Synthesis, Characterization, Structural Study, Hirshfeld Surface Analysis and Antibacterial Activity of a New Dithiophosphorus Compound with a P(S)(S)(N)(C) Skeleton
In the present study, the new compound from Dithiophosphorus with the formula [(S–) (S)P(OC6H4-p-CH3) (NHCH2CH2NH(Me)2) +] was prepared and determined by IR spectroscopy, 1H, 13C NMR, 31P NMR, elemental analysis and single crystal X-ray diffraction analysis. Structural analysis revealed that the compound was crystallized in monoclinic crystal system with P21/c space group. The crystal structure of the compound showed that asymmetric unit contains two molecules and the phosphorus atom displayed P(S)(S)(N)(C) a distorted tetrahedral environment. In the crystal structure N-H…S=P H-bonding produced a one dimensional molecular structure along the b axis. This pattern contains R_2^2 (7) and R_2^2 (8) motifs. Hirshfeld surfaces and two-dimensional fingerprint plots are generated using the Crystal Explorer software program in which the CIF input file is used. These analyses revealed that H…H interactions had 51.1 % and 50.9 % portions of total interactions for the two molecules. Antibacterial properties of the new compound were additionally tested against E. coli, P. aeruginosa, S. aureus and B. cereus.
Saadat, A. (2021). Synthesis, Characterization, Structural Study, Hirshfeld Surface Analysis and Antibacterial Activity of a New Dithiophosphorus Compound with a P(S)(S)(N)(C) Skeleton. Nashrieh Shimi va Mohandesi Shimi Iran, (), -.
MLA
Afshin Saadat. "Synthesis, Characterization, Structural Study, Hirshfeld Surface Analysis and Antibacterial Activity of a New Dithiophosphorus Compound with a P(S)(S)(N)(C) Skeleton". Nashrieh Shimi va Mohandesi Shimi Iran, , , 2021, -.
HARVARD
Saadat, A. (2021). 'Synthesis, Characterization, Structural Study, Hirshfeld Surface Analysis and Antibacterial Activity of a New Dithiophosphorus Compound with a P(S)(S)(N)(C) Skeleton', Nashrieh Shimi va Mohandesi Shimi Iran, (), pp. -.
VANCOUVER
Saadat, A. Synthesis, Characterization, Structural Study, Hirshfeld Surface Analysis and Antibacterial Activity of a New Dithiophosphorus Compound with a P(S)(S)(N)(C) Skeleton. Nashrieh Shimi va Mohandesi Shimi Iran, 2021; (): -.
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