bagherzadeh S.B., A Review of Photocatalytic Membrane Reactors and Their Application in the Treatment of Dye-containing Wastewater, Journal of Studies in Color World, 15(3): 331-358 (2025).
[15] Pedebos M.E.S., Druzian D.M., Oviedo L.R., Ruiz Y.P.M., Galembeck A., Pavoski G., Espinosa D.C.R., da Silva W.L., Removal of Rhodamine B Dye by Adsorption onto an Eco-Friendly Zeolite and Machine Learning Modeling, Journal of Photochemistry and Photobiology A: Chemistry, 449: 115404 (2024).
[16] Liu Z., Demeestere K., Hulle S.V., Comparison and Performance Assessment of Ozone-Based AOPs in View of Trace Organic Contaminants Abatement in Water and Wastewater: A review, Journal of Environmental Chemical Engineering, 9(4): 105599 (2021).
[17] Rice R.G., Applications of Ozone for Industrial Wastewater Treatment — A Review, Ozone: Science & Engineering, 18(6): 477-515 (1996).
[18] Jamali G.A., Devrajani S.K., Memon S.A., Qureshi S.S., Anbuchezhiyan G., Mubarak N.M., Shamshuddin S.Z.M., Siddiqui M.T.H., Holistic Insight Mechanism of Ozone-Based Oxidation Process for Wastewater Treatment, Chemosphere, 359: 142303 (2024).
[19] Das T.K., Ultraviolet Disinfection Application to a Wastewater Treatment Plant, Clean Products and Processes, 3(2): 69-80 (2001).
[20] Wei C., Zhang F., Hu Y., Feng C., Wu H., Ozonation in water treatment: the generation, basic properties of ozone and its practical application, Reviews in Chemical Engineering, 33(1): 49-89 (2017).
[21] Zong Q., Niu X., Cheng X., Liu Y., Liu C., Shi T., Liu J., Yang X., Wang W., Guo Z., Xiao F., Advanced Solar Photo-Fenton-Like Process with Directly Growing Nano-Heterojunctions on Graphite Fiber Felt for Phenolic Wastewater Treatment: Synergistically Expand the pH Activity Range and Facilitate the Fe(III)/Fe(II) Cycle. Chemosphere, 373: 143980 (2025).
[22] Korkmaz G., Aktay N., Palas B., Ersöz G., Atalay S., Photo Fenton-Like Oxidation of Real Textile Wastewater: Operating Conditions, Kinetic Modelling and Cost Analysis, Chemical Engineering and Processing - Process Intensification, 204: 109951 (2024).
[23] Li Q., Zhao T., Zhu J., Ma M., Hou G., Fang M., Shen Y., Zhao X., Tang Z., Wu F., Designing Ultrathin Single and Multilayered Ti3C2TX MXene as Photocatalysts for Enhanced Acetaminophen Degradation in Photo-Fenton-Like Reactions, Chemical Engineering Journal, 516: 163691 (2025).
[24] مرضیه بیات.، مریم رنجبر.، سهیلا شکرالله زاده.، سنتز و شناسایی نانوکاتالیست Mn3O4 و کاربرد آن برای حذف فنل، نشریه شیمی و مهندسی شیمی ایران، (2)37: 13 تا 20 (1397). 
[25] Fanaee M., Vahid B., Treatment of Direct Red 23 in Recirculating Semi-Pilot System by O3/UV Process: Operational Parameters Effect and Central Composite Design Modeling, Iranian Journal of Chemistry and Chemical Engineering, 41(5): 1755-1764 (2022).
[26] Azimi S.C., Shirini F., Pendashteh A.R., Advanced Oxidation Process as a Green Technology for Dyes Removal from Wastewater: A Review, Iranian Journal of Chemistry and Chemical Engineering, 40(5): 1467-1489 (2021).
[27] Pourfalatoon S., Mazaheri H., Hassani joshaghani A., Shokri A., Employing a New Catalytic Ozonation(O3/MnO2/CP) for Degradation of Nitro Toluene in Aqueous Environment Using Box-Behnken Experimental Design, Iranian Journal of Chemistry and Chemical Engineering, 40(3): 804-814 (2021).
[28] Mousanejad T., Vahid B., Ultrasound Enhanced Activity of Catalytic Ozonation for Degradation of 2-sec-butyl-4,6-dinitrophenol in Aqueous Solution and Wastewater, Iranian Journal of Chemistry and Chemical Engineering, 39(4): 223-233 (2020).
[29] Das P.P., Dhara S., Samanta N.S., Purkait M.K., Advancements on Ozonation Process for Wastewater Treatment: A Comprehensive Review, Chemical Engineering and Processing - Process Intensification, 202: 109852 (2024).
[30] Wang J., Chen H., Catalytic Ozonation for Water and Wastewater Treatment: Recent Advances and Perspective, Science of The Total Environment, 704: 135249 (2020).
[31] Li X., Fu L., Chen F., Zhao S., Zhu J., Yin C., Application of Heterogeneous Catalytic Ozonation in Wastewater Treatment: An Overview, Catalysts, 13(2): 342 (2023).
[32] Li L., Fu R., Zou J., Wang S., Ding J., Han J., Zhao M., Research Progress of Iron-Based Catalysts in Ozonation Wastewater Treatment, ACS ES&T Water, 3(4): 908-922 (2023).
[33] Prada-Vásquez M.A., Simarro-Gimeno C., Vidal-Barreiro I., Cardona-Gallo S.A., Pitarch E., Hernández F., Torres-Palma R.A., Chica A., Navarro-Laboulais J., Application of Catalytic Ozonation Using Y Zeolite in the Elimination of Pharmaceuticals in Effluents from Municipal Wastewater Treatment Plants, Science of The Total Environment, 925: 171625 (2024).
[34] Issaka E., Amu-Darko J.N.-.O., Yakubu S., Fapohunda F.O., Ali N., Bilal M., Advanced Catalytic Ozonation for Degradation of Pharmaceutical Pollutants―A Review, Chemosphere, 289: 133208 (2022).
[35] Issaka E., Baffoe J., Adams M., Exploring Heterogeneous Catalytic Ozonation: Catalyst Types, Reaction Mechanisms, Applications, Challenges, and Future Outlook, Sustainable Chemistry for the Environment, 8: 100185 (2024).
[36] Issaka E., Fapohunda F.O., Amu-Darko J.N.O., Yeboah L., Yakubu S., Varjani S., Ali N., Bilal M., Biochar-Based Composites for Remediation of Polluted Wastewater and Soil Environments: Challenges and Prospects, Chemosphere, 297: 134163 (2022).
