Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Purification of Ammonium Carbonate Solution Using Ceramic Membrane in the Production of Ammonium Sulfate in Uremia Petrochemical Company

Document Type : Research Article

Authors
Reza Seifi 1
Sona Jamshidi 1
Ali Akbar Babaluo 2
1 Department of Chemical Engineering, Tabriz Branch, Islamic Azad University, Tabriz, I.R. IRAN
2 Department of Chemical Engineering, Sahand University of Technology, Tabriz, I.R. IRAN
Abstract
One important application of the membrane technology is in solid particles separation from suspension. Recently, Ceramic membranes have been investigated significantly due to it,s advantages such as high mechanical strength, high thermal and chemical stability, etc. In this work, for the first time, the ceramic membrane has been used for solid particles separation of ammonium carbonate as a feed-in Uremia Petrochemical. The experimental results showed that the rejection factor reduced (less than 10%) with increasing temperature and pressure difference. Also, enhancing of rejection factor (up to 97%) and reducing of permeated flux (less than 0.5 cc/min) was observed for at a long time due to cake formation on the ceramic membrane. After 30 min washing with pure water, the used membrane at a long time was regenerated. So, the results confirmed the high potential of the ceramic membranes in solid particle separation of ammonium carbonate.
Keywords
Separation process
Ceramic membrane
Ammonium carbonate
Solid particles

Subjects

[1] Keller G.E., "Separation Technologies for the Industries of the Future", Publication NMAB-487-3, National Academy Press, Washington, D.C., (1998).
[2] Tabe-Mohammadi, A., A Review of the Applications of Membrane Separation Technology in Natural Gas Treatment, Sep Sci Technol, 34(10):  2095-2111 (1999).
[3] Voutchkov N., "Pretreatment for Reverse Osmosis Desalination- Chapter 9: Membrane Filtration", Elsevier Science, (2017).
[4] Rushton A., Ward A.S., Holdich R.G., "Solid-Liquid Filtration and Separation Technology", John Wiley & Sons, Inc., Germany (2008).
[5] Strathmann H., Membrane Separation Processes, J. Membr. Sci., 9(1–2): 121-189 (1981).
[6] Hsieh, H.P., "Inorganic Membranes for Separation and Reaction", Elsevier Science B.V., Amsterdam, The Netherlands (1996).
[7] Lin Y.S., Microporous and Dense Inorganic Membranes: Current Status and Prospective, Sep. Purif. Technol., 25 (1–3): 39-55 (2001).
[8] Das B., Chakrabarty B., Barkakati P., Preparation and Characterization of Novel Ceramic Membranes for Micro-Filtration Applications, Ceram Int., 42(13): 14326-14333 (2016).
[9] Kazemzadeh A., Bayati B., Kalantari N., Babaluo A.A., Tubular MFI Zeolite Membranes Made by In-Situ Crystallization, Iran. Chem. Chem. Eng. (IJCCE), 31(2): 37-44 (2012).
[10] Malzbender J., "Mechanical Aspects of Ceramic Membrane Materials", Ceram Int., 42(7): 7899-7911 (2016).
[11] Bowen W.R., Jenner F., Theoretical Descriptions of Membrane Filtration of Colloids and Fine Particles: An Assessment and Review, Adv. Colloid Interface Sci., 56: 141-200 (1995).
[12] Buekenhoudt A., Luca G. D., Unravelling the Solvent Flux Behavior of Ceramic Nano Filtration and Ultrofiltration Membrane, J. Membr. Sci., 439: 36-47 (2013).
[13] Ahmadian Namini P., Babaluo A. A., Jannatdoust E., Peyravi M., Akhfash Adrestani M., An Optimum Routine for Surface Modification of Ceramic Supports to Facilitate Deposition of Defect-Free Overlaying Micro and Meso (Nano) Porous Membrane, Iran. Chem. Chem. Eng. (IJCCE), 30 (3): 63-73 (2011).
[14] Belfort G., Davis R. H., Zydney A. L., The behavior of Suspensions and Macromolecular Solutions in Cross-Flow Microfiltration, J. Membr. Sci., 96: 1-58 (1994).
[15] Guirgis A., Gay-de-Montella R., Faiz R., Treatment of Produced Water Streams in SAGD Processes Using Tubular Ceramic Membranes, Desalination, 358: 27-32 (2015).
[16] Siskens C.A., Applications of Ceramic Membranes in Liquid Filtration, Membr. Sci. Technol., 4: 619-639 (1996).
[17] Grumezescu A., "Water Purification- Chapter 15: Nanocomposite Filtration Membranes for Drinking Water Purification", Academic Press, 517–549 (2017).
[18] Goh P. S., Ismail A. F., "A Review on Inorganic Membranes for Desalination and Wastewater Treatment", Desalination, In Press (2017).
[19] Majewska-Nowak K.M., Application of Ceramic Membranes for the Separation of Dye Particles, Desalination, 254 (1–3): 185-191 (2010).
[20]Golbandi R., Abdi M.A., Babaluo A.A., Khoshfetrat A.B., Mohammadlou T.,Fouling Study of TiO2–Boehmite MF Membrane in Defatting of Whey Solution: Feed Concentration and pH Effects, J. Membr. Sci., 448: 135-142 (2013).
[21] Ali Razavi S.M., Jones M., The Study of Dynamic Milk Ultrafiltration Performance Influenced by Membrane Molecular Weight Cut off, Iran. Chem. Chem. Eng. (IJCCE), 26(1): 61-69 (2007).