Impact of Operating Conditions on Crystallization Fouling of Calcium Sulfate on Heat Transfer Surfaces

Document Type : Research Article

Authors

Department of Chemical Engineering, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz, I.R. IRAN

Abstract

Deposit formation on heat transfer surfaces in heat exchangers is one of the most chronic problems in many industries. It causes flow mal-distribution, increased pressure drop, excessive fuel consumption, and generally reduction of the exchanger thermal efficiency. It is therefore indispensable to investigate fouling mechanisms as well as the impact of various operating conditions. These would, in turn, help to develop mitigation strategies. Water is the most widely used as working fluid in heat exchangers due to its high heat capacity, redundancy, and low price. However, the presence of various ions, such as calcium, carbonate, and sulfate in water, causes the formation of calcium sulfate and/or calcium carbonate deposits in heat exchangers. In this study, the effect of operating conditions including fluid velocity, calcium sulfate concentration, and heat flux on the formation of calcium sulfate deposit has experimentally been investigated. For doing so, firstly, the impact of these parameters on deionized water was examined under clean condition. The results of fouling experiments showed that increased heat flux and concentration of calcium sulfate resulted in intensified deposit formation as well as increased surface temperature and thermal resistance, which all would give rise in reduction of heat transfer coefficient. In contrast, the higher that fluid velocity is, the lower would be the deposition, surface temperature, and thermal resistance.

Keywords

Main Subjects


[1] سرمستی امامی م.ر.، غلامی ع.ر.، بررسی تحلیلی اثر رسوبات و کیفیت آب ورودی بر خوردگی لوله‌های تبادلگر دیگی.  نشریه شیمی و مهندسی شیمی ایران، (4)39: 225-235 (1398).
[2] Malayeri M.R., Al‐Janabi A., Müller‐Steinhagen H., Application of Nano‐Modified Surfaces for Fouling Mitigation, International Journal of Energy Research, 33(13): 1101-1113 (2009).
[3] Nategh M., Malayeri M.R., Mahdiyar, H., A Review on Crude Oil Fouling and Mitigation Methods in Pre-Heat Trains of Iranian Oil Refineries, Journal of Oil, Gas and Petrochemical Technology, 4(1): 1-17 (2017).
[4] Al-Janabi A., Malayeri M.R., Innovative Non-Metal Heat Transfer Surfaces to Mitigate Crystallization Fouling. International Journal of Thermal Sciences138: 384-392 (2019).
[5] Al-Janabi A.K.A., Convective Heat Transfer Fouling of Aqueous Solutions on Modified Surfaces, Ph.D. Thesis, The University of Stuttgart, Germany (2011).
[6] Nikoo A.H., Malayeri M.R., Incorporation of Surface Energy Properties into General Crystallization Fouling Model for Heat Transfer SurfacesChemical Engineering Science215: 115461 (2020).
[7] Najibi S.H., Müller-Steinhagen H., Jamialahmadi M., Calcium Sulphate Scale Formation during Subcooled Flow Boiling, Chemical Engineering Science52(8): 1265-1284 (1997).
[8] Bansal B., Müller-Steinhagen H., Crystallization Fouling in Plate Heat ExchangersJournal of Heat Transfer115(3): 584-591 (1993).
[9] Helalizadeh A., Müller-Steinhagen H., Jamialahmadi M., Mixed Salt Crystallisation FoulingChemical Engineering and Processing: Process Intensification39(1): 29-43 (2000).
[10] Bohnet M., Fouling of Heat Transfer SurfacesChemical Engineering & Technology10(1): 113-125 (1987).
[11] Hasson D., Zahavi J., Mechanism of Calcium Sulphate Scale Deposition on Heat Transfer SurfacesIndustrial & Engineering Chemistry Fundamentals9(1): 1-10 (1970).
[12] Kukulka D.J., Devgun M., Fluid Temperature and Velocity Effect on FoulingApplied Thermal Engineering27(16): 2732-2744 (2007).
[13] Kho T., Zettler H.U., Müller-Steinhagen H., Hughes D., Effect of Flow Distribution on Scale Formation in Plate and Frame Heat ExchangersChemical Engineering Research and Design75(7): 635-640 (1997).
[14] Bott T.R., Fouling of Heat Exchangers, Elsevier (1995).
[15] Malayeri M.R., Müller-Steinhagen H., Bartlett T.H., Fouling of Tube Bundles under Pool Boiling ConditionsChemical Engineering Science60(6): 1503-1513 (2005).
[16] Jamialahmadi M., Blöchl R., Müller-Steinhagen H., Bubble Dynamics and Scale Formation during Boiling of Aqueous Calcium Sulphate Solutions, Chemical Engineering and Processing: Process Intensification, 26(1): 15-26 (1989).