[37] Dharmalingam B.C., Koushik V.A., Mureddu M., Atzori L., Lai S., Pettinau A., Kaisare N.S., Aghalayam, P., Varghese, J.J., Unravelling the Role of Metal-Metal Oxide Interfaces of Cu/ZnO/ZrO2/Al2O3 Catalyst for Methanol Synthesis from CO2: Insights from Experiments and DFT-Based Microkinetic Modeling, Applied Catalysis B: Environmental, 332: 122743 (2023).
[38] Chen J., Yang C., Wu T., Wang J., Yang L., Sun W., Li W., Wang A., Lv S., Metal-Free N-doped Spongy Carbon Recycled from Waste MOF for Enhanced Catalytic Ozonation: Mechanistic Insights and Practical Applications, Journal of Water Process Engineering, 55: 104044 (2023).
[39] Li Y., Dong H., Li L., Tang L., Tian R., Li R., Chen J., Xie Q., Jin Z., Xiao J., Xiao S., Zeng G., Recent Advances in Waste Water Treatment through Transition Metal Sulfides-Based Advanced Oxidation Processes, Water Research, 192: 116850 (2021).
[40] Yang Z., Yang H., Liu Y., Hu C., Jing H., Li H., Heterogeneous Catalytic Ozonation for Water Treatment: Preparation and Application of Catalyst, Ozone: Science & Engineering, 45(2): 147-173 (2023).
[41] Issaka E., Danso-Boateng E., Baffoe J., Harnessing the Power of Heterogeneous Photocatalytic Process for Sustainable Pharmaceutical Contaminant Remediation in Water Environments. Desalination and Water Treatment, 319: 100574 (2024).
[42] Rekhate C.V., Srivastava J.K., Recent Advances in Ozone-Based Advanced Oxidation Processes for Treatment of Wastewater- A Review, Chemical Engineering Journal Advances, 3: 100031 (2020).
[43] Liu F., Tu Y., Chen J., Shao G., Zhou Z., Tian S., Ren Z., Treatment of Saline Organic Wastewater by Heterogeneous Catalytic Ozonation with Al2O3-PEC-CaxOy as Catalysts. Chemical Engineering Journal Advances, 14: 100447 (2023).
[44] Wang P., Wang Y., Zhou B., Meng F., Zhao Z., Wei C., Zhou L., Wen G., Zhang X., Layered Double Oxide (CoAl-LDO) Catalysis for Enhanced Ozonation of Methyl Orange: Performance Assessment and Mechanistic Insights, Journal of Molecular Liquids, 404: 124995 (2024).
[45] Ren T., Ouyang C., Zhou Z., Chen S., Yin M., Huang X., Zhang X., Mn-Doped Carbon-Al2SiO5 Fibers Enable Catalytic Ozonation for Wastewater Treatment: Interface Modulation and Mass Transfer Enhancement. Journal of Hazardous Materials, 460: 132307 (2023).
[46] Wu T., Tang X., Lin Y., Wang Y., Ma S., Xue Y., Ren H., Xu K., Heterogeneous Catalytic Ozonation of Atrazine with Oxygen Vacancy-Rich Cu-Loaded and Ce-Loaded Attapulgite: Efficiency, Mechanism and Environmental Application, Chemical Engineering Journal, 486: 150079 (2024).
[47] Chen W., He H., Liang J., Wei X., Li X., Wang J., Li L., A Comprehensive Review on Metal Based Active Sites and Their Interaction with O3 During Heterogeneous Catalytic Ozonation Process: Types, Regulation and Authentication,  Journal of Hazardous Materials, 443: 130302 (2023).
[48] He Y., Chen Y., Li J., Wang D., Song S., Dong F., He Z., Efficient Degradation of 2,3,5-Trimethylpyrazine by Catalytic Ozonation Over MnOx Supported on Biochar Derived from Waste Tea Leaves, Chemical Engineering Journal, 464: 142525 (2023).
[49] Yang D., Meng F., Zhang Z., Liu X., Enhanced Catalytic Ozonation by Mn–Ce Oxide-Loaded Al2O3 Catalyst for Ciprofloxacin Degradation. ACS Omega, 8(24): 21823-21829 (2023).
[50] Orge C.A., Graça C.A.L., Restivo J., Pereira M.F.R., Soares O.S.G.P., Catalytic Ozonation of Pharmaceutical Compounds Using Carbon-Based Catalysts, Catalysis Communications, 187: 106863 (2024).
[51] Rubin M.B., The History of Ozone. The Schönbein Period, 1839–1868, Bull. Hist. Chem, 26(1): 40–56 (2001).
[52] Rice R.G., Robson C.M., Miller G.W., Hill A.G., Uses of Ozone in Drinking Water Treatment, Journal AWWA, 73(1): 44-57 (1981).
[53] Nawrocki J., Kasprzyk-Hordern B., The Efficiency and Mechanisms of Catalytic Ozonation, Applied Catalysis B: Environmental, 99(1): 27-42 (2010).
[54] Haag W.R., Hoigne J., Ozonation of Bromide-Containing Waters: Kinetics of Formation of Hypobromous Acid and Bromate, Environmental Science & Technology, 17(5): 261-267 (1983).
[55] Ziylan A., Ince N.H., Catalytic Ozonation of Ibuprofen with Ultrasound and Fe-Based Catalysts, Catalysis Today, 240: 2–8 (2015).
[56] Chen J., Tian S., Lu J., Xiong Y., Catalytic Performance of MgO With Different Exposed Crystal Facets Towards the Ozonation of 4-Chlorophenol. Applied Catalysis A: General, 506: 118-125 (2015).
[57] Dai Q., Zhang Z., Zhan T., Hu Z.-.T., Chen J., Catalytic Ozonation for the Degradation of 5-Sulfosalicylic Acid with Spinel-Type ZnAl2O4 Prepared by Hydrothermal, Sol–Gel, and Coprecipitation Methods: A Comparison Study, ACS Omega, 3(6): 6506-6512 (2018).
[58] Bilińska M., Bilińska L., Gmurek M., Homogeneous and Heterogeneous Catalytic Ozonation of Textile Wastewater: Application and Mechanism, Catalysts, 13(1): 6 (2023).
[59] Wang J., Bai Z., Fe-Based Catalysts for Heterogeneous Catalytic Ozonation of Emerging Contaminants in Water and Wastewater, Chemical Engineering Journal, 312: 79-98 (2017).
[60] Yu G., Wang Y., Cao H., Zhao H., Xie Y., Reactive Oxygen Species and Catalytic Active Sites in Heterogeneous Catalytic Ozonation for Water Purification, Environmental Science & Technology, 54(10): 5931-5946 (2020).
