نشریه شیمی و مهندسی شیمی ایران

نشریه شیمی و مهندسی شیمی ایران

سنتز و به‌کارگیری کلروسولفونیل‌کالیکس[4]آرن تثبیت‌شده بر روی سیلیکاژل به عنوان واکنشگر جابه‌جایی شیمیایی در NMR

نوع مقاله : علمی-پژوهشی

نویسندگان
زهرا ثروتی 1
ماندانا صابر تهرانی 1
سعید تقوایی گنجعلی 1
رضا زادمرد 2
1 دانشکده شیمی، واحد تهران شمال، دانشگاه آزاد اسلامی، تهران، ایران
2 پژوهشگاه شیمی و مهندسی شیمی ایران، تهران، ایران
چکیده
در این پژوهش، نخستا کلروسولفونیل کالیکس[4]آرن تثبیت‌شده بر روی سیلیکاژل (CSC[4]A-SiO2) سنتز شد و سپس به کمک آن طیف­های  1H-NMRمربوط به سه ترکیب شیمیایی مورد استفاده در صنعت لاستیک‌سازی مانند: دی فنیل گوانیدین (DPG)، N ـ سیکلوهگزیل ـ 2 ـ بنزوتیازول سولفنامید (CBS) و 2ـ مرکاپتوبنزوتیازول (MBT) مورد مطالعه قرار گرفت. نتیجه­های به ­دست آمده نشان داد کلروسولفونیل کالیکس[4]آرن تثبیت‌شده بر روی سیلیکاژل برای دی­فنیل­گوانیدین و N ـ سیکلوهگزیل ـ 2ـ بنزوتیازول سولفنامید (به عنوان شتاب‌دهنده در تولید ترکیب­ های صنعت لاستیک‌سازی مورد استفاده قرار می‌گیرند) به عنوان یک واکنشگر جا به­ جایی شیمیایی عمل کرده است که این امر به ­دلیل برهم‌کنش‌های الکترواستاتیک و پیوندهای هیدروژنی بین گروه‌های هیدروکسیل حلقۀ کالیکس[4]آرن و گروه NH در مولکول‌های DPG و CBS اتفاق می‌افتد. به نظر می­ رسد که اندازه مولکول مهمان در این بر همنکنش نقش اساسی بازی می ­کند.
کلیدواژه‌ها
کلروسولفونیل‌کالیکس[4]آرن تثبیت‌شده بر روی سیلیکاژل
دی‌فنیل‌گوانیدین
N ـ سیکلوهگزیل ـ 2 ـ بنزو تیازول سولفنامید
2ـ مرکاپتو بنزوتیازول
واکنشگر جابه‌جایی شیمیایی NMR

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