Determination of Diazinon in Apple Juice and Underground Water Using Dispersive Liquid-Liquid Microextraction Coupled with Corona Discharge Ion Mobility Spectroscopy

Document Type : Research Article

Authors

Department of Chemistry, Isfahan University of Technology, Isfahan, I.R. IRAN

Abstract

In this work, Dispersive Liquid-Liquid Microextraction coupled with Corona Discharge Ion Mobility Spectroscopy (DLLME-CD-IMS) was applied for the extraction and determination of diazinon in apple juice and underground water samples. For the extraction, an appropriate mixture of methanol as dispersive solvent and CCl4 as extraction solvent was injected rapidly into a glass tube with conical bottom containing an aqueous solution of diazinon. This injection led to a cloudy water solution, caused by the fine droplets dispersion of the immiscible extraction solvent (CCl4) in the aqueous sample. The result of this phenomenon was the generation of a high contact area between the aqueous phase and the extraction solvent. The final step of the microextraction procedure was centrifugation (5 min at 3000 rpm) to collect the dispersed tinny CCl4 droplets in the bottom of the test tube. Afterward, 5.0 µL of the solution was directly injected into the IMS, for analysis of the analyte. In order to obtain an optimum condition of the extraction, several parameters affecting on the extraction such as extraction solvent type, dispersive solvent type, extraction and dispersive solvent volume, salt addition, and pH were studied. Under optimum condition (pH 7, 60 µL extraction solvent, 1 mL dispersive solvent and without salt addition), enrichment factor 60 and the limit of detection of 0.2 µg/L was obtained. The good dynamic range was obtained in the range of 0.5 – 100.0 µg/L for extraction of diazinon. The relative standard deviations for analysis of 20 µg/L of diazinon in standard solutions, was 7% (n=3). The obtained recovery for spiked samples was above 89%, indicating the capability of DLLME as a rapid and convenient method for real sample analysis.