[61] Huang Y., Cui C., Zhang D., Li L., Pan D., Heterogeneous Catalytic Ozonation of Dibutyl Phthalate in Aqueous Solution in the Presence of Iron-Loaded Activated Carbon, Chemosphere, 119: 295-301 (2015).
[62] Asgari G., Seidmohammadi A., Faradmal J., Esrafili A., Noori Sepehr M., Jafarinia M., Optimization of Synthesis a New Composite of Nano-MgO, CNT and Graphite as a Catalyst in Heterogeneous Catalytic Ozonation for the Treatment of Pesticide-Laden Wastewater, Journal of Water Process Engineering, 33: 101082 (2020).
[63] Tizaoui C., Haydar M.-S., Suhartono J., Multiwalled Carbon Nanotubes for Heterogeneous Nanocatalytic Ozonation, Ozone: Science & Engineering, 37(3): 269-278 (2015).
[64] Chen H., Wang J., Catalytic Ozonation of Sulfamethoxazole over Fe3O4/Co3O4 Composites, Chemosphere, 234: 14–24 (2019).
[65] Wang S., Wang J., Activation of Peroxymonosulfate by Sludge-Derived Biochar for the Degradation of Triclosan in Water and Wastewater, Chemical Engineering Journal, 356: 350-358 (2019).
[66] Wang Y., Xie Y., Sun H., Xiao J., Cao H., Wang S., 2D/2D Nano-Hybrids of γ-MnO2 on Reduced Graphene Oxide for Catalytic Ozonation and Coupling Peroxymonosulfate Activation, Journal of Hazardous Materials, 301: 56-64 (2016).
[67] Yan H., Lu P., Pan Z., Wang X., Zhang Q., Li L., Ce/SBA-15 as a Heterogeneous Ozonation Catalyst for Efficient Mineralization of Dimethyl Phthalate, Journal of Molecular Catalysis A: Chemical, 377: 57-64 (2013).
[68] Yang L., Hu C., Nie Y., Qu J., Surface Acidity and Reactivity of β-FeOOH/Al2O3 for Pharmaceuticals Degradation with Ozone: In Situ ATR-FTIR Studies, Applied Catalysis B: Environmental, 97(3): 340-346 (2010).
[69] Faria P.C.C., Órfão J.J.M., Pereira M.F.R., Activated Carbon and Ceria Catalysts Applied to the Catalytic Ozonation of Dyes and Textile Effluents, Applied Catalysis B: Environmental, 88(3): 341-350 (2009).
[70] Yang L., Hu C., Nie Y., Qu J., Catalytic Ozonation of Selected Pharmaceuticals over Mesoporous Alumina-Supported Manganese Oxide, Environmental Science & Technology, 43(7): 2525-2529 (2009).
[71] Hu, C., Xing, S., Qu, J., He, H., Catalytic Ozonation of Herbicide 2,4-D over Cobalt Oxide Supported on Mesoporous Zirconia, The Journal of Physical Chemistry C, 112(15): 5978-5983 (2008).
[72] Huang, X., Xu, Y., Shan, C., Li, X., Zhang, W., Pan, B., Coupled Cu(II)-EDTA Degradation and Cu(II) Removal from Acidic Wastewater by Ozonation: Performance, Products and Pathways, Chemical Engineering Journal, 299: 23-29 (2016).
[73] Wu C.-H., Kuo C.-Y., Chang C.-L., Homogeneous Catalytic Ozonation of C.I. Reactive Red 2 by Metallic Ions in a Bubble Column Reactor, Journal of Hazardous Materials, 154(1): 748-755 (2008).
[74] Beltrán F.J., Rivas F.J., Montero-de-Espinosa R., Ozone-Enhanced Oxidation of Oxalic Acid in Water with Cobalt Catalysts. 1. Homogeneous Catalytic Ozonation, Industrial & Engineering Chemistry Research, 42(14): 3210-3217 (2003).
[75] Andreozzi R., Marotta R., Sanchirico R., Manganese-Catalysed Ozonation of Glyoxalic Acid in Aqueous Solutions, Journal of Chemical Technology & Biotechnology, 75(1): 59-65 (2000).
[76] Beltrán F.J., Rivas F.J., Montero-de-Espinosa R., Iron Type Catalysts for the Ozonation of Oxalic Acid in Water, Water Research, 39(15): 3553-3564 (2005).
[77] Pines D.S., Reckhow D.A., Effect of Dissolved Cobalt(II) on the Ozonation of Oxalic Acid, Environmental Science & Technology, 36(19): 4046-4051 (2002).
[78] Andreozzi, R., Caprio, V., Insola, A., Marotta, R., Tufano, V., The Ozonation of Pyruvic Acid in Aqueous Solutions Catalyzed by Suspended and Dissolved Manganese, Water Research, 32(5): 1492-1496 (1998).
[79] Andreozzi, R., Insola, A., Caprio, V., D'Amore, M.G., The Kinetics of Mn(II)-Catalysed Ozonation of Oxalic Acid in Aqueous Solution, Water Research, 26(7): 917-921 (1992).
[80] El-Raady A.A.A., Nakajima T., Decomposition of Carboxylic Acids in Water by O3, O3/H2O2, and O3/Catalyst, Ozone: Science & Engineering, 27(1): 11-18 (2005).
[81] Trapido, M., Y., V., R., M., Kallas, J., Catalytic Ozonation of m-Dinitrobenzene, Ozone: Science & Engineering, 27(5): 359-363 (2005).
[82] Ni C.-H., Chen J.-N., Yang P.-Y., Catalytic Ozonation of 2-Dichlorophenol by Metallic Ions, Water Science and Technology, 47(1): 77-82 (2003).
[83] Cortés, S., J., S., P., O., R., G., Ovelleiro, J.L., Comparative Efficiency of the Systems O3/High pH And 03/Catalyst for the Oxidation of Chlorobenzenes in Water, Ozone: Science & Engineering, 22(4): 415-426 (2000).
[84] Matheswaran, M., Balaji, S., Chung, S.J., Moon, I.S., Studies on Cerium Oxidation in Catalytic Ozonation Process: A Novel Approach for Organic Mineralization, Catalysis Communications, 8(10): 1497-1501 (2007).
[85] Zhang X.-b., Dong W.-y., Yang W., Decolorization Efficiency and Kinetics of Typical Reactive Azo Dye RR2 in the Homogeneous Fe(II) Catalyzed Ozonation Process, Chemical Engineering Journal, 233: 14-23 (2013).
[86] Ma J., Graham N.J.D., Degradation of Atrazine by Manganese-Catalysed Ozonation: Influence of Humic Substances, Water Research, 33(3): 785-793 (1999).
