Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Synthesis of Nanofiber Composite Based on Biomass Derived Material Conjugated with Nanocapsules of Ni-Co Oxides as an Effective Catalyst for Oxygen Reduction Reaction and Oxygen Evolution Reaction

Document Type : Research Article

Authors
Farhad Golmohammadi
Massoud Amiri
Department of Chemistry, Kermanshah Branch, Islamic Azad University, Kermanshah, I.R. IRAN
Abstract
The development of low-cost, high-performance catalysts and the use of renewable sources for use in oxygen reduction and evolution reactions have received considerable attention. In this study, using an efficient and single-stage method using nickel-cobalt oxides and a material obtained from southern cattail or karrapo (KP) as available biomass, a catalyst with nano-fiber structures was synthesized (NFKP/Ni-Co). In order to synthesize the NFKP/Ni-Co, the Ni-Co compound, by sol-gel method in the autoclave at 200°C for 12h, was loaded on the surface of KP, and finally, it was pyrolyzed at 700°C for 3h in an argon atmosphere. The structure, composition, morphology, and catalytic activity of the synthesized nanocomposites have been investigated. The TEM studies prove the formation of 20nm of nanoparticles of Ni-Co oxides on the surface of nanofibers. Here, KP acted as a boat-like platform in which Ni-Co oxides were loaded. Due to the synergistic effect between KP and Ni-Co oxides, NFKP/Ni-Co nanocomposite exhibit remarkable catalytic activity for the oxygen reduction reaction with an initial potential of -0.15V, half wave potential of -0.32V, peak current density of 0.25 mA/cm2 and limiting current density of 0.23 mA/cm2 which is comparable to commercial Pt/C catalyst.
Keywords
Biomass
Nanofibers composite
Ni-Co oxides
Oxygen reduction reaction
Oxygen evolution reaction