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References

[1] Brealy C.Y., Walker G.H., Blodwin B.C., A Estereases Activities in Relation on Different Toxicity of Perimophose-Methyl to Birds Anad Mamals, Pestic. Sci., 11: 154-155 (1980).
[2] Ramos L., Critical Overview of Selected Contemporary Sample Preparation Techniques, J. Chromatogr. A, 1221: 84-98 (2012).
[3] Chamsaz M., Hossein-Poor-Zaryabi M., Arbab-Zavar M.H., Dispersive Liquid-Liquid Microextraction Based on Solidification of Floating Organic Drop combined with Flame Atomic Absorption Spectrometry for Preconcentration and Determination of Thallium(III) in Water Samples, Iran. J. Chem. Chem. Eng. (IJCCE), 33(1): 59-66 (2014).
[4] Bahar S., Zakerian R., Ionic Liquid Based Dispersive Liquid Liquid Microextraction and Enhanced Determination of the Palladium in Water, Soil and Vegetable Samples by FAAS, Iran. J. Chem. Chem. Eng. (IJCCE), 33(4): 51-58 (2014).
[5] El-Shahawi M.S., Al-Saidi H.M., Dispersive Liquid-Liquid Microextraction for Chemical Speciation and Determination of Ultra-Trace Concentrations of Metal Ions, Trends Anal. Chem., 44: 12-24 (2013).
[6] Nuhu A.A., Basheer C., Saad B., Liquid-Phase and Dispersive Liquid-Liquid Microextraction Techniques with Derivatization: Recent Applications in Bioanalysis, J. Chromatogr. B, 879:1180-1188 (2011).
[7] Andruch V., Kocúrová L., Balogh I.S., ˇSkrlíková J., Recent Advances in Coupling Single-Drop and Dispersive Liquid-Liquid Microextraction with UV–vis Spectrophotometry and Related Detection Techniques J., Microchem. J., 102: 1-10 (2012).
[8] Kocúrová L., Balogh I.S., ˇSandrejová J., Andruch V., Recent Advances in Dispersive Liquid-Liquid Microextraction Using Organic Solvents Lighter Than Water. A Review, Microchem. J., 102:11-17 (2012).
[9] Rezaee M., Yamini Y., Faraji M., Evolution of Dispersive Liquid-Liquid Microextraction Method, J. Chromatogr. A, 1217: 2342-2357 (2010).
[10] Zgoła-Grzesıkowiak A., Grzeskowiak T., Dispersive Liquid-Liquid Microextraction, Trend. Anal. Chem., 30: 1382-1399 (2011).
[11] Andruch V., Balogh I.S., KocurovÁ L., ˇSandrejová J., Five Years of Dispersive Liquid-Liquid Microextraction, Appl. Spectrosc. Rev., 48: 161-259 (2013).
[12] Zhao E., Zhao W., Han L., Jiang S., Zhou Z., Application of Dispersive Liquid–Liquid Microextraction for the Analysis of Organophosphorus Pesticides in Watermelon and Cucumber, J. Chromatogr. A, 1175: 137-140 (2007).
[13] Farahani H., Norouzi P., Dinarvand R., Ganjali M.R., Development of Dispersive Liquid-Liquid Microextraction Combined with Gas Chromatography–Mass Spectrometry as a Simple, Rapid and Highly Sensitive Method for the Determination of Phthalate Esters in Water Samples, J. Chromatogr. A, 1172: 105-112 (2007).
[14] Garcııa-Loıpez, M., Rodrııguez, I., C.ela, R., Development of a Dispersive Liquid–Liquid Microextraction Method for Organophosphorus Flame Retardants and Plastizicers Determination in Water Samples, J. Chromatogr. A, 1166: 9-15 (2007).
[15] Fattahi N., Samadi S., Assadi Y., Hosseini M.R.M.,Solid-Phase Extraction Combined with Dispersive Liquid–Liquid Microextraction-Ultra Preconcentration of Chlorophenols in Aqueous Samples, J. Chromatog. A, 1169: 63-69 (2007).
[16] Farajzadeh M.A., Bahram M., Jonsson J.A., Dispersive Liquid–Liquid Microextraction Followed by High-Performance Liquid Chromatography-Diode Array Detection as an Efficient and Sensitive Technique for Determination of Antioxidants, Anal. Chim. Acta, 591: 69-79 (2007).
[17] Xia J., Xiang B., Zhang W., Determination of Metacrate in Water Samples Using Dispersive Liquid–Liquid Microextraction and HPLC with the Aid of Response Surface Methodology and Experimental Design, Anal. Chim. Acta, 625: 28-34 (2008).
[18] Li Y., Wei G., Hu J., Liu X., Zhao X., Wang X., Dispersive Liquid–Liquid Microextraction Followed by Reversed Phase-High Performance Liquid Chromatography for the Determination of Polybrominated Diphenyl Ethers at Trace Levels in Landfill Leachate and Environmental Water Samples, Anal. Chim. Acta, 615: 96-103 (2008).
[19] Chiang J.S., Huang S.D., Simultaneous Derivatization and Extraction of Anilines in Waste Water with Dispersive Liquid–Liquid Microextraction Followed by Gas Chromatography–Mass Spectrometric Detection, Talanta, 75: 70-75 (2008).
[20] Luo S., Fang L., Wang X., Liu H., Ouyang G., Lan C., Luan T., Determination of Octylphenol and Nonylphenol in Aqueous Sample Using simultaneous Derivatization and Dispersive Liquid–Liquid Microextraction Followed by Gas Chromatography–Mass Spectrometry, J. Chromatogr. A, 1217: 6762-6768 (2010).
[21] Montes R., Rodrııguez I., Ramil M., Rubıı E., Cela R., Solid-Phase Extraction Followed by Dispersive Liquid-Liquid Microextraction for the Sensitive Determination of Selected Fungicides in Wine, J. Chromatogr. A, 1216: 5459-5466 (2009).