[87] Pera-Titus, M., Garcı́a-Molina, V., Baños, M.A., Giménez, J., Esplugas, S., Degradation of Chlorophenols by Means of Advanced Oxidation Processes: A General Review, Applied Catalysis B: Environmental, 47(4): 219-256 (2004).
[88] Zeng, Z., Zou, H., Li, X., Sun, B., Chen, J., Shao, L., Ozonation of Phenol with O3/Fe(II) in Acidic Environment in a Rotating Packed Bed, Industrial & Engineering Chemistry Research, 51(31): 10509-10516 (2012).
[89] Rivas, F.J., J., B.F., M., C., Gimeno, O., Homogeneous Catalyzed Ozone Decomposition in the Presence of Co(II), Ozone: Science & Engineering, 25(4): 261-271 (2003).
[90] Staehelin J., Hoigne J., Decomposition of Ozone in Water in the Presence of Organic Solutes Acting as Promoters and Inhibitors of Radical Chain Reactions, Environmental Science & Technology, 19(12): 1206-1213 (1985).
[91] Tang W.Z., Tassos S., Oxidation Kinetics and Mechanisms of Trihalomethanes by Fenton's Reagent, Water Research, 31(5): 1117-1125 (1997).
[92] Ma J., Graham N.J.D., Degradation of Atrazine by Manganese-Catalysed Ozonation—Influence of Radical Scavengers, Water Research, 34(15): 3822-3828 (2000).
[93] Oyama S.T., Chemical and Catalytic Properties of Ozone, Catalysis Reviews, 42(3): 279-322 (2000).
[94] Luo, K., Zhao, S.-.X., Wang, Y.-.F., Zhao, S.-.J., Zhang, X.-.H., Synthesis of Petal-Like δ-MnO2 and its Catalytic Ozonation Performance, New Journal of Chemistry, 42(9): 6770-6777 (2018).
[95] Nawaz, F., Xie, Y., Cao, H., Xiao, J., YueqiuWang, Zhang, X., Li, M., Duan, F., Catalytic Ozonation of 4-Nitrophenol over an Mesoporous α-MnO2 with Resistance to Leaching, Catalysis Today, 258: 595-601 (2015).
[96] Dong, Y., Li, K., Jiang, P., Wang, G., Miao, H., Zhang, J., Zhang, C., Simple Hydrothermal Preparation of α-, β-, and γ-MnO2 and Phase Sensitivity in Catalytic Ozonation, RSC Advances, 4(74): 39167-39173 (2014).
[97] Dong, Y., Yang, H., He, K., Song, S., Zhang, A., β-MnO2 Nanowires: A Novel Ozonation Catalyst for Water Treatment, Applied Catalysis B: Environmental, 85(3): 155-161 (2009).
[98] Zhao, H., Dong, Y., Jiang, P., Wang, G., Zhang, J., Li, K., Feng, C., An α-MnO2 Nanotube Used as a Novel Catalyst in Ozonation: Performance and the Mechanism, New Journal of Chemistry, 38(4): 1743-1750 (2014).
[99] Alsheyab M.A., Muñoz A.H., Comparative Study of Ozone and MnO2/O3 Effects on the Elimination of TOC and COD of Raw Water at the Valmayor Station, Desalination, 207(1): 179-183 (2007).
[100]  Tong, S.-.p., Liu, W.-.p., Leng, W.-.h., Zhang, Q.-.q., Characteristics of MnO2 Catalytic Ozonation of Sulfosalicylic Acid and Propionic Acid in Water, Chemosphere, 50(10): 1359-1364 (2003).
[101]  Ma J., Graham N.J.D., Preliminary Investigation of Manganese-Catalyzed Ozonation for the Destruction of Atrazine, Ozone: Science & Engineering, 19(3): 227-240 (1997).
[102]  Centurião, A.P.S.L., Z., B.V., G., S., M., d.A.S., Moreira, R.F.P.M., Enhanced Ozonation Degradation of Petroleum Refinery Wastewater in the Presence of Oxide Nanocatalysts, Environmental Technology, 40(10): 1239-1249 (2019).
[103]  Wang J., Wang S., Activation of Persulfate (PS) and Peroxymonosulfate (PMS) and Application for the Degradation of Emerging Contaminants, Chemical Engineering Journal, 334: 1502-1517 (2018).
[104]  Zhu, S., Dong, B., Yu, Y., Bu, L., Deng, J., Zhou, S., Heterogeneous Catalysis of Ozone Using Ordered Mesoporous Fe3O4 for Degradation of Atrazine, Chemical Engineering Journal, 328: 527-535 (2017).
[105]  Yin, R., Guo, W., Zhou, X., Zheng, H., Du, J., Wu, Q., Chang, J., Ren, N., Enhanced Sulfamethoxazole Ozonation by Noble Metal-Free Catalysis Based on Magnetic Fe3O4 Nanoparticles: Catalytic Performance and Degradation Mechanism, RSC Advances, 6(23): 19265-19270 (2016).
[106]  Shahamat, Y.D., Farzadkia, M., Nasseri, S., Mahvi, A.H., Gholami, M., Esrafili, A., Magnetic Heterogeneous Catalytic Ozonation: A New Removal Method for Phenol in Industrial Wastewater, Journal of Environmental Health Science and Engineering, 12(1): 50 (2014).
[107]  Kishimoto N., Ueno S., Catalytic Effect of Several Iron Species on Ozonation, Journal of Water and Environment Technology, 10(2): 205-215 (2012).
[108]  Oputu, O., Chowdhury, M., Nyamayaro, K., Fatoki, O., Fester, V., Catalytic Activities of Ultra-Small β-FeOOH Nanorods in Ozonation of 4-Chlorophenol, Journal of Environmental Sciences, 35: 83-90 (2015).
[109]  Zhang T., Ma J., Catalytic Ozonation of Trace Nitrobenzene in Water with Synthetic Goethite, Journal of Molecular Catalysis A: Chemical, 279(1): 82-89 (2008).
[110]  Li, X., Chen, W., Tang, Y., Li, L., Relationship Between the Structure of Fe-MCM-48 and its Activity in Catalytic Ozonation for Diclofenac Mineralization, Chemosphere, 206: 615-621 (2018).
[111]  Ncanana Z.S., Rajasekhar Pullabhotla V.S.R., Oxidative Degradation of m-Cresol Using Ozone in the Presence of Pure γ-Al2O3, SiO2 and V2O5 Catalysts, Journal of Environmental Chemical Engineering, 7(3): 103072 (2019).
[112]  Mao, L., Chen, Z., Wu, X., Tang, X., Yao, S., Zhang, X., Jiang, B., Han, J., Wu, Z., Lu, H., Nozaki, T., Plasma-Catalyst Hybrid Reactor with CeO2/γ-Al2O3 for Benzene Decomposition with Synergetic Effect and Nano Particle By-Product Reduction, Journal of Hazardous Materials, 347: 150-159 (2018).
