Taguchi Experimental Design for Simultaneous Absorption of Chromium and Copper from Wastewater by Chitosan

Document Type : Research Article

Authors

Faculty of Petroleum, Gas, and Petrochemical Engineering (FPGPE), Persian Gulf University (PGU), P.O. Box 75169-13817 Bushehr, I.R. IRAN

Abstract

The aim of this study is the parametric optimization of simultaneous absorption of chromium and copper from wastewater by chitosan by using Taguchi experimental design. So chitosan of Shrimp was used as an adsorbent. Experiments were performed in batch mode. The effect of five parameters including adsorbent dosage, contact time, pH (each case in 4 levels), temperature and initial concentration (each case in 3 levels) were investigated. The results clearly show that adsorbent dosage and temperature has the highest and lowest effect in the removal efficiency, respectively. Maximum efficiency for simultaneous removal of chromium and copper was obtained 86.04% and 79.06%, respectively, at the condition of 20 ppm concentration, 0.16 g adsorbent dosage at pH 4 and contact time of 90 min. Adsorbent kinetic obey the pseudo-second-order model.

Keywords


[1] علی محمدی زنجانی، مژگان؛ ابوالحمد، گیتی؛ کشتکار، علیرضا؛ بررسی جذب بیولوژیکی جهت جداسازی فلزات سنگین از پساب‌ها – مورد دو جزئی سرب و مس، "نهمین کنگره ملی مهندسین شیمی ایران"، دانشگاه علم و صنعت ایران، (1383).
[2] صفی­خانی، لیلا؛ نیرآبادی، رضا؛ سپهوند، سمیه؛ عبادی، تقی؛ بررسی اثر پارامترهای مختلف در جذب فلزات سنگین توسط کیتوسان، "اولین همایش ملی برنامه ریزی حفاظت، حمایت از محیط زیست و توسعه پایدار"، همدان دانشگاه شهید مفتح، (1392)
[3] Heidari A., Younesi H., Mehraban Z., Heikkinen H., Selective Adsorption of Pb(II), Cd(II), and Ni(II) Ions from Aqueous Solution Using Chitosan–MAA Nanoparticles, International Journal of Biological Macromolecules, 61: 251-263 (2013).
[4] Zareie C., Najafpour G., Sharifzadeh baei M., Preparation of Nano Chitonsan as an Effective Sorbent for the Removal of Copper Ions from Aqueous Solutions, Ije Transactions B: Applications, 8: 829-836 (2013).
[5] Md. Tajuddin Sikder, Yoshihiro Mihara, Md. Shariful Islam, Takeshi Saito, Shunitz Tanakaa, Masaaki Kurasaki., Preparation and Characterization of Chitosan–Caboxymethyl-Bcyclodextrin Entrapped Nanozero-Valent Iron Composite for Cu (II) and Cr (IV) Removal From Wastewater, Chemical Engineering Journal, 236: 378-387 (2014).
[7] Faghihian H., Rasekh M., Removal of Chromate from Aqueous Solution by a Novel Clinoptilolite-Polyanillin Composite, Iran. J. Chem. Chem. Eng. (IJCCE), 33(1): 254-      (2014).
[8] Ranjit K., “Design of Experiments Using the Taguchi Approach”, John Wiley& Sons, Inc.,
New York (2001).
[9] Ranjit K., “A Primer on the Taguchi Method”, Society of Manufacturing Engineers, Birminghom (1990).
[10] علیزاده، رضا؛ عابدینی، سوده؛ نبی بیدهندی، غلامرضا؛ عموعابدینی، قاسم؛ حذف سرب از پساب صنایع باتری‌سازی
با استفاده از نانوذرات مغناطیسی آهن
، نشریه شیمی و مهندسی شیمی ایران، (1)30: 71 تا 77 (1390).
[11] Han j, Du Zh., Zou W., Li L., Zhang Ch., In-Situ Improved Phenol Adsorption at Ions-Enrichment Interface of Porous Adsorbent for Simultaneous Removal of Copper Ions and Phenol, Chemical Engineering Journal, 262: 571-580 (2015).
[12] Z. Kyzas G., Kostoglou M., K. Lazaridis N., Copper and Chromium (VI) Removal by Chitosan Derivatives-Equilibrium and Kinetic Studies, Chemical Engineering Journal, 152: 440-448 (2009).