Degrading Methylene Blue Photocatalytically via the ZnO/SnO2 Nanocomposite

Document Type : Research Article

Authors

1 Nano Chemical Engineering Department., Faculty of Advanced Technologies, Shiraz University, Shiraz, I.R. IRAN

2 Nano Chemical Engineering Department, International Division, Shiraz University, Shiraz, I.R. IRAN

Abstract

Considering the environmental pollution by the colored waste, the need for nanostructured materials is self-evident. Hence, in this research, the decolorization property of the ZnO/SnO2 nanocomposite was investigated. To produce the desired nanocomposite, the co-precipitation method was used. The desired nanocomposite characterization was performed by PSA, FT-IR, XRD, and SEM, where the nanocomposite size was about 15 nm. The effect of several parameters such as the initial wastewater concentration and the amount of catalyst and time were examined. The nanocomposite particles size reduction due to an increase in the nanocomposites surface area increased the amount of decolorization. In all the experiments the dye removal rate was 100% and the difference pertained to the complete removal time of the dye. It is noteworthy that a decrease in the methylene-blue concentration in the range of the tested concentrations reduced the decolorization and by increasing the amount of nanocomposite tested in the range of the values, a decline was observed in decolorization.

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[1] Kuzhalosai V., Subash B., Senthilraja A., Dhatshanamurthi P., Shanthi M., Synthesis, Characterization and Photocatalytic Properties of SnO2–ZnO Composite under UV-A Light, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 115(1): 876-882 (2013).
[2] Hamrouni S., Hinda Lachheb, Ammar Houas, Synthesis, Characterization and Photocatalytic Activity of ZnO-SnO2 Nanocomposites, Materials Science and Engineering  (2013).
[3] زمانخان، حسام؛ آیتی، بیتا؛ گنجی دوست، حسین؛ تجزیه فتوکاتالیستی فنل به وسیله نانوذرات روی اکسید تثبیت شده بر بستر بتنی، نشریه شیمی و مهندسی شیمی ایران، (3و4) 9:31 تا 19 (1391).
[5] Yang Z., Lv L, Dai y., Xv Z., Qian D, Synthesis of ZnO–SnO2 Composite Oxides by CTAB-Assisted Co-Precipitation and Photocatalytic Properties, Applied Surface Science, 256; 2898–2902 (2010).
[6] Houas A., Lachheb H., Ksibi M., Elaloui E., Guillard CH., Herrmann J.M., Photocatalytic Degradation Pathway of Methylene Blue in Water, Applied Catalysis B: Environmental, 31: 145–157(2001).
[7] Lin C.C., Chiang Y.J., Feasibility of Using a Rotating Packed Bed in Preparing Coupled ZnO/SnO2 Photocatalysts, Journal of Industrial and Engineering Chemistry, 18: 1233–1236 (2012).
[9] Li D., Haneda H., Photocatalysis of Sprayed Nitrogen-Containing Fe2O3–ZnO and WO3–ZnO Composite Powders in Gas-Phase Acetaldehyde Decomposition, Journal of Photochemistry and Photobiology A: Chemistry, 160: 203–212 (2003).
[10] Yang J., Li D., Wang X., Yang X.J., Lu L.D., Rapid Synthesis of Nanocrystalline TiO2/SnO2 Binary Oxides and Their Photoinduced Decomposition of Methyl Orange, Journal of Solid State Chemistry, 165, 193-198 (2002).
[11] Shi L., Li Ch., Gu H., Fang D., Morphology and Properties of Ultrafine SnO2-TiO2 Coupled Semiconductor Particles, Materials Chemistry and Physics, 62: 62-67 (2000).
[12] Wang L., Wei H., Fan Y., Gu X., Zhan J., One-Dimensional CdS/α-Fe2O3 and CdS/Fe3O4 Heterostructures: Epitaxial and Nonepitaxial Growth and Photocatalytic Activity, J. Phys. Chem. C, 113: 14119–14125 (2009).
[13] Wang C., Xu B.Q., Wang X., Zhao J., Preparation and Photocatalytic Activity of ZnO/TiO2/SnO2 Mixture, Journal of Solid State Chemistry, 178: 3500–3506 (2005).
[14] Cun W., Jincai Z., Xinming W., Bixian M., Guoying Sh., Ping’an P., Jiamo F., Preparation, Characterization and Photocatalytic Activity of Nano-Sized ZnO/SnO2 Coupled Photocatalysts, Applied Catalysis B: Environmental, 39: 269-279 (2002).
[15] Marco S. Lucas, Jose´ A. Peres, Degradation of Reactive Black 5 by Fenton/UV-C and Ferrioxalate/H2O2/Solar Light Processes, Dyes and Pigments,74: 622-629 (2007).
[16] Aksu z, Application of Biosorption for the Removal of Organic Pollutants: A Review, Process Biochemistry, 40: 997-1026 (2005).
[17] Somasiri W, Li X.F., Ruan W.Q, Chen Jian, Evaluation of the Efficacy of Upflow Anaerobic Sludge Blanket Reactor in Removal of Colour and Reduction of COD in Real Textile Wastewater, Bioresource Technology, 99: 3692–3699 (2008).
[18] Wang C., Wang X., Xu B.Q., Zhao J., Mai B., Peng P., Sheng G., Fu J., Enhanced Photocatalytic Performance of Nanosized Coupled ZnO/SnO2 Photocatalysts for Methyl Orange Degradation, Journal of Photochemistry and Photobiology A: Chemistry, 168: 47–52 (2004).
[19] Kumar H., Rani R., Structural and Optical Characterization of ZnO Nanoparticles Synthesized by Microemulsion Route, International Letters of Chemistry, Physics and Astronomy, 14: 26-36 (2013).
[20] Zhang B., Tian Y., Zhang J., Cai W., The FTIR Studies on the Structural and Electrical Properties of SnO2:F Films as a Function of Hydrofluoric Acid Concentration, Optoelectronics and Advanced Materials – Rapid Communications, 4(8): 1158-1162 (2010).
[21] By Özlem Esen Kartal, Murat Erol, and Hüseyin OgÏuz, Photocatalytic Destruction of Phenol by TiO2 Powders, Chem. Eng. Technol., 24, 6 (2001).
[22] Konstantinou I.K., Albanis T.A., TiO2-Assisted Photocatalytic Degradation of Zzo Dyes I Aqueous Solution, Kinetic and Mechanistic Investigations, A Review. Appl. Catal. B, Environ., 49: 1-4 (2004).
[23] Mahmoodi N.M., Rayat Tari K.H., Borhany S., Arami M., Nourmohammadian F., Decolorization of Colored Wastewater Containing Azo Acid Dye Using Photo-Fenton Process, Operational Parameters and a Comparative Study, J. Color Science and Technology, 2: 31-40 (2008).
[24] Mahmoodi N.M., Arami M., Gharanjig K., Nourmohammadian F., Decolorization and Mineralization of Basic Dye using Nanophotocatalysis, Pilot Scale Study, J. Color Science and Technology, 1: 1-6 (2008).
[25] Daneshvar N., Khataee A., Rasoulifard M.H., Seyed Dorraji M., Removal of Organic Dyes from Industrial Wastewaters Using UV/H2O2, UV/H2O2/Fe (II), UV/H2O2/Fe (III) Processes, J. Water and Wastewater, 61: 34-42 (2007).
[26] Ghanbarian R., Mahvi A.H., Nabizadeh R., Saeedniya S., A Pilot Study of RO16 Discoloration and Mineralization in Textile Effluents Using the Nanophotocatalytic Process, J. of Water and Wastewater, 69: 45-51 (2008).