[113]  Ziylan-Yavaş A., Ince N.H., Catalytic Ozonation of Paracetamol Using Commercial and Pt-Supported Nanocomposites of Al2O3: The Impact of Ultrasound, Ultrasonics Sonochemistry, 40: 175-182 (2018).
[114]  Wu, J., Su, T., Jiang, Y., Xie, X., Qin, Z., Ji, H., In Situ DRIFTS Study of O3 Adsorption on CaO, γ-Al2O3, CuO, α-Fe2O3 and ZnO at Room Temperature for the Catalytic Ozonation of Cinnamaldehyde, Applied Surface Science, 412: 290-305 (2017).
[115]  Guzman-Perez C.A., Jafar S., Robertson J., Catalytic Ozonation of 2,4-Dichlorophenoxyacetic Acid Using Alumina in the Presence of a Radical Scavenger, Journal of Environmental Science and Health, Part B, 47(6): 544-552 (2012).
[116]  Qi, F., Xu, B., Chen, Z., Ma, J., Catalytic Ozonation for Degradation of 2, 4, 6-Trichloroanisole in Drinking Water in the Presence of γ-AlOOH, Water Environment Research, 81(6): 592-597 (2009).
[117]  Qi, F., Xu, B., Chen, Z., Zhang, L., Zhang, P., Sun, D., Mechanism Investigation of Catalyzed Ozonation of 2-Methylisoborneol in Drinking Water over Aluminum (Hydroxyl) Oxides: Role of Surface Hydroxyl Group, Chemical Engineering Journal, 165(2): 490-499 (2010).
[118]  Qi, F., Xu, B., Chen, Z., Feng, L., Zhang, L., Sun, D., Catalytic Ozonation of 2-Isopropyl-3-Methoxypyrazine in Water by γ-AlOOH and γ-Al2O3: Comparison of Removal Efficiency and Mechanism, Chemical Engineering Journal, 219: 527-536 (2013).
[119]  Ni C.H., Chen J.N., Heterogeneous Catalytic Ozonation of 2-Chlorophenol Queous Solution with Alumina as a Catalyst, Water Science and Technology, 43(2): 213-220 (2001).
[120]  Zhang, L.-.H., Jing, Z., Zheng-Qian, L., and Guo, J.-.B., Mesoporous CeO2 Catalyst Synthesized by Using Cellulose as Template for the Ozonation of Phenol, Ozone: Science & Engineering, 41(2): 166-174 (2019).
[121]  Chen, J., Xu, S., Yang, H., Au, C., Tian, S., Xiong, Y., Ozonation Inactivation of in Aqueous Solution over MgO Nanocrystals: Modelling and Mechanism, Journal of Chemical Technology & Biotechnology, 93(6): 1648-1654 (2018).
[122]  Zhu, H., Ma, W., Han, H., Han, Y., Ma, W., Catalytic Ozonation of Quinoline Using Nano-MgO: Efficacy, Pathways, Mechanisms and its Application to Real Biologically Pretreated Coal Gasification Wastewater, Chemical Engineering Journal, 327: 91-99 (2017).
[123]  Bashiri H., Rafiee M., Kinetic Monte Carlo Simulation of 2,4,6-Thrichloro Phenol Ozonation in the Presence of ZnO Nanocatalyst, Journal of Saudi Chemical Society, 20(4): 474-479 (2016).
[124]  Dai, Q., Wang, J., Yu, J., Chen, J., Chen, J., Catalytic Ozonation for the Degradation of Acetylsalicylic Acid in Aqueous Solution by Magnetic CeO2 Nanometer Catalyst Particles, Applied Catalysis B: Environmental, 144: 686-693 (2014).
[125]  Yang, Y., Cao, H., Peng, P., Bo, H., Degradation and Transformation of Atrazine under Catalyzed Ozonation Process with TiO2 as Catalyst, Journal of Hazardous Materials, 279: 444-451 (2014).
[126]  Moussavi G., Mahmoudi M., Degradation and Biodegradability Improvement of the Reactive Red 198 Azo Dye Using Catalytic Ozonation with MgO Nanocrystals, Chemical Engineering Journal, 152(1): 1-7 (2009).
[127]  Yang, Y., Ma, J., Qin, Q., Zhai, X., Degradation of Nitrobenzene by Nano-TiO2 Catalyzed Ozonation, Journal of Molecular Catalysis A: Chemical, 267(1): 41-48 (2007).
[128]  Wang J., Zhuang S., Covalent Organic Frameworks (COFs) for Environmental Applications, Coordination Chemistry Reviews, 400: 213046 (2019).
[129]  Fan, X., Restivo, J., Órfão, J.J.M., Pereira, M.F.R., Lapkin, A.A., The Role of Multiwalled Carbon Nanotubes (MWCNTs) in the Catalytic Ozonation of Atrazine, Chemical Engineering Journal, 241: 66-76 (2014).
[130]  Liu, Z.-.Q., Ma, J., Cui, Y.-.H., Zhao, L., Zhang, B.-.P., Influence of Different Heat Treatments on the Surface Properties and Catalytic Performance of Carbon Nanotube in Ozonation, Applied Catalysis B: Environmental, 2010. 101(1): 74-80 (2010).
[131]  Cao, H., Xing, L., Wu, G., Xie, Y., Shi, S., Zhang, Y., Minakata, D., Crittenden, J.C., Promoting Effect of Nitration Modification on Activated Carbon in the Catalytic Ozonation of Oxalic Acid, Applied Catalysis B: Environmental, 146: 169-176 (2014).
[132]  Qu, R., Xu, B., Meng, L., Wang, L., Wang, Z., Ozonation of Indigo Enhanced by Carboxylated Carbon Nanotubes: Performance Optimization, Degradation Products, Reaction Mechanism and Toxicity Evaluation, Water Research, 68: 316-327 (2015).
[133]  Yoon, Y., Oh, H., Ahn, Y.T., Kwon, M., Jung, Y., Park, W.K., Hwang, T.M., Yang, W.S., Kang, J.W., Evaluation of the O3/Graphene-Based Materials Catalytic Process: pH Effect and Iopromide Removal, Catalysis Today, 282: 77-85 (2017).
[134]  Kruanak K., Jarusutthirak C., Degradation of 2,4,6-Trichlorophenol in Synthetic Wastewater by Catalytic Ozonation Using Alumina Supported Nickel Oxides, Journal of Environmental Chemical Engineering, 7(1): 102825 (2019).
