Cellulose Extraction and Investigation of Carboxymethyl Cellulose Production from Some Agricultural Wastes

Document Type : Research Article

Authors

Faculty of Chemical Engineering, Babol Noshirvani University of Technology, Babol, I.R. IRAN

Abstract

In this research, some agricultural wastes such as sugarcane bagasse, rice straw, wheat straw, sawdust and leaves of palm tree for production of CarboxyMethyl Cellulose (CMC) are investigated. Also, the effect of NaOH on these sources to obtain the maximum Degree of Substitutions (DS) was studied. The results showed that the maximum DSs were 0.71, 0.58, 0.41, 0.67, and 0.54 for sugarcane bagasse, rice straw, wheat straw, sawdust, and leaves of palm tree, respectively.  Also at this condition, viscosity of produced CMCs  ( 1 % w/w ) were measured   6.84, 10.8, 4.97, 4.08, and 7.71 cp for sugarcane bagasse, rice straw, wheat straw, sawdust, and leaves of palm tree at, respectively. To confirm the Carboxymethyl Cellulose production, the FT-IR of commercially obtained purified CMC and CMCs of this study were compared. According to our work, these results suggest that the agricultural wastes are appropriate candidates for production of CMC in different industries.

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[1] خواجوی ر.، مفتاحی ا.، اصفهانی ا.ج.، ستاری م.، سنتز سلولز میکروبی از سویه بومی و بررسی شبکه نانو الیافی به دست آمده از ساکاریدهای گوناگون، نشریه شیمی و مهندسی شیمی ایران، (3)31، ص. 79  (1391).
[2] امانی ح.، بررسی تولید رامنولیپید درون راکتورهای زیستی به عنوان یک مدل توسط گونه Pseudomonas aeruginosa NP2، نشریه شیمی و مهندسی شیمی ایران، (1)32: 61 تا 72 (1392).
[3] Stewart D., Lignin as a Base Material for Materials Applications: Chemistry, Application and Economics, Ind. Crops Prod., 27(2): 202–207 (2008).
[4] Varshney V. K.,. Gupta P. K, Naithani S., Khullar R., Bhatt A., Soni P. L., Carboxymethylation of α-Cellulose Isolated from Lantana Camara with Respect to Degree of Substitution and Rheological Behavior, Carbohydr. Polym., 63: 40–45 (2006).
[5] Barai B. K., Singhal R. S., Kulkarni P. R., Optimization of a Process for Preparing Carboxymethyl Cellulose from Water Hyacinth (Eichornia Crassipes), Carbohydr. Polym., 32(96): 229–231 (1997).
[7] Sun J. X., Sun X. F., Zhao H., Sun R. C., Isolation and Characterization of Cellulose from Sugarcane Bagasse, Polym. Degrad. Stab., 84: 331–339 (2004).
[8] Melia C. D., Hydrophilic Matrix Sustained Release Systems Based on Polysaccharide Carriers, Crit. Rev. Ther. Drug Carrier Syst., 8(4): 395–421 (1990).
[9] Heydarzadeh H. D., Najafpour G. D., Catalyst-Free Conversion of Alkali Cellulose to Fine Carboxymethyl Cellulose at Mild Conditions, World Appl. Sci. J., 6(4): 564–569 (2009).
[13] Bono A., Ying P.H., Yan F.Y., Muei C.L., Sarbatly R., Krishnaiah D., Synthesis and Characterization of Carboxymethyl Cellulose from Palm Kernel Cake, Adv. Nat. Appl. Sci., 3(1): 5-11 (2009).
[14] Mandal A., Chakrabarty D., Isolation of Nanocellulose from Waste Sugarcane Bagasse (SCB) and its Characterization, Carbohydr. Polym., 86(3): 1291-1299 (2011).
[15] Aguilar Vega M., Cruz Ramos C.A., Properties of Henequen Cellulosic Fibers, J. Appl. Polym. Sci., 56(10); 1245-1252 (1995).
[16] Eyler R.W., Klug E.D., Diephuis F., Determination of Degree of Substitution of Sodium Carboxymethylcellulose, Anal. Chem., 19(1):, 24-27 (1947).
[17] de Castro G. R., de Alcântara I. L., dos Roldan P., de Bozano D., Padilha M., Florentino O., Rocha J.C., Synthesis, Characterization and Determination of the Metal Ions Adsorption Capacity of Cellulose Modified with p-Aminobenzoic Groups, Mater. Res., 7(2): 329-334 (2004).