Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Application of Polymer Inclusion Membranes Composed of Cellulosetri acetate and Trioctylamine for the Decontamination of Water Solutions Containing Anionic Dye Congo Red

Document Type : Research Article

Authors
Bahareh Beigzadi 1
Leila Dolatyari 2
Mohammad Reza Yaftian 3
1 Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan, I.R. IRAN.
2 Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, I.R. IRAN.
3 Department of Chemistry, Faculty of Science, University of Zanjan. Zanjan, I.R. IRAN.
Abstract
In the present study a polymer inclusion membrane (PIM) was developed for the extraction of Congo Red (CR). A PIM composed of 40% w/w CTA, 25% w/w TOA and 35% w/w TBP was selected as the optimum PIM and characterized by determining its weight, thickness, SEM, AFM, TGA and stress/strain curve. To achieve the highest efficiency, the parameters affecting the extraction process including extraction time, shaking rate, pH, initial concentration, and extraction stoichiometry were investigated. It is shown that the developed PIM was able to efficiently extract 94.3% of CR from 50 mL water solution containing 20 mg/L CR at pH 7 after 6 h and shaking rate 200 rpm. Back-extraction of CR from 50 mL of solution containing 0.1 mol/L NH3. The selected PIM exhibited excellent performance after 3 months and good stability in 5 extraction/back-extraction cycles. The membrane was successfully used for the recovery of CR from some various water and wastewater samples. It was suggested that the extraction takes place via the formation of [TOAH+][CR-] ion-pair species. The kinetics and isotherms of the process were well described by pseudo-second order and Langmuir models, respectively. These analyses revealed the extraction might be chemical processes and maximum capacity was found to be 43.8 mg CR per 1 g of the PIM.
Keywords
Polymer inclusion membrane
Tri-n-octyl amine
Cellulose triacetate
Congo red
Kinetics
Isotherm

