پیروکلر استرانسیوم آرسنات و نمونه دوپه شده آن (Sr2As2EuxO7+δ) به عنوان کاتالیست های ناهمگن قابل بازیافت در سنتز تک ظرفی، سه جزئی مشتق های 2-آمینو-H4-کرومن تحت تابش ریزموج

نوع مقاله : علمی-پژوهشی

نویسندگان

1 گروه شیمی معدنی، دانشکده شیمی، دانشگاه ارومیه، ارومیه، ایران

2 گروه شیمی معدنی، دانشکده شیمی، دانشگاه سمنان ، سمنان، ایران

3 گروه شیمی آلی، دانشکده شیمی، دانشگاه ارومیه، ارومیه، ایران

چکیده

در این مقاله روشی بسیار موثر برای سنتز مشتق ­های 2-آمینو-H4-کرومن گزارش شده است، طی واکنش تراکمی تک ظرفی، سه جزئی بین آلدهیدهای آروماتیک، مالونونیتریل و β-نفتول در حضور حلال سازگار با محیط زیست آب و تحت تابش ریزموج با استفاده از نانوکاتالیست­ های ناهمگن Sr2As2O7 و Sr2As2EuxO7+δ  به ­دست آمدند. این اولین گزارش استفاده از کاتالیست­ های مذکور در زمینه سنتز مشتق های کرومن می­ باشد. این کاتالیست ­­ها با استفاده از روش سولوترمال در دمای 180 درجه سلسیوس به مدت 24 ساعت سنتز شدند و توسط تکنیک­ های گوناگون از جمله،­UV-Vis, PXRD, FTIR, FESEM EDX, مورد شناسایی قرار گرفتند. برای انجام واکنش کاتالیستی شرایط واکنش بهینه شده و مشخص گردید زمانی که 15 میلی گرم کاتالیست­، حلال آب و زمان تابش ریزموج 6 دقیقه در واکنش نمونه به کار گرفته شود، بازده بالاتری به دست می­ آید. بررسی­ ها نشان داد که آلدهیدهای آروماتیک حاوی گروه های الکترون دهنده و الکترون کشنده می توانند محصولات مربوطه را تولید کنند اما بازده واکنش با آلدهیدهای دارای گروه های الکترون کشنده بیشتر است (99-97 درصد). کاتالیست ­های سنتزشده را می توان به آسانی بازیافت کرد و 4 بار بدون کاهش چشمگیری در فعالیت کاتالیستی، آنها را مورد استفاده مجدد قرار داد. بعد از مرحله چهارم بازده واکنش برای نمونه بدون دوپه 71 درصد و برای نمونه دوپه شده 73 درصد بدست آمد. استفاده از حلال سازگار با محیط زیست، زمان کوتاه واکنش، جداسازی آسان و تولید محصولات با بازده بالا از محاسن این روش می باشد.

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مراجع

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