Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Performance Evaluation of PES/Modified-Titanium Oxide Nanofiltration Membrane for Chromium Sulfate Wastewater Treatment

Document Type : Research Article

Authors
Fahime Parvizian
Samaneh Bandehali
Fateme Ansari
Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak, I.R. IRAN
Abstract
In this study, polyethersulfone (PES)-based nanofiltration (NF) membranes were prepared by introducing synthesized oleic acid-titanium oxide (OA-TiO2) nanoparticles by phase inversion method. Various concentration of OA-TiO2 nanoparticles were used to the membrane fabrication. The OA-TiO2 nanoparticles were characterized by Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), and X-Ray Diffraction Analysis (XRD). Moreover, the membrane morphology was investigated by FESEM, 3D surface images. The separation performance of membranes were studied by the contact angle, pure water flux (PWF), flux recovery ratio (FRR%), and the rejection of Na2SO4 and CrSO4. The best pure water flux (18.206 L/m2h) was revealed for M2 with 42% increase compared with neat PES membrane at operation pressure 4.5 MPa due to increase membrane hydrophilicity and better dispersion of OA-TiO2 nanoparticles. Furthermore, the best Na2SO4 rejection (81.5%) was obtained to M3 and the highest CrSO4 removal (80.4%) was revealed to M5 at operation pressure 4.5 MPa. The enhancement of salt rejection attributed to Donnan effects and adsorption mechanism. The incorporation of OA-TiO2 nanoparticles into the PES improved the anti-fouling properties and FRR% increased to 83%.
Keywords
Nanofiltration membrane
Modified-titanium oxide nanoparticles
chromium removal
Oleic acid

Subjects

[1] Bandehali S., Parvizian F., Moghadassi A.R., Hosseini S.M., Copper and Lead Ions Removal from Water by New PEI based NF Membrane Modified by Functionalized POSS Nanoparticles, Journal of Polymer Research, 26: 211-221 (2019).
[2] Bandehali S., Moghadassi A., Parvizian F., Hosseini S., A New Type of [PEI-Glycidyl POSS] Nanofiltration Membrane with Enhanced Separation and Antifouling Performance, Korean Journal of Chemical Engineering, 36: 1657-1668 (2019).
[3] Hosseini S.M., Afshari M., Fazlali A.R., Koudzari Farahani S., Bandehali S., Van der Bruggen B., Bagheripour E., Mixed Matrix PES-Based Nanofiltration Membrane Decorated by (Fe3O4–Polyvinylpyrrolidone) Composite Nanoparticles with Intensified Antifouling and Separation Characteristics, Chemical Engineering Research and Design, 147: 390-398 (2019).
[4] Wilbert M.C., Leitz F., Abart E., Boegli B., Linton K., Desalting and Water Treatment Membrane Manual: A Guide to Membranes for Municipal Water Treatment, Desalination, (1998).
[5] Baker R.W., Overview of Membrane Science and Technology, Membrane Technology applications, 3: 1-14 (2004).
[6] Bandehali S., Moghadassi A., Parvizian F., Shen J., Hosseini S., Glycidyl POSS-Functionalized ZnO Nanoparticles Incorporated Polyether-Imide based Nanofiltration Membranes for Heavy Metal Ions Removal from Water, Korean Journal of Chemical Engineering, 37: 263-273 (2020).
[7] Fane A., Tang C., Wang R., Membrane Technology for Water: Microfiltration, Ultrafiltration, Nanofiltration, and Reverse Osmosis, Treatise on water science, 4: (2011).
[8] Zhao G., Hu R., Zhao X., He Y., Zhu H., High Flux Nanofiltration Membranes Prepared with a Graphene Oxide Homo-Structure, Journal of Membrane Science, 585: 29-37 (2019).
[9] Zangeneh H., Zinatizadeh A.A., Zinadini S., Feyzi M., Bahnemann D.W., Preparation and Characterization of a Novel Photocatalytic Self-Cleaning PES Nanofiltration Membrane by Embedding a Visible-Driven Photocatalyst Boron Doped-TiO2 -SiO2/CoFe2O4 Nanoparticles., Separation Purification Technology, 209: 764-775 (2019).
[10] Zhao D.L., Chung T.-S., Applications of Carbon Quantum Dots (CQDs) in Membrane Technologies: A Review., Water Research, 147: 43-49 (2018).
[11] Wang X.-M., Li X.-Y., Shih K., In Situ Embedment and Growth of Anhydrous and Hydrated Aluminum Oxide Particles on Polyvinylidene Fluoride (PVDF) Membranes, Journal of