The Study of Polyacrylamide-ZnO Composite as Electrode in Electrochemical Supercapacitor

Document Type : Research Note

Authors

1 Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN

2 Nuclear Fuel Cycle School, NSTRI, Tehran, I.R. IRAN

Abstract

In this study, polyacrylamide-ZnO composites were synthesized and the behavior of the obtained composites were studied as electrode materials in electrochemical supercapacitors. The morphology, crystal structure, and thermal stability of the composites were examined by Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), Thermal Gravimetric Analysis (TGA), and FT-IR. Electrochemical properties were determined by Cyclic Voltammetry (CV). Cyclic voltammetry curves confirmed the reversible electrochemical behavior of the composites. The composite oxide content was found to be 15% of the composite’s capacity, with 30% and 50% for zinc oxide. The results indicated that although presence of zinc oxide in the composite has effective role on the electrochemical behavior of the composite, the morphology and thermal stability of the composite determined the composite’s capacity as an electrode in electrochemical supercapacitors.  

Keywords

Main Subjects


[1] Halper M.S., Ellenbogen J.C., Supercapacitors: A Brief Overview, The MITRE Corporation, McLean, Virginia, (2006)
[2] Aravinda L.S., Udaya Bhat K., Ramachandra Bhat B., Nano CeO2/Activated Carbon Based Composite Electrodes for High Performance Supercapacitor, Materials Letters, 112: 158-161 (2013).
[3] Sebastian M., Nethravathi C., Rajamathi M., Interstratified Hybrids of a-Hydroxides of Nickel and Cobalt as Supercapacitor Electrode Materials, Mater. Res. Bull., 48: 2715-2719 (2013).
[4] Shi R., Jiang L., Chunxu P., A Single - Step Process for Preparing Supercapacitor Electrodes from Carbon Nanotubes, Soft Nanoscience Lett., 1: 11–15 (2011).
[5] Beidaghi M., Wang C., Micro-Supercapacitors Based on Three Dimensional Interdigital Polypyrrole/C-MEMS Electrodes, Electrochimica Acta, 56: 9508-9514 (2011).
[6] Cong H.P., Ren X.C., Wang P., Yu S.H., Flexible Graphene–Polyaniline Composite Paper for High-Performance Supercapacitor, Energy Environ. Sci., 6: 1185-1191 (2013).
[7] Kazemi S.H., Kiani M.A., Mohamadi R., Eskandarian L., Metal–Polyaniline Nanofibre Composite for Supercapacitor Applications, Bull. Mater. Sci., 37: 1001–1006 (2014).
[8] Wang C., Zhang L., Zhang J., A Review of Electrode Materials for Electrochemical Supercapacitors, Chem. Soc. Rev., 41: 797-828 (2012).
[9] عقل آرا حسن، ساخت خازن به ظرفیت پیکوفاراد با استفاده از پلی آنیلین رسانا، مجله علوم و تکنولوژی پلیمر، 15: 35 تا 43 (1381).
[10] جمشیدی راد روح اله, قائمی مهدی, حقیقت پژوه حمیدرضا، سنتز فیلم های نازک  LiMn2O4روی گرافیت و مطالعه ساختار بلوری، شکل شناسی و ویژگی های الکتروشیمیایی آن به عنوان کاتد در باتری های قابل شارژ لیتیمی، نشریه شیمی و مهندسی شیمی ایران، (2) 27: 67 تا 76 (1387).
[11] جعفری نژاد شهریار، ابوالقاسمی حسین، احمدی سید جواد، قربانیان سهرابعلی، ویژگی های مکانیکی نانوکامپوزیت های پلی پروپیلن ـ خاک رس تهیه شده با روش مخلوط مذاب، نشریه شیمی و مهندسی شیمی ایران، (2)30: 61 تا 67 (1390).
[12] Simjoo M., Vafaie Sefti M., Dadvand Koohi A., Hasheminasab R., Polyacrylamide Gel Polymer as Water Shut-off System: Preparation and Investigation of Physical and Chemical Properties in One of the Iranian Oil Reservoirs Conditions, Iranian Journal Chemistry and Chemical Engineering (IJCCE), 26(4):99-108 (2007)
[13] Sadeghi B., Sarraf-Mamoory R, Shahverdi H.R., The Effect of LiFePO4 Coating on Electrochemical Performance of LiMn2O4 Cathode Material, Iranian Journal Chemistry and Chemical Engineering (IJCCE), 31(4): 29-34 (2012)
[14] Adelkhani H., Didehban Kh., Hayasi M., Performance Evaluation of Polyacrylamide/Silver Composite as Electrode Material in Electrochemical Capacitor, Current Applied Physics, 13: 522-525 (2013).
[16] Yan J., Wei T., Fan Z, Qian W., Zhang M., Shen X., Wei F., Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density, Adv. Funct. Mater., 21: 2366-2375 (2011).
[17] Wei W., Cui X., Chen W., Ivey D.G., Manganese Oxide-Based Materials as Electrochemical Supercapacitor Electrodes, Chem. Soc. Rev., 40: 1697-1721 (2011).
[18] Monteiro P.J.M., Chong K.P., Larsen-Basse J., Komvopoulos K., “Long Term Durability of Structural Materials” Elsevier (2001).