[22] Rezaee M., Yamini Y., Moradi M., Saleh A., Faraji M., Naeeni M.H., Supercritical Fluid Extraction Combined with Dispersive Liquid–Liquid Microextraction as a Sensitive and Efficient Sample Preparation Method for Determination of Organic Compounds in Solid Samples, J. Supercrit. Fluid., 55: 161-168 (2010).
[23] Creaser C.S., Griffiths J.R., Bramwell C.J., Noreen S., Hill C.A., Paul C.L., Ion Mobility Spectrometry: A Review. Part 1. Structural Analysis by Mobility Measurement, Analyst, 129: 984- 994 (2004).
[24] Eiceman G.A., Ion-Mobility Spectrometry as a Fast Monitor of Chemical Composition, Trend. Anal. Chem., 21: 259-275 (2002).
[25] Eiceman G.A., Karpas Z., “Ion Mobility Spectrometry”, 2th ed., CRC Press, BocaRaton, FL, (2005).
[26] Saraji M., Jafari M.T., Sherafatmand H., Sol–Gel/Nanoclay Composite as a Solid-Phase Microextraction Fiber Coating for the Determination of Organophosphorus Pesticides in Water Samples, Anal. Bioanal. Chem., 407:1241–1252 (2015).
[27] Jafari M.T., Riahi F., Feasibility of Corona Discharge Ion Mobility Spectrometry for Direct Analysis of Samples Extracted by Dispersive Liquid-Liquid Microextraction, J. Chromatogr. A, 1188: 97-107 (2008).
[28] Jafari M.T., Improved Design for High Resolution Electrospray Ionization Ion Mobility Spectrometry, Talanta, 77: 1632-1639 (2009).
[29] Saraji M., Boroujeni M.K., Recent Developments in Dispersive Liquid-Liquid Microextraction, Anal. Bioanal. Chem., 406: 2027-2066 (2014).
[30] Bota G.M., Harrington P.B., Direct Detection of Trimethylamine in Meat Food Products Using Ion mobility Spectrometry, Talanta, 68: 629-635 (2006).
[31 Jafari M.T., Saraji M., Sherafatmand H., Design for Gas Chromatography Corona Discharge Ion Mobility Spectrometry, Anal. Chem., 84: 10077-10084 (2012).
[32] Saraji M., Boroujeni M.K., Bidgoli A.A.H., Comparison of Dispersive Liquid–Liquid Microextraction and Hollow Fber Liquid–Liquid–Liquid Microextraction for the Determination of Fentanyl, Alfentanil, and Sufentanil in Water and Biological Fluids by High-Performance Liquid Chromatography, Anal. Bioanal. Chem., 400: 2149-2158 (2011).
[33] Mirzaei M., Behzadi M., Abadi M.N., Beizaei A., Simultaneous Separation/Preconcentration of Ultratrace Heavy Metals in Industrial Wastewaters by Dispersive Liquid-Liquid Microextraction Based on Solidification of Floating Organic Drop Prior to Determination by Graphite Furnace Atomic Absorption Spectrometry, J. Hard. Mater., 186: 1739-1743 (2011).
[34] Liu J.F., Chi Y.G., Jiang G.B., Screening the Extractability of Some Typical Environmental Pollutants by Ionic Liquids in Liquid-Phase Microextraction, J. Sep. Sci., 28: 87-91 (2005).
[35] Melwanki M.B., Chen W.S., Bai H.Y., Lin T.Y., Fuh M.R., Determination of 7-Aminoflunitrazepam in Urine by Dispersive Liquid–Liquid Microextraction with Liquid Chromatography-Electrospray-Tandem mass Spectrometry, Talanta, 78: 618-622 (2009).
[36] Peng J.F., Liu J.F., Jiang G.B., Tai C., Huang M.J., Ionic Liquid for High Temperature Headspace Liquid-Phase Microextraction of Chlorinated Anilines in Environmental Water Samples, J. Chromatogr. A, 1072: 3-6 (2005).
[37] Soisungnoen P., Burakham R., Srijaranai S., Determination of Organophosphorus Pesticides Using Dispersive Liquid–Liquid Microextraction Combined with Reversed Electrode Polarity Stacking Mode Micellar Electrokineticchromatography, Talanta, 98: 62-68 (2012).
[38] Wang Y.L., Zeng Z.R., Liu M.M., Yang M., Dong C.Z., Determination of Organophosphorus Pesticides in Pakchoi Samples by Headspace Solid-Phase Microextraction Coupled with Gas Chromatography Using Home-Made Fiber, Eur. Food Res. Technol., 226: 1091-1098 (2008).
[39] Sánchez M.E.R., Gómez X., Martín‐Villacorta J., Determination of Diazinon and Fenitrothion in Environmental Water and Soil Samples by HPLC, J. Liq. Chromatogr. Rel. Tech., 26: 483-497 (2003).
[40] Yu J., Wu C., Xing J., Development of New Solid-Phase Microextraction Fibers by Sol–Gel Technology for the Determination of Organophosphorus Pesticide Multiresidues in Food, J. Chromatogr. A, 1036: 101-111 (2004).
[41] Ng W.F., Teo M.J.K., Lakso H.Å., Determination of Organophosphorus Pesticides in Soil by Headspace Solid-Phase Microextraction, Fresenius J. Anal. Chem., 363: 673-679 (2000).
[42] Samadi S., Sereshti H., Assadi Y., Ultra-Preconcentration and Determination of Thirteen Organophosphorus Pesticides in Water Samples Using Solid-Phase Extraction Followed by Dispersive Liquid–Liquid Microextraction and Gas Chromatography with Flame Photometric Detection, J. Chromatogr. A, 1219: 61-65 (2012).
[43] Hu X., Zhang M., Ruan W., Zhu F., Ouyang G., Determination of Organophosphorus Pesticides in Ecological Textiles by Solid-Phase Microextraction with a Siloxane-Modified Polyurethane Acrylic Resin Fiber, Anal. Chim. Acta, 736: 62-68 (2012).
[44] Ciucu A., Ciucu C., Organic Phase Amperometric Biosensor for Detection of Pesticides, Roum. Biotechnol. Lett., 7: 667-676 (2002).

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