Synthesis of Fe3O4/Graphene Nanocomposite and Investigation of Their Catalytic Activity on Thermal Decomposition of Ammonium Perchlorate Particles

Document Type : Research Article

Authors

Department of Chemistry, Malek Ashtar University of Technology, P.O. Box 16765-3454 Tehran, I.R. IRAN

Abstract

In this study, Fe3O4/ graphene nanocomposite was prepared by a gas/liquid interface reaction and characterized by XRD, IR and SEM techniques. Transmission electron microscope images revealed that the ultrafine Fe3O4 NPs are homogeneously deposited on the supporting G-O sheets and graphene oxide sheets could hinder the aggregation of Fe3O4 NPs. Then, the catalytic performance of the synthesized material on the thermal decomposition of ammonium perchlorate (AP) was investigated by ThermoGravimetry Analysis (TGA) and differential scanning calorimetry (DSC) techniques. The results of the thermal analysis showed that the composites exhibit better catalytic effect for the thermal decomposition of ammonium perchlorate than Fe3O4 NPs due to the combination of graphene sheets and Fe3O4 NPs.

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Main Subjects


[1] Berger C., Song Z., Li X., Wu X., Brown N., Naud C., Mayou D., Li T., Hass J., Marchenkov A.N., Electronic Confinement and Coherence in Patterned Epitaxial Graphene, Science, 312: 1191-1196 (2006).
[2] Geim A.K., Novoselov K.S., The Rise of Graphene, Nat. Mater., 6(3): 183-191 (2007).
[3] Naseri A., Barati R., Rasoulzadeh F., Bahram M., Studies on Adsorption of Some Organic Dyes from Aqueous Solution onto Graphene Nanosheets, Iran. J. Chem. Chem. Eng. (IJCCE), 34(2): 51-60 (2015). 
[4] lake P. B, Brimicombe P.D., Nair R.R., Booth T.J., Jiang D., Schedin F., Ponomarenko L.A., Morozov S.V., Gleeson H.F., Hill E.W., Graphene-Based Liquid Crystal Device, Nano Lett., 8(6): 1704-1708 (2008).
[5]  Arsat R., Breedon M., Shafiei M., Spizziri P., Gilje S., Kaner R., Kalantar-zadeh K., Wlodarski W., Graphene-Like Nano-Sheets for Surface Acoustic Wave Gas Sensor Applications, Chem. Phys. Lett., 467 (4): 344-347(2009).
[7]  Zh J.i, Tian-Fang W., Shu-Fen L., Feng-Qi Z., Zi-Ru L., Cui-Mei, Y. Yang L., Shang-Wen L., Gang-Zhui Z., Thermal Behavior of Ammonium Perchlorate and Metal Powders of Different Grades, J. Therm. Anal. Calorim., 85 (2): 315-320 (2005).
[8] Zarrin Ghalam Moghaddam A., Hashemi Pour Rafsanjani A.A., The Role of Boron in Thermal Decomposition of Ammonium Perchlorate, Iran. J. Chem. Chem. Eng. (IJCCE), 19(1): 40-42 (2000).
[11]  Zhang Y., Wang  N., Huang Y., Wu W., Huang  C., Meng  C., Fabrication and Catalytic Activity of Ultra-Long V2O5 Nanowires on the Thermal Decomposition of Ammonium Perchlorate, Ceram. Int., 40 (7): 11393-11398 (2014).
[13] Liu E., Zhang W., Zheng J. G., Hu X., Ou H., Du R., Kou C., Zhai Y., Xu Q., Du J., Inverse Magnetoresistance in Textured Fe3O4 Film, J. Alloys Compd., 649: 239-243 (2015).
[14]  Urbanova V., Magro M., Gedanken A., Baratella D., Vianello F., Zboril R., Nanocrystalline Iron oxides, Composites, and Related Materials as a Platform for Electrochemical, Magnetic, and Chemical Biosensors, Chem. Mater., 26 (23): 6653-6673 (2014).
[16] Stankovich S., Dikin D.A., Dommett G.H., Kohlhaas K.M., Zimney E.J., Stach E.A., Piner R.D., Nguyen S.T., Ruoff R.S., Graphene-Based Composite Materials, Nature, 442: 282-286 (2006). 
[18]  Becerril H.A., Mao J., Liu Z., Stoltenberg R.M., Bao Z., Chen Y., Evaluation of Solution-Processed Reduced Graphene Oxide Films as Transparent Conductors, ACS Nano., 2(3): 463-470 (2008).
[19] Lu A.H., Salabas E.e.L., Schüth F., Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application, Angew. Chem. Int. Ed., 46: 1222-1244 (2007).
[20] Cui Z. M., Jiang  L. Y., Song W. G., Guo Y. G., High-Yield Gas− Liquid Interfacial Synthesis of Highly Dispersed Fe3O4Nanocrystals and Their Application in Lithium-Ion Batteries, Chem. Mater., 21 (6): 1162-1166 (2009).
[21] Shi R., Yan L., Xu T., Liu D., Zhu Y., Zhou J., Graphene Oxide Bound Silica for Solid-Phase Extraction of 14 Polycyclic Aromatic Hydrocarbons in Mainstream Cigarette Smoke, J. Chromatogr. A., 1375: 1-7 (2015).
[22] Zaitsev V.S., Filimonov D.S., Presnyakov I.A., Gambino R.J., Chu B., Physical and Chemical Properties of Magnetite and Magnetite-Polymer Nanoparticles and Their Colloidal Dispersions, J. Colloid Interface Sci., 212 (1): 49-57(1999).
[25] Li N., Geng  Z., Cao M., Ren L., Zhao X., Liu B., Tian Y., Hu C., Well-Dispersed Ultrafine Mn3 O4 Nanoparticles on Graphene as a Promising Catalyst for the Thermal Decomposition of Ammonium Perchlorate, Carbon, 54: 124-132 (2013).
[26] Yuan Y., Jiang W., Wang Y., Shen P., Li F., Li P., Zhao F., Gao H, Hydrothermal Preparation of Fe2 O3/Graphene Nanocomposite and Its Enhanced Catalytic Activity on the Thermal Decomposition of Ammonium Perchlorate, Appl. Surf. Sci, 303 (1): 354-359 (2014).
[27] Zhu J., Zeng G., Nie F., Xu X., Chen S., Han Q., Wang X, Decorating Graphene Oxide with CuO Nanoparticles in a Water–Isopropanol System. Nanoscale., 2(6): 988-994 (2010).