Subjects

[1] Gharibi H., Golmohammadi F., Kheirmand M., Fabrication of MEA Based on Optimum Amount of Co in PdxCo/C Alloy Nanoparticles as a New Cathode for Oxygen Reduction Reaction in Passive Direct Methanol Fuel Cells, Electrochimica Acta, 89: 212-221 (2013).
[2] Gharibi H., Sadeghi S., Golmohammadi F., Electrooxidation of Ethanol on Highly Active and Stable Carbon Supported PtSnO2 and Its Application in Passive Direct Ethanol Fuel Cell: Effect of Tin Oxide Synthesis Method, Electrochimica Acta, 190: 1100-1112 (2016).
[3] Zhang J., Lv M., Liu D., Du L., Liang Z., Nitrogen-Doped Carbon Nanoflower with Superior ORR Performance in Both Alkaline and Acidic Electrolyte and Enhanced Durability, International Journal Of Hydrogen Energy, 43 (9): 4311-4320 (2018).
[4] Zhan T., Liu X., Lu S., Hou W., Nitrogen Doped NiFe Layered Double Hydroxide/Reduced Graphene Oxide Mesoporous Nanosphere as an Effective Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions, Applied Catalysis B: Environmental, 205: 551-558 (2017).
[5] Jia X., Gao S., Liu T., Li D., Tang P., Feng Y., Fabrication and Bifunctional Electrocatalytic Performance of Ternary Conimn Layered Double Hydroxides/Polypyrrole/Reduced Graphene Oxide Composite for Oxygen Reduction and Evolution Reactions, Electrochimica Acta, 245: 59-68 (2017).
[6] Gao M., Liu X., Irfan M., Shi J., Wang X., Zhang P., Nickle-Cobalt Composite Catalyst-Modified Activated Carbon Anode for Direct Glucose Alkaline Fuel Cell, International Journal Of Hydrogen Energy, 43: 1805-1815 (2018).
[7] Lin S., Shi X., Yang H., Fan D., Wang Y., Bi K., Reduced Graphene Oxide-NiCo2O4 Nanoflowers as Efficient  Electrocatalysts for the Oxygen Reduction Reaction, Journal of Alloys and Compounds, 720: 147-155 (2017).
[8] Carenco S., Wu C.-H., Shavorskiy A., Alayoglu S., Somorjai G.-A., Bluhm H., Salmeron M., Synthesis and Structural Evolution of Nickel–Cobalt Nanoparticles under H2 and CO2, Small, 11 (25): 3045-3053 (2015).
[9] Fan D., Lv X., Feng J., Zhang S., Bai J., Lu R., Liu J., Cobalt Nickel Nanoparticles Encapsulated Within Hexagonal Boron Nitride as Stable, Catalytic Dehydrogenation Nanoreactor, International Journal of Hydrogen Energy, 42 (16): 11312-11320 (2017).
[10] Tian X., Zhou M., Li M., Tan C., Liang L., Su P., Nitrogen-Doped Activated Carbon as Metal-Free Oxygen Reduction Catalyst for Cost-Effective Rolling-Pressed Air-Cathode in Microbial Fuel Cells, Fuel, 223: 422-430(2018).
[11] Farzaneh A., Saghatoleslami N., Goharshadi E.-K., Gharibi H., Ahmadzadeh H., 3-D Mesoporous Nitrogen-Doped Reduced Graphene Oxide as an Efficient Metal-Free Electrocatalyst for Oxygen Reduction Reaction in Alkaline Fuel Cells: Role of Π and Lone Pair Electrons, Electrochimica Acta, 222: 608-618 (2016).
[12] Tian X., Zhou M., Tan C., Li M., Liang L., Li K., Su P., KOH Activated N-Doped Novel Carbon Aerogel As Efficient Metal-Free Oxygen Reduction Catalyst For Microbial Fuel Cells, Chemical Engineering Journal, 348: 775-785 (2018).
[13] Tong J., Ma W., Wang W., Ma J., Li W., Bo L., Fan H., Nitrogen/Phosphorus Dual-Doped Hierarchically Porous Graphitic Biocarbon with Greatly Improved Performance on Oxygen Reduction Reaction in Alkaline Media, Journal of Electroanalytical Chemistry, 809: 163-170 (2018).
[14] Deng L., Yuan Y., Zhang Y., Wang Y., Chen Y., Yuan H., Chen Y., Alfalfa Leaf-Derived Porous Heteroatom-Doped Carbon Materials as Efficient Cathodic Catalysts in Microbial Fuel Cells, ACS Sustainable Chemistry & Engineering, 5: 9766-9773 (2017).
[15] Amiri M., Golmohammadi  F., Biomass Derived Hierarchical 3D Graphene Framework for High Performance Energy Storage Devices, Journal Of Electroanalytical Chemistry, 849: 113388 (2019)
[16] Golmohammadi F., Gharibi H., Sadeghi S., Synthesis And Electrochemical Characterization of Binary Carbon Supported Pd3Co Nanocatalyst for Oxygen Reduction Reaction in Direct Methanol Fuel Cells, International Journal of Hydrogen Energy, 41 (18): 7373-7387 (2016).
[17] Sachin Kumar B., Kalpathy S.K., Anandhan S., Synergism of Fictitious Forces on Nickel Cobaltite Nanofibers: Electrospinning Forces Revisited, Physical Chemistry Chemical Physics, 20 (7): 5295-5304 (2018).
[18] Jiang Y., Tang C., Zhang H., Shen T., Zhang C., Liu S., Hierarchical Walnut-Like Ni0.5Co0.5O Hollow Nanospheres Comprising Ultra-Thin Nanosheets for Advanced Energy Storage Devices, Journal Of Materials Chemistry A, 5 (12): 5781-5790 (2017).
[19] Zhao Y., Ma H., Huang S., Zhang X., Xia M., Tang Y., Ma Z.F., Monolayer Nickel Cobalt Hydroxyl Carbonate for High Performance All-Solid-State Asymmetric Supercapacitors, ACS Applied Materials & Interfaces, 8 (35): 22997-23005 (2016).
[20] Xu X., Chen S., Xiao C., Xi K., Guo C., Guo S., Ding S., Yu D., Kumar R.V., Rational Design of NiCoO2@SnO2 Heterostructure Attached on Amorphous Carbon Nanotubes with Improved Lithium Storage Properties, ACS Applied Materials & Interfaces, 8 (9): 6004-6010 (2016).
[21] Ensafi A.A., Moosavifard S.E., Rezaei B., Kaverlavani S.K., Engineering Onion-Like Nanoporous CuCo2O4 Hollow Spheres Derived From Bimetal–Organic Frameworks for High-Performance Asymmetric Supercapacitors, Journal of Materials Chemistry A, 6 (22): 10497-10506 (2018).
[22] Molina-García M.A., Rees N.V., “Metal-Free” Electrocatalysis: Quaternary-Doped Graphene and the Alkaline Oxygen Reduction Reaction, Applied Catalysis A: General, 553: 107-116 (2018).
[23] Kakaei K., Balavandi A., Hierarchically Porous Fluorine-Doped Graphene Nanosheets as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Gas Diffusion Electrode, Journal of Colloid And Interface Science, 490: 819-824 (2017).
[24] Zhu L., Wu J., Zhang Q., Li X., Li Y., Cao X., Chemical-Free Fabrication of N, P Dual-Doped Honeycomb-Like Carbon as an Efficient Electrocatalyst for Oxygen Reduction, Journal of Colloid and Interface Science, 510: 32-38 (2018).
[25] Khalafallah D., Alothman O.Y., Fouad H., Khalil K.A., Nitrogen and Carbon Functionalized Cobalt Phosphide as Efficient Non-Precious Electrocatalysts for Oxygen Reduction Reaction Electrocatalysis in Alkaline Environment, Journal of Electroanalytical Chemistry, 809: 96-104 (2018).
[26] Li F., Li L., Wang W., Gao J., A New Facile Approach to Prepare Reduced Graphene Oxide and MoO2/Reduced Graphene Oxide as Electrode Materials for Oxygen Reduction Reactions, Journal of Colloid and Interface Science, 519: 194-202 (2018).
[27] Zhan T., Zhang Y., Liu X., Lu S., Hou W., Nife Layered Double Hydroxide/Reduced Graphene Oxide Nanohybrid as an Efficient Bifunctional Electrocatalyst for Oxygen Evolution and Reduction Reactions, Journal of Power Sources, 333: 53-60 (2016).
[28] Takako Toda H.I., Uchida H., Watanabe M., Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co, Journal of the Electrochemical Society, 146 (10): 3750-3756 (1999).
[29] Pyun S.I., Lee S.B., Effect of Surface Groups on the Electrocatalytic Behaviour of Pt–Fe–Co Alloy-Dispersed Carbon Electrodes in the Phosphoric Acid Fuel Cell, Journal of Power Sources, 77 (2): 170-177 (1999).
[30] Wang Y., Wang Z., Wu X., Liu X., Li M., Synergistic Effect Between Strongly Coupled Coal Layered Double Hydroxides and Graphene for the Electrocatalytic Reduction of Oxygen, Electrochimica Acta, 192: 196-204 (2016).