[135]  Wang, J., Quan, X., Chen, S., Yu, H., Liu, G., Enhanced Catalytic Ozonation by Highly Dispersed CeO2 on Carbon Nanotubes for Mineralization of Organic Pollutants, Journal of Hazardous Materials, 368: 621-629 (2019).
[136]  Wu, Z., Zhang, G., Zhang, R., Yang, F., Insights into Mechanism of Catalytic Ozonation over Practicable Mesoporous Mn-CeOx/γ-Al2O3 Catalysts, Industrial & Engineering Chemistry Research, 57(6): 1943-1953 (2018).
[137]  Bai Z.Y., Yang Q., Wang J.L., Fe3O4/Multi-Walled Carbon Nanotubes as an Efficient Catalyst for Catalytic Ozonation of P-Hydroxybenzoic Acid, International Journal of Environmental Science and Technology, 13(2): 483-492 (2016).
[138]  Bai Z., Yang Q., Wang J., Catalytic Ozonation of Sulfamethazine Antibiotics Using Ce0.1Fe0.9OOH: Catalyst Preparation and Performance, Chemosphere, 161: 174-180 (2016).
[139]  Kermani, M., Kakavandi, B., Farzadkia, M., Esrafili, A., Jokandan, S.F., Shahsavani, A., Catalytic Ozonation of High Concentrations of Catechol over TiO2@Fe3O4 Magnetic Core-Shell Nanocatalyst: Optimization, Toxicity and Degradation Pathway Studies, Journal of Cleaner Production, 192: 597-607 (2018).
[140]  Kasprzyk-Hordern B., Chemistry of Alumina, Reactions in Aqueous Solution and its Application in Water Treatment, Advances in Colloid and Interface Science, 110(1): 19-48 (2004).
[141]  Al-Abadleh H.A., Grassian V.H., FT-IR Study of Water Adsorption on Aluminum Oxide Surfaces, Langmuir, 19(2): 341-347 (2003).
[142]  Wei, K., Cao, X., Gu, W., Liang, P., Huang, X., Zhang, X., Ni-Induced C-Al2O3-Framework (NiCAF) Supported Core–Multishell Catalysts for Efficient Catalytic Ozonation: A Structure-to-Performance Study, Environmental Science & Technology, 53(12): 6917-6926 (2019).
[143]  Dadban Shahamat, Y., Mahdi, S., Ali, S., Niloofar, O., Farshad, B.A., and Baneshi, M.M., Heterogeneous Catalytic Ozonation of 2, 4-Dinitrophenol in Aqueous Solution by Magnetic Carbonaceous Nanocomposite: Catalytic Activity and Mechanism, Desalination and Water Treatment, 57(43): 20447-20456 (2016).
[144]  Guo Y., Xu B., Qi F., A Novel Ceramic Membrane Coated with MnO2–Co3O4 Nanoparticles Catalytic Ozonation for Benzophenone-3 Degradation in Aqueous Solution: Fabrication, Characterization and Performance, Chemical Engineering Journal, 287: 381-389 (2016).
[145]  Bing, J., Hu, C., Nie, Y., Yang, M., Qu, J., Mechanism of Catalytic Ozonation in Fe2O3/Al2O3@SBA-15 Aqueous Suspension for Destruction of Ibuprofen, Environmental Science & Technology, 49(3): 1690-1697 (2015).
[146]  Bulanin K.M., Lavalley J.C., Tsyganenko A.A., IR Spectra of Adsorbed Ozone, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 101(2): 153-158 (1995).
[147]  Mashayekh-Salehi A., Moussavi G., Yaghmaeian K., Preparation, Characterization and Catalytic Activity of a Novel Mesoporous Nanocrystalline MgO Nanoparticle for Ozonation of Acetaminophen as an Emerging Water Contaminant, Chemical Engineering Journal, 310: 157-169 (2017).
[148]  Liu, Y., Wu, D., Peng, S., Feng, Y., Liu, Z., Enhanced Mineralization of Dimethyl Phthalate by Heterogeneous Ozonation over Nanostructured Cu-Fe-O Surfaces: Synergistic Effect and Radical Chain Reactions, Separation and Purification Technology, 209: 588-597 (2019).
[149]  Xu L., Wang J., The Application of Graphene-Based Materials for the Removal of Heavy Metals and Radionuclides from Water and Wastewater, Critical Reviews in Environmental Science and Technology, 47(12): 1042-1105 (2017).
[150]  Wang J., Wang S., Preparation, Modification and Environmental Application of Biochar: A Review, Journal of Cleaner Production, 227: 1002-1022 (2019).
[151]  Gonçalves A.G., Órfão J.J.M., Pereira M.F.R., Ozonation of Sulfamethoxazole Promoted by MWCNT, Catalysis Communications, 35: 82-87 (2013).
[152]  Gu L., Zhang X., Lei L., Degradation of Aqueous p-Nitrophenol by Ozonation Integrated with Activated Carbon, Industrial & Engineering Chemistry Research, 47(18): 6809-6815 (2008).
[153]  Alvárez, P.M., García-Araya, J.F., Beltrán, F.J., Giráldez, I., Jaramillo, J., Gómez-Serrano, V., The Influence of Various Factors on Aqueous Ozone Decomposition by Granular Activated Carbons and the Development of a Mechanistic Approach, Carbon, 44(14): 3102-3112 (2006).
[154]  Beltrán, F.J., J., R., P., Á., Montero-de-Espinosa, R., Kinetics of Heterogeneous Catalytic Ozone Decomposition in Water on an Activated Carbon, Ozone: Science & Engineering, 24(4): 227-237 (2002).
[155]  Liu, Z.-.Q., Ma, J., Cui, Y.-.H., Zhang, B.-.P., Effect of Ozonation Pretreatment on the Surface Properties and Catalytic Activity of Multi-Walled Carbon Nanotube, Applied Catalysis B: Environmental, 92(3): 301-306 (2009).
[156]  Sánchez-Polo M., von Gunten U., Rivera-Utrilla J., Efficiency of Activated Carbon to Transform Ozone into OH Radicals: Influence of Operational Parameters, Water Research, 39(14): 3189-3198 (2005).
[157]  Ma, Z., Zhu, L., Lu, X., Xing, S., Wu, Y., Gao, Y., Catalytic Ozonation of p-Nitrophenol over Mesoporous Mn–Co–Fe Oxide, Separation and Purification Technology, 133: 357-364 (2014).
[158]  Bai Z., Yang Q., Wang J., Catalytic Ozonation of Sulfamethazine Using Ce0.1Fe0.9OOH as Catalyst: Mineralization and Catalytic Mechanisms, Chemical Engineering Journal, 300: 169-176 (2016).
