Investigation of Sulfur Recovery Efficiency of SRUs in the Presence of Heavy Aromatic Compounds

Document Type : Research Article

Authors

Chemical Engineering Group, Engineering Faculty, Ferdowsi University of Mashhad, Mashhad, I.R. IRAN

Abstract

Claus process is a well-known industrial method to recover elemental sulfur from hydrogen sulfide in Sulfur Recovery Units (SRUs). Despite high efficiency of such units, these SRUs operate at much lower efficiencies than the standard value of 97% due to some operational shortcomings. Presence of heavy aromatic compounds such as Benzene, Toluene, and Xylene (BTX) within the acid gas feed entering the SRUs, can harmfully affect Claus catalyst performance and decrease the overall efficiency. In this research, Promax simulator was employed to simulate SRUs of Khangiran natural gas refinery. Five different scenarios were discussed to increase the temperature of combustion chamber and BTX destruction as well. Finally, the effect of BTX content entering the catalytic beds was investigated on the efficiency of catalytic beds and the overall sulfur recovery.

Keywords

Main Subjects


[1] "Sulfur Process Technology", Linde Process Plants, Inc., (2012).
[2] Schoofs G., Sulfur condensation in Claus catalyst., Hydrocarbon Process., Int. Ed., 64(2): 71-73 (1985).
[3] Campbell J.M., "Gas Conditioning and Processing", Vol. 4, Gas and Liquid Sweetening, (1982).
[4] Goodboy KP, Downing JC, Fleming HL., Sulfur and Carbon Deposition on Claus Catalysts Examined, Oil Gas J., 83(44):89-   (1985).
[5] Johnson A, Edwards T, Miller M., Techniques Curb Catalyst Deactivation at Sulfur Plant., Oil Gas J., 85(43):33-      (1987).
[6] Rameshni M, Santo S., Production of Elemental Sulphur from SO2., Arcadia, California. (2005).
[7] Collie J, Hlavinka M, Ashworth A., An analysis of BTEX Emissions from Amine Sweetening and Glycol Dehydration Facilities., "Proceedings of the Laurance Reid Gas Conditioning Conference", University of Oklahoma foundation, pp. 175-93, (1998).
[8] Shahsavand A., Modeling and Simulation of BTX Removal Process from Acid Gas, "13th Iranian National Chemical Engineering Congress & 1st International Regional Chemical and Petroleum Engineering", Kermanshah, Iran, (2010).
[9] Adab A.M., BaAqeel H.M., Crevier P.P., Hummam I.A., Al-Misfer A.S., Saudi Aramco Eliminates Claus Catalyst Deactivation Caused by Aromatics Using Activated Carbon., Saudi Aramco J. Tech., 9-19 (2007).
[10] Rameshni M., "Challenges with Thermal Combustion Stage in SRU Designs", Brimstone Sulphur Symposium, Vail, CO.
[11] Crevier PP, Clark PD, Dowling NI, Huang M., Quantifying the Effect of Individual Aromatic Contaminants on a Claus Catalyst, Saudi Aramco J. Tech., 47: 46-54 (2001).
[12] Asadi S., Hamed Mosavian M., Ahmadpour A., Effect of O2 Concentration on the Reaction Furnace Temperature and Sulfur Recovery Using a TSWEET Process Simulator, J. Chem. Eng. Process. Technol., 4: 152- (2013).
[13] Asadi S., Pakizeh M., Pourafsharichenar M., An Investigation on Effects of Catalytic Bed Temperature, Tailgas Ratio and Type of Catalytic Bed on the Sulphur Recovery Using TSWEET Process Simulator, "The Frst National Conference on Wastewater and Solid Waste Management in Oil and Energy", Iran, Tehran, (1389).
[14] Mattsson-Bose, K. and L.G. Lyddon, "Using a Process Simulator to Improve Sulphur Recovery", Sulphur-London, pp. 37-42, Jan/Feb (1997).
[15] مهدی‌پور, خورسندی، گنجی، حسن بروجردی، طراحی بهینه یک واحد صنعتی بازیافت گوگرد با خوراک گاز اسیدی رقیق، چهاردهمین کنگره ملی مهندسی شیمی ایران، تهران، دانشگاه صنعتی شریف، (1391).
[16] Flowers J., Chow T., Wong V., Tackling Contaminants in Sulfur Recovery., Sulphur, 333: 42-58 (2011).
[18] Gupta A, Bolz S, Hasegawa T., Effect of Air preheat Temperature and Oxygen Concentration on Flame Structure and Emission, J. Energ Resour-Asme, 121(3): 209-16 (1999).
[20] Parnell D., Look at Claus Unit Design, Hydrocarbon Process., Int. Ed., 64(9): 114-8 (1985).
[21] Selim H, Gupta A, Al ShohainiI A., Effect of CO2 and N2 Concentration in Acid Gas Stream on H2S Combustion, Appl. Energy, 98: 53-8 (2012).
[22] Srinivasan V, Aiken RC., Selective Absorption of H2S from CO2-Factors Controlling Selectivity Toward H2S, Fuel Process. Technol., 19(2): 141-52 (1988).
[23] Hashim SS, Mohamed AR, Bhatia S., Oxygen Separation from Air Using Ceramic-Based Membrane Technology for Sustainable Fuel Production and Power Generation, Renewable Sustainable Energy Rev., 5(2): 1284-93 (2011).