Subjects

[1] Yakupova E.I., Bobyleva L.G., Vikhlyantsev I.M., Bobylev A.G., Congo Red and Amyloids: History and Relationship. Bioscience Rep., 39: 1 (2019).
[2] Rasilingwani T.E., Gumbo J.R., Masindi V., Foteinis S., Removal of Congo Red Dye from Industrial Effluents using Metal Oxide-clay Nanocomposites: Insight into Adsorption and Precipitation Mechanisms. Water Resour. Ind., 13: 100253 (2024).
[3] Al-Haidari A.A., Al-Taweel S.S., Jassim L.S., Adsorptive Removal of Congo Red from Aqueous Solution by Local Chaff Surface: Thermodynamics and Kinetics Studies. Ibn AL-Haitham Jou.r for Pure. & Appl. Sci., 26: 166-177 (2017).
[4] Manzoor K., Batool M., Naz F., Nazar M.F., Hameed B.H., Zafar M.N., A Comprehensive Review on Application of Plant-based Bioadsorbents for Congo Red Removal. Biomass Convers. Biorefin., 14: 4511-37 (2024).
[5] Siddique N., Din M.I., Khalid R., Hussain Z., A Comprehensive Review on the Photocatalysis of Congo Red Dye for Wastewater Treatment. Rev. Chem. Eng., 40: 481-510 (2024).
[6] Jiraratananon R., Sungpet A., Luangsowan P., Performance Evaluation of Nanofiltration Membranes for Treatment of Effluents Containing Reactive Dye and Salt. Desalination, 130: 177-183 (2000).
[7] SenGupta A.K., Environmental Separation of Heavy Metals: Engineering Processes. CRC Press., (2001).
[8] Noble R.D., Stern S.A., Membrane Separations Technology: Principles and Applications, Elsevier) 1995).
[9] Pandey P., Chauhan R., Membranes for Gas Separation. Prog. Polym. Sci., 26: 853-893 (2001).
[10] Tor A., Arslan G., Muslu H., Celiktas A., Cengeloglu Y., Ersoz M., Facilitated Transport of Cr(III) Through Polymer Inclusion Membrane with di (2-ethylhexyl) Phosphoric Acid (DEHPA). J. Membr. Sci., 329: 169-174 (2009).
[11] Oguma K., Yoshioka O., Noro J., Sakurai H., Simultaneous Determination of Vanadium(IV) and Vanadium(V) by Flow Injection Analysis using Kinetic Spectrophotometry with Xylenol Orange. Talanta, 96: 44-49 (2012).
[12] Bahrami S., Dolatyari L., Shayani‐Jam H., Yaftian M.R., Membrane Extraction of V(V) by an Oleic Acid Plasticized Poly (Vinyl Chloride)/Aliquat® 336 Polymer Inclusion Membrane. J. Appl. Polym. Sci., 139: 52434 (2022).
[13] Jayawardane B.M., Cattrall R.W., Kolev S.D., The Use of a Polymer Inclusion Membrane in a Paper-based Sensor for the Selective Determination of Cu(II). Ana.l Chim. Acta., 803: 106-112 (2013).
[14] Nghiem L.D., Mornane P., Potter I.D., Perera J.M., Cattrall R.W., Kolev, S.D. Extraction and Transport of Metal Ions and Small Organic Compounds using Polymer Inclusion Membranes (PIMs). J. Memb.r Sci., 281: 7-41 (2006).
[15] Tajabadi F., Ghambarian M., Carrier-mediated Extraction: Applications in Extraction and Microextraction Methods. Talanta, 206: 120145 (2020).
[16] Olasupo A., Sadiq A.C., Suah F.B.M., A Novel Approach in the Removal of Ciprofloxacin Antibiotic in an Aquatic System using Polymer Inclusion Membrane. Environ. Technol. Innovation, 27: 102523 (2022).
[17] Steed J.W., Atwood J.L., Supramolecular Chemistry, John Wiley & Sons., (2022).
[18] Yan X., Zhang X., Li Q., Preparation and Characterization of CS/β-CD/Nano-ZnO Composite Porous Membrane Optimized by Box-Behnken for the Adsorption of Congo Red. Environ. Sci. pollut Res., 25: 22244-22258 (2018).
[19] Wong H.S., The removal of cationic and Anionic Dyes Using PVC Polymer Inclusion Membranes Incorporated with Aliquat 336. Discol. Umk. Edu. My., (2020).
[20] Abdul-Halim N., Idris N., Tou Y., Cellulose Triacetate Polymer Inclusion Membrane (PIM) for Dye Removal. IOP Conf. Ser.: Earth Environ. Sci., 842: 012075 (2021).
[21] Ndlovu L.N., Malatjie K.I., Chabalala M.B., Mishra A.K., Mishra S.B., Nxumalo E.N., Beta Cyclodextrin Modified Polyvinylidene Fluoride Adsorptive Mixed Matrix Membranes for Removal of Congo Red. J. Appl. Polym. Sci., 139: 52302 (2022).
[22] Sharma U., Pandey R., Basu S., Saravanan P., ZIF-67 Blended PVDF Membrane for Improved Congo Red Removal and Antifouling Properties: A Correlation Establishment Between Morphological Features and Ultra-filtration Parameters. Chemosphere, 320: 138075 (2023).
[23] Gherasim C.V., Bourceanu G., Olariu R.I., Arsene C., A Novel Polymer Inclusion Membrane Applied in Chromium(VI) Separation from Aqueous Solutions. J. Hazard. Mater., 197: 244-253 (2011).
[24] Benosmane N., Boutemeur B., Hamdi S.M., Hamdi M., Removal of Methylene Blue Dye from Aqueous Solutions using Polymer Inclusion Membrane Technology. Appl. Water Sci., 12: 104 (2022).
[25] Soo J.A.L., Makhtar M.M.Z., Shoparwe N.F., Otitoju T.A., Mohamad M., Tan L.S., Li S., Characterization and Kinetic Studies of Poly (vinylidene fluoride-co-hexafluoropropylene) Polymer Inclusion Membrane for the Malachite Green Extraction. Membranes, 11: 676 (2021).
[26] Dolatyari L., Yaftian M.R., Rostamnia S., Removal of Uranium(VI) Ions from Aqueous Solutions using Schiff Base Functionalized SBA-15 Mesoporous Silica Materials. J. Environ. Manage., 169: 8-17 (2016).
[27] Ghaderi N., Dolatyari L., Kazemi D., Sharafi H.R., Shayani‐Jam H., Yaftian M.R., Application of a Polymer Inclusion Membrane Made of Cellulose Triacetate Base Polymer and Trioctylamine for the Selective Extraction of Bismuth(III) from Chloride Solutions. J. Appl. Polym. Sci., 139: 51480 (2022).
[28] Kozlowski C.A., Walkowiak W., Applicability of Liquid Membranes in Chromium(VI) Transport with Amines as Ion Carriers, J. Membr. Sci., 266: 143-150 (2005).
[29] Sellami F., Kebiche-Senhadji O., Marais S., Couvrat N., Fatyeyeva K., Polymer Inclusion Membranes Based on CTA/PBAT Blend Containing Aliquat 336 as Extractant for Removal of Cr(VI): Efficiency, Stability and Selectivity. React. Funct. Polym., 139: 120-132 (2019).
[30] Vázquez M., Romero V., Fontàs C., Anticó E., Benavente J., Polymer Inclusion Membranes (PIMs) with the Ionic Liquid (IL) Aliquat 336 as Extractant: Effect of Base Polymer and IL Concentration on their Physical–Chemical and Elastic Characteristics. J. Membr. Sci., 455: 312-319 (2014).
[31] Kazemi D., Yaftian M.R., Kolev S.D., Selective Extraction of Bi(III) from Sulfate Solutions by a Poly (vinyl chloride) Based Polymer Inclusion Membrane Incorporating Bis (2-ethylhexyl) Phosphoric Acid as the Extractant. React. Funct. Polym., 164: 104935 (2021).
[32] احمدی، میثم؛ دولتیاری، لیلا؛ یافتیان، محمد رضا؛ تهیه یک غشاء پلیمری درون‌گیر حاوی اتر تاجی دی‌سیکلو هگزانو-18-کراون-6 و بررسی کارایی آن در استخراج کروم(VI) از محلول‌های آبی، نشریه شیمی و مهندسی شیمی ایران، (3)42: 89 تا 106 (1402).
[33] Dolatyari L., Yaftian M.R., Rostamnia S., Th(IV)/U(VI) Sorption on Modified SBA–15 Mesoporous Materials in Fixed–Bed Column. Iran. Chem. Chem. Eng., (IJCCE), 36(6): 115-125 (2017).
[34] اسدی، مهدی؛ آزرده، سهیلا؛ حذف یون فلزهای سنگین Cd2+ و  Pb2+از آب با نانو مواد متخلخل، نشریه شیمی و مهندسی شیمی ایران، (4)39: 13 تا 23 (1399).