[159]  Dai, Q., Chen, L., Chen, W., Chen, J., Degradation and Kinetics of Phenoxyacetic Acid in Aqueous Solution by Ozonation, Separation and Purification Technology, 142: 287-292 (2015).
[160]  Zeng Y.-F., Liu Z.-L., Qin Z.-Z., Decolorization of Molasses Fermentation Wastewater by SnO2-Catalyzed Ozonation, Journal of Hazardous Materials, 162(2): 682-687 (2009).
[161]  Sui, M., Sheng, L., Lu, K., Tian, F., FeOOH Catalytic Ozonation of Oxalic Acid and the Effect of Phosphate Binding on its Catalytic Activity, Applied Catalysis B: Environmental, 96(1): 94-100 (2010).
[162]  Zhao, L., Ma, J., Sun, Z., Zhai, X., Mechanism of Influence of Initial pH on the Degradation of Nitrobenzene in Aqueous Solution by Ceramic Honeycomb Catalytic Ozonation, Environmental Science & Technology, 42(11): 4002-4007 (2008).
[163]  Pang, H., Wang, Y., Wu, Y., He, J., Deng, H., Li, P., Xu, J., Yu, Z., Gligorovski, S., Unveiling the pH-Dependent Yields of H2O2 and OH by Aqueous-Phase Ozonolysis of m-Cresol in the Atmosphere, Environmental Science & Technology, 56(12): 7618-7628 (2022).
[164]  Ma, J., Sui, M., Zhang, T., Guan, C., Effect of pH on MnOx/GAC Catalyzed Ozonation for Degradation of Nitrobenzene, Water Research, 39(5): 779-786 (2005).
[165]  Dong, Y., Yang, H., He, K., Wu, X., Zhang, A., Catalytic Activity and Stability of Y zeolite for Phenol Degradation in the Presence of Ozone, Applied Catalysis B: Environmental, 82(3): 163-168 (2008).
[166]  Chen, C., Wei, L., Guo, X., Guo, S., Yan, G., Investigation of Heavy Oil Refinery Wastewater Treatment by Integrated Ozone and Activated Carbon -Supported Manganese Oxides, Fuel Processing Technology, 124: 165-173 (2014).
[167]  Mehrjouei M., Müller S., Möller D., A Review on Photocatalytic Ozonation Used for the Treatment of Water and Wastewater, Chemical Engineering Journal, 263: 209-219 (2015).
[168]  Xiong, Z., Cao, J., Yang, D., Lai, B., Yang, P., Coagulation-Flocculation as Pre-Treatment for Micro-Scale Fe/Cu/O3 Process (CF-mFe/Cu/O3) Treatment of the Coating Wastewater from Automobile Manufacturing, Chemosphere, 166: 343-351 (2017).
[169]  Gharbani P., Mehrizad A., Heterogeneous Catalytic Ozonation Process for Removal of 4-Chloro-2-Nitrophenol from Aqueous Solutions, Journal of Saudi Chemical Society, 18(5): 601-605 (2014).
[170]  Almomani, F.A., Shawaqfah, M., Bhosale, R.R., Kumar, A., Removal of Emerging Pharmaceuticals from Wastewater by Ozone-Based Advanced Oxidation Processes, Environmental Progress & Sustainable Energy, 35(4): 982-995 (2016).
[171]  Tian, S.-.Q., Qi, J.-.Y., Wang, Y.-.P., Liu, Y.-.L., Wang, L., Ma, J., Heterogeneous Catalytic Ozonation of Atrazine with Mn-Loaded and Fe-Loaded Biochar, Water Research, 193: 116860 (2021).
[172]  Yu, L., Zhang, Y., Li, F., Xu, C., Efficient Catalytic Ozonation for Hexazinone Degradation by Fe/Ce-doped MOF Derivatives, Separation and Purification Technology, 344: 127277 (2024).
[173]  Chokshi, N.P., Chauhan, A., Chhayani, R., Sharma, S., Ruparelia, J.P., Preparation and Application of Ag–Ce–O Composite Metal Oxide Catalyst in Catalytic Ozonation for Elimination of Reactive Black 5 Dye from Aqueous Media, Water Science and Engineering, 17(3): 257-265 (2024).
[174]  Mohebali, H., Moussavi, G., Karimi, M., Giannakis, S., Development of a Magnetic Ce-Zr Bimetallic MOF as an Efficient Catalytic Ozonation Mediator: Preparation, Characterization, and Catalytic Activity, Separation and Purification Technology, 315: 123670 (2023).
[175]  Rezvani B., Nabavi S.R., Ghani M., Magnetic Nanohybrid Derived from MIL-53(Fe) as an Efficient Catalyst for Catalytic Ozonation of Cefixime and Process Optimization by Optimal Design, Process Safety and Environmental Protection, 177: 1054-1071 (2023).
[176]  Chen H., Wang J., MOF-Derived Co3O4-C@FeOOH as an Efficient Catalyst for Catalytic Ozonation of Norfloxacin, Journal of Hazardous Materials, 403: 123697 (2021).
[177]  Zhou, S., Cheng, H., Komarneni, S., Ma, J., Enhanced Heterogeneous Catalytic Ozonation to Degrade p-Nitrophenol by Co-Doped Ni3S2/NF Nanosheets, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 689: 133717 (2024).
[178]  Yin, X., Zhang, J., Chen, S., Li, W., Zhu, H., Wei, K., Zhang, Y., Chen, H., Han, W., Electric Field-Enhanced Heterogeneous Catalytic Ozonation (EHCO) Process for Sulfadiazine Removal: The Role of Cathodic Reduction, Chemosphere, 351: 141226 (2024).
[179]  Fidelis, M.Z., Favaro, Y.B., Santos, A.S.G.G.d., Pereira, M.F.R., Brackmann, R., Lenzi, G.G., Soares, O.S.G.P., Andreo, O.A.B., Enhancing Ibuprofen and 4-Isobutylacetophenone Degradation: Exploiting the Potential of Nb2O5 Sol-Gel Catalysts in Photocatalysis, Catalytic Ozonation, and Photocatalytic Ozonation, Journal of Environmental Chemical Engineering, 11(5): 110690 (2023).
[180]  Li, Z., Jing, J., Gao, K., Ren, G., Zhang, J., Jiao, W., Liu, Y., Degradation of Nitrobenzene by High-Gravity Intensified Heterogeneous Catalytic Ozonation with Mn-Fe/ZSM-5 Catalysts, Chemical Engineering and Processing - Process Intensification, 169: 108642 (2021).
[181]  Chen, S., Ren, T., Lu, K., Ouyang, C., Huang, X., Zhang, X., MnNx-Carbon-Silica-Framework for Highly Efficient Heterogeneous Catalytic Ozonation of Electron-Rich Organics through Nonradical Pathway, Chemical Engineering Journal, 466: 143110 (2023).
