واکنش جفت شدن بدون کاتالیست فلزی، سنتز مستقیم دی آریل دی چالکوژنیدهای متقارن از آریل‌هالیدها در حضور پتاسیم ترشیوبوتوکسید

نوع مقاله : علمی-پژوهشی

نویسندگان

1 گروه شیمی، دانشگاه ایلام، ایلام، ایران

2 گروه شیمی، دانشکده علوم، دانشگاه ایلام، ایلام، ایران

چکیده

در این پروژهش، در ادامه پژوهش ­ها برای سنتز دی ­آریل دی­ چالکوژنیدها با استفاده از واکنش­ های جفت شدن و در راستای تلاش برای پیدا کردن یک روش مؤثر، ساده و کلی برای تشکیل پیوند های کربن ـ چالکوژن، برای اولین بار سنتز دی ­آریل دی ­چالکوژنیدها (دی­سولفید، دی­سلنید، دی­تلورید) از آریل هالید­ها در شرایط بدون کاتالیست فلزی استفاده شد. پتاسیم ترشیو بوتوکسید می ­تواند به­ طور مؤثری واکنش جفت شدن میان آریل هالیدها (و توسیلات­ها) با عنصرهای گوگرد، سلنیوم و تلوریوم را در حلال دی ­متیل سولفوکسید و بدون کمک هیچ کاتالیست فلزی بهبود بخشد. واکنش در حضور پتاسیم ترشیو بوتوکسید با مکانیسم رادیکالی پیش رفته و در شرایط بهینه واکنش، تعدادی از مشتق­ های دی ­آریل دی سولفید، دی­آریل دی سلنید و دی­ آریل دی تلورید با بازده خوب تا درخشان و در زمان به نسبت مناسب سنتز شدند.

کلیدواژه‌ها

موضوعات


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