Determination of Trace Amount of Methyl Parathion Using In Situ Solvent Formation Microextraction Method (ISFME) Based on Ionic Liquids in Aqueous Samples by GC-FID

Document Type : Research Article

Author

Department of Chemistry, Faculty of Science, University of Ayatollah Alozma Borujerdi, Borujerd, I.R. IRAN

Abstract

A simple, green, precise, and sensitive method to determine trace amounts of Methyl parathion in aqueous solutions was used. In situ solvent formation microextraction based two components solvent system containing organic and aqueous phases. The organic phase contains hydrophilic ionic liquid namely 1-hexyl-3-methylimidazolium chloride [Hmim][Cl] and the aqueous phase contains an analyte of Methyl parathion. After mixing of two phases, the maximum mass transfer of the analyte from aqueous to organic phase was occurred and finally separation of phases use counter ion namely lithium bis(trifluoromethansulfonyl) imide. By adding of counter ion, hydrophilic ionic liquid [Hmim][Cl] caused anion exchange converted to hydrophobic ionic liquid [Hmim][NTF2] and phase separation was possible. Analyte enriched in organic phase after thermal desorption by using gas chromatography-flame photometry detection was determined. Effective parameters on extraction such as pH of the aqueous phase, amounts of ionic liquid, and the amount of counter-ion was evaluated and optimized. Figures of merit such as precision in the form of percent Relative Standard Deviation (RSD) for 7 replicate measurements equal to 1.2%, quantity Limit of Detection (LOD) of 0.39 µg/L, enrichment factor of 125, and linear range of 10-150 µg/L were obtained. Finally, the method was used successfully to determine amounts of methyl parathion in different aqueous and saline samples.

