Effects of Clay on the Performance of Ultrafiltration Membrane for Landfill Leachate Treatment

Document Type : Research Article

Authors

Babol Noshirvany University of Technology, Babol, I.R. IRAN

Abstract

This study investigates the effect of different concentrations of clay on the structure and performance of polysulfone (PSf) UltraFiltration (UF) membranes for landfill leachate treatment. The membranes were prepared by phase inversion method via dissolving PSf powder in N-methyl-2-pyrrolidone (NMP) solvent at the presence of different content of clay. Performance and fouling behavior of prepared membranes were evaluated using a lab-scale cross-flow setup. The structure and morphology of the modified membranes were investigated by Field Emission ScanningElectron Microscopy(FESEM), Atomic Force Microscopy (AFM) and Energy Dispersive X-ray (EDX). The results confirmed that the adsorbent-modified UF membranes had higher flux and improved COD removal in comparison to the neat membrane. COD removal and NOM removal for 1.5% clay membrane was 35% and 51% respectively, and It was higher than the neat membrane (24% COD removal and 34% NOM removal). As the neat membrane was capable of reducing the COD by only 24%, It can be concluded that the addition of the adsorbents significantly enhanced the overall performance of the ultrafiltration membrane.

Keywords

Main Subjects


[1] Wiszniowski J., Robert D., Surmacz-Gorska J., Miksch K., Weber J., Landfill Leachate Treatment Methods: A Review, Environmental Chemistry Letters, 4: 51-61 (2006).
[2] Chian E.S., Dewalle F.B., Sanitary Landfill Leachates and Their Treatment, Journal of
the Environmental Engineering Division
, 102: 411-431 (1976).
[3] Renou S., Givaudan J., Poulain S., Dirassouyan F., Moulin P., Landfill Leachate Treatment: Review and Opportunity, Journal of Hazardous Materials, 150: 468-493 (2008).
[4] Foo K., Hameed B., An Overview of Landfill Leachate Treatment via Activated Carbon Adsorption Process, Journal of Hazardous Materials, 171: 54-60 (2009).
[5] Trebouet D., Schlumpf J., Jaouen P., Quemeneur F., Stabilized Landfill Leachate Treatment
by Combined Physicochemical–Nanofiltration Processes,
Water Research, 35: 2935-2942 (2001).
[6] Kjeldsen P., Barlaz M.A., Rooker A.P., Baun A., Ledin A., Christensen T.H., Present and Long-Term Composition of MSW Landfill Leachate: A Review, Critical Reviews in Environmental Science and Technology, 32: 297-336 (2002).
[7] Li N.N., Fane A.G., Ho W.W., Matsuura T., “Advanced Membrane Technology and Applications”, John Wiley & Sons, Inc., (2011).
[9] Ballinas L., Torras C., Fierro V., Garcia-Valls R., Factors Influencing Activated Carbon-Polymeric Composite Membrane Structure and Performance, Journal of Physics and Chemistry of Solids, 65: 633-637 (2004).
[10] Ghaemi N., Madaeni S.S., Alizadeh A., Rajabi H., Daraei P., Preparation, Characterization and Performance of Polyethersulfone/Organically Modified Montmorillonite Nanocomposite Membranes in Removal of Pesticides, Journal of Membrane Science, 382: 135-147 (2011).
[11] Mierzwa J.C., Arieta V., Verlage M., Carvalho J., Vecitis C.D., Effect of Clay Nanoparticles on the Structure and Performance of Polyethersulfone Ultrafiltration Membranes, Desalination, 314: 147-158 (2013).
[12] Rahimpour A., Madaeni S.S., Jahanshahi M., Mansourpanah Y., Mortazavian N., Development of High Performance Nano-Porous Polyethersulfone Ultrafiltration Membranes with Hydrophilic Surface and Superior Antifouling Properties, Applied Surface Science, 255: 9166-9173 (2009).
[13] Alsari A.M., Khulbe K., Matsuura T., The Effect of Sodium Dodecyl Sulfate Solutions
as Gelation Media on the Formation of PES Membranes,
Journal of Membrane Science, 188: 279-293 (2001).
[14] Mollahosseini A., Rahimpour A., Jahamshahi M., Peyravi M., Khavarpour M., The Effect of Silver Nanoparticle Size on Performance and Antibacteriality of Polysulfone Ultrafiltration Membrane, Desalination, 306: 41-50 (2012).
[16] Yunos M.Z., Harun Z., Basri H., Ismail A.F., Studies on Fouling by Natural Organic Matter (NOM) on Polysulfone Membranes: Effect of Polyethylene Glycol (PEG), Desalination, 333: 36-44 (2014).
[17] Zirehpour A., Rahimpour A., Seyedpour F., Jahanshahi M., Developing New CTA/CA-Based Membrane Containing Hydrophilic Nanoparticles to Enhance the Forward Osmosis Desalination, Desalination, 371: 46-57 (2015).
[18] Gumı T., Valiente M., Khulbe K., Palet C., Matsuura T., Characterization of Activated Composite Membranes by Solute Transport, Contact Angle Measurement, AFM and ESR, Journal of Membrane Science, 212(12): 134-3 (2003).
[19] Rajabi H., Ghaemi N., Madaeni S.S., Daraei P., Khadivi M.A., Falsafi M., Nanoclay Embedded Mixed Matrix PVDF Nanocomposite Membrane: Preparation, Characterization and Biofouling Resistance, Applied Surface Science, 313: 207-214 (2014).
[20] Ma Y., Shi F., Zhao W., Wu M., Zhang J., Ma J., Gao C., Preparation and Characterization of PSf/Clay Nanocomposite Membranes with LiCl as a Pore Forming Additive, Desalination, 303: 39-47 (2012).
[21] Ma Y., Shi F., Wang Z., Wu M., Ma J., Gao C., Preparation and Characterization of PSf/Clay Nanocomposite Membranes with PEG 400 as a Pore Forming Additive, Desalination, 286: 131-137 (2012).