[182]  Nguyen, T.T., Trinh, T.V., Tran, D.N., Le, G.T., Le, G.H., Vu, T.A., Nguyen, T.M., Novel FeMgO/CNT Nano Composite as Efficient Catalyst for Phenol Removal in Ozonation Process, Materials Research Express, 5(9): 095603 (2018).
[183]  Xu L., Wang J., Fenton-Like Degradation of 2,4-Dichlorophenol Using Fe3O4 Magnetic Nanoparticles, Applied Catalysis B: Environmental, 123-124: 117-126 (2012).
[184]  Xu L., Wang J., Magnetic Nanoscaled Fe3O4/CeO2 Composite as an Efficient Fenton-Like Heterogeneous Catalyst for Degradation of 4-Chlorophenol, Environmental Science & Technology, 46(18): 10145-10153 (2012).
[185]  Zhang, F., Wu, K., Zhou, H., Hu, Y., Sergei, P., Wu, H., Wei, C., Ozonation of Aqueous Phenol Catalyzed by Biochar Produced from Sludge Obtained in the Treatment of Coking Wastewater, Journal of Environmental Management, 224: 376-386 (2018).
[186]  Zhao, H., Dong, Y., Wang, G., Jiang, P., Zhang, J., Wu, L., Li, K., Novel Magnetically Separable Nanomaterials for Heterogeneous Catalytic Ozonation of Phenol Pollutant: NiFe2O4 and Their Performances, Chemical Engineering Journal, 219: 295-302 (2013).
[187]  Wang, B., Xiong, X., Ren, H., Huang, Z., Preparation of MgO Nanocrystals and Catalytic Mechanism on Phenol Ozonation, RSC Advances, 7(69): 43464-43473 (2017).
[188]  Nawaz F., Cao H., Xie Y., Xiao J., Chen Y., Ghazi Z.A., Selection of Active Phase of MnO2 for Catalytic Ozonation of 4-Nitrophenol,  Chemosphere, 168: 1457-1466 (2017).
[189]  Li H., Zhou B., Degradation of Atrazine by Catalytic Ozonation in the Presence of Iron Scraps: Performance, Transformation Pathway, and Acute Toxicity, Journal of Environmental Science and Health, Part B, 54(5): 432-440 (2019).
[190]  Wang D., Xu H., Ma J., Lu X., Qi J., Song S., Strong Promoted Catalytic Ozonation of Atrazine at Low Temperature Using Tourmaline as Catalyst: Influencing Factors, Reaction Mechanisms and Pathways, Chemical Engineering Journal, 354: 113-125 (2018).
[191]  Yuan X., Xie R., Zhang Q., Sun L., Long X., Xia D., Oxygen Functionalized Graphitic Carbon Nitride as an Efficient Metal-Free Ozonation Catalyst for Atrazine Removal: Performance and Mechanism, Separation and Purification Technology, 211: 823-831 (2019).
[192]  Lü X., Zhang Q., Yang W., Li X., Zeng L., Li L., Catalytic Ozonation of 2,4-Dichlorophenoxyacetic Acid over Novel Fe–Ni/AC, RSC Advances, 5(14): 10537-10545 (2015).
[193]  Wang J., Lou Y., Zhuang X., Song S., Liu W., Xu C., Magnetic Pr6O11/SiO2@Fe3O4 Particles as the Heterogeneous Catalyst for the Catalytic Ozonation of Acetochlor: Performance and Aquatic Toxicity, Separation and Purification Technology, 197: 63-69 (2018).
[194]  Xu Y., Lin Z., Zheng Y., Dacquin J.-.P., Royer S., Zhang H., Mechanism and Kinetics of Catalytic Ozonation for Elimination of Organic Compounds with Spinel-Type CuAl2O4 and its Precursor, Science of The Total Environment, 651: 2585-2596 (2019).
[195]  Shokrollahzadeh S., Abassi M., Ranjbar M., A New Nano-ZnO/Perlite as an Efficient Catalyst for Catalytic Ozonation of Azo Dye, Environmental Engineering Research, 24(3): 513-520 (2019).
[196]  Ghuge S.P., Saroha A.K., Ozonation of Reactive Orange 4 Dye Aqueous Solution Using Mesoporous Cu/SBA-15 Catalytic Material, Journal of Water Process Engineering, 23: 217-229 (2018).
[197]  Dong Y., He K., Zhao B., Yin Y., Yin L., Zhang A., Catalytic Ozonation of Azo Dye Active Brilliant Red X-3B in Water with Natural Mineral Brucite, Catalysis Communications, 8(11): 1599-1603 (2007).
[198]  Wu J., Gao H., Yao S., Chen L., Gao Y., Zhang H., Degradation of Crystal Violet by Catalytic Ozonation Using Fe/Activated Carbon Catalyst, Separation and Purification Technology, 147: 179-185 (2015).
[199]  Tang S., Yuan D., Zhang Q., Liu Y., Zhang Q., Liu Z., Huang H., Fe-Mn Bi-Metallic Oxides Loaded on Granular Activated Carbon to Enhance Dye Removal by Catalytic Ozonation, Environmental Science and Pollution Research, 23(18): 18800-18808 (2016).
[200]  Sun Q., Lu J., Wu J., Zhu G., Catalytic Ozonation of Sulfonamide, Fluoroquinolone, and Tetracycline Antibiotics Using Nano-Magnesium Hydroxide from Natural Bischofite, Water, Air, & Soil Pollution, 230(3): 55 (2019).
[201]  Wang C., Li A., Shuang C., The Effect on Ozone Catalytic Performance of Prepared-FeOOH by Different Precursors, Journal of Environmental Management, 228: 158-164 (2018).
[202]  Rosal R., Rodríguez A., Gonzalo M.S., García-Calvo E., Catalytic Ozonation of Naproxen and Carbamazepine on Titanium Dioxide, Applied Catalysis B: Environmental, 84(1): 48-57 (2008).
[203] Luo L., Zou D., Lu D., Xin B., Zhou M., Zhai X., Ma J., Heterogeneous Catalytic Ozonation of Ciprofloxacin in Aqueous Solution Using a Manganese-Modified Silicate Ore, RSC Advances, 8(58): 33534-33541 (2018).
[204]  González-Labrada, K., Richard, R., Andriantsiferana, C., Valdés, H., Jáuregui-Haza, U.J., Manero, M.-.H., Enhancement of Ciprofloxacin Degradation in Aqueous System by Heterogeneous Catalytic Ozonation, Environmental Science and Pollution Research, 27(2): 1246-1255 (2020).