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References

[1] Deshpande K., Mishra R.K., Bhand S., Determination of Methyl Parathion in Water and its Removal on Zirconia using Optical Enzyme Assay, Appl. Biochem. Biotechnol., 164: 906–917 (2011).
[2] Tiwari N., Asthana A., Upadhyay K., Kinetic-Spectrophotometric Determination of Methyl Parathion in Water and Vegetable, Spectrochim. Acta Part A, 101: 54–58 (2013).
[3] Pahlavanzadeh  H., Khayati G., Ghaemi N., Vasheghani-Farahani E., Liquid-Liquid Extraction of 2,3-Butanediol from Fermentation Broth, Iran. J. Chem. Chem. Eng. (IJCCE), 31(2): 59–63 (2012).
[4] Hosseini M., Dalali N., Karimi A., Dastanra K., Solid Phase Extraction of Copper, Nickel, and Cobalt in Water Samples after Extraction using Surfactant Coated Alumina Modified with Indane-1,2,3-trione 1,2-Dioxime and Determination by Flame Atomic Absorption Spectrometry, Turk. J. Chem., 34: 805–814 (2010).
[5] Hosseini M., Dalai N., Mohammadnejad S., Preconcentration of Trace Amounts of Copper(II) on Octadecyl Silica Membrane Disks Modified with Indane-1,2,3-trione 1,2-dioxime Prior to Its Determination by Flame Atomic Absorption Spectrometry, Int. J. Ind. Chem., 3: 1–6 (2012).
[6] Xiang G., Wen S., Jiang X., Liu x., He L., Determination of Trace Copper (II) in Food Samples by Flame Atomic Absorption Spectrometry after Cloud Point Extraction, Iran. J. Chem. Chem. Eng. (IJCCE), 30(3): 101–107 (2011).
[7] Prasad R., Sirkar K.K., Hollow Fiber Solvent Extraction: Performances and Design, J. Member. Sci., 50(2): 153–175 (1990).
[8] Fouladvandi B., Elhami S., Ultra-Trace Determination of Silver in Water, Soil and Radiology Film Samples using Dispersive Liquid-Liquid Microextraction and Microvolume UV–Vis Spectrophotometry, Iran. J. Chem. Chem. Eng. (IJCCE), 36(6): 163–170 (2017).
[9] Berijani S., Sadigh M., Pournamdari E., Homogeneous Liquid-Liquid Microextraction for Determination of Organophosphorus Pesticides in Environmental Water Samples Prior to Gas Chromatography-Flame Photometric Detection, J. Chromatogr. Sci., 54(6): 1061–1067 (2016).
[10] Anbia M., Khazaei M., Ordered Nanoporous Carbon based Solid-Phase Microextraction for the Analysis of Nitroaromatic Compounds in Aqueous Samples, Iran. J. Chem. Chem. Eng. (IJCCE), 33(4): 29–39 (2014).
[11] Ide A.H., Nogueira J.M.F., Hollow Fiber Microextraction: A New Hybrid Microextraction Technique for Trace Analysis, Anal. Bioanal. Chem., 410(12): 2911–2920 (2018).
[12] Baghdadi M., Shemirani F., Cold-Induced Aggregation Microextraction: A Novel Sample Preparation Technique Based on Ionic Liquids, Anal. Chim. Acta, 613(1): 56–63 (2008).
[13] Lopez-Darias J., Germ an-Hernandez M., Pino V., Afonso A.M., Dispersive Liquid-Liquid Microextraction Versus Single-Drop Microextraction for the Determination of Several Endocrine-Disrupting Phenols From Seawaters, Talanta, 80(5): 1611–1618 (2010). 
[14] Hosseini M., Dalali N., Mohammad-Nejad S., A New Mode of Homogeneous Liquid–Liquid Microextraction (HLLME) Based on Ionic Liquids: In Situ Solvent Formation Microextraction (ISFME) for Determination of Lead, J. Chin. Chem. Soc., 59: 872–878 (2012).
[15] Jamali M.R., Soleimani B., Rahnama R., Rahimi S.H.A, Development of an In Situ Solvent Formation Microextraction and Preconcentration Method based on Ionic Liquids for the Determination of Trace Cobalt (II) in Water Samples by Flame Atomic Absorption Spectrometry, Arabian J. Chem., 10: 321–327 (2017).
[16] Berthod A., Ruiz-Angel M.J., Carda-Broch S., Ionic Liquids in Separation Techniques, J. Chromatogr. A, 1184: 6–18 (2008).
[17] Hosseini M., Dalali N., Moghadasifar S., Ionic Liquid for Homogeneous Liquid−Liquid Microextraction Separation/Preconcentration and Determination of Cobalt in Saline Samples, J. Anal. Chem., 69: 1141–1146 (2014).
[18] Hosseini M., Dalali N., Mohammadnejad S., Jamali R., In Situ Solvent Formation Microextraction based on Ionic Liquids and 1-(2-Hydroxynaphtalene-1-yl)ethane Oxime for Determination of Zinc, J. Braz. Chem. Soc., 23(1): 78–84 (2012).
[19] Hosseini M., Dalali N., Use of Ionic Liquids for Trace Analysis of Methyl Tert-Butyl Ether in Water Samples using In Situ solvent Formation Microextraction Technique and Determination by GC/FID, Sep. Sci. Technol., 49: 1889–1894 (2014).
[20] Zhang Y.,  Yang X.,  Wang  J., Zhou  W., Lu  R., Gao H., Zhang S., In Situ Solvent Formation Microextraction Combined with Magnetic Dispersive Micro Solid Phase Extraction for the Determination of Benzoylurea Insecticides in Water Samples, J. Sep. Sci., 40(2): 442–448 (2017).
[21] Majidi B., Shemirani F., In Situ Solvent Formation Microextraction in the Presence of Ionic Liquid for Preconcentration and Speciation of Arsenic in Saline Samples and Total Arsenic in Biological Samples by Electrothermal Atomic Absorption Spectrometry, Biol. Trace Elem. Res., 143(1): 579–90 (2011).
[22] Baghdadi M., Shemirani F., In Situ Solvent Formation Microextraction Based on Ionic Liquids: A Novel Sample Preparation Technique for Determination of Inorganic Species in Saline Solutions, Anal. Chim. Acta, 634(2): 186–91 (2009).
[23] Zhao L., Zha F., Zeng B., Electrochemical Determination of Methyl Parathion Using a Molecularly Imprinted Polymer–Ionic Liquid–Graphene Composite Film Coated Electrode, Sens. Actuators B, 176: 818–824 (2013).
[24] Wenzhi T., Jiazheng Z., Qunqing Y.,  Qiqi Z.,  Jian W., Determination of Methyl Parathion by Solid-Phase Extraction on an Ionic liquid–Carbon Nanotube Composite Electrode, Anal. Methods, 6: 5886–5890 (2014).
[25] Huddleston, J.G., Visser A.E., Reichert W.M., Willauer H.D., Broker G.A., Rogers R.D., Characterization and Comparison of Hydrophilic and Hydrophobic Room Temperature Ionic Liquids Incorporating the Imidazolium Cation, Green Chem., 3: 156–164 (2001).
[26] Xue X., Wei Q., Wu D., Li H., Zhang Y., Feng R., Du B., Determination of Methyl Parathion by a Molecularly Imprinted Sensor Based on Nitrogen Doped Graphene Sheets, Electrochim. Acta, 116: 366–371 (2014).
[27] Doumandji L., Moussiden A., Ihdene Z., Hamada B., Hydrolytic Decontamination of Methyl Parathion in the Presence of 2-aminoethanol: Kinetics Study, J. Pestic. Sci., 43(1): 41–46 (2018).
[28] Govindasamy M., Mani V., Chen S.M., Chen T.W., Sundramoorthy A.K., Methyl Parathion Detection in Vegetables and Fruits using Silver@Graphene Nanoribbons Nanocomposite Modified Screen Printed Electrode, Sci. Rep., 7: 46471–46482 (2017).
[29] Da Silva D.F., Paiva Silva F.E., Silva F.G., Nunes G.S., Badea M., Direct Determination of Methyl Parathion Insecticide in Rice Samples by Headspace Solid-phase Microextraction-Gas Chromatography-Mass Spectrometry, Pest. Manag. Sci., 71(11): 1497–502 (2015).
[30] Huang B., Zhang W.D., Chen C.H., Yu Y.X., Electrochemical Determination of Methyl Parathion at a Pd/MWCNTs-Modified Electrode, Microchim. Acta, 171: 57–62 (2010).
Nashrieh Shimi va Mohandesi Shimi Iran
Volume 40, Issue 4 - Serial Number 102
December 2021
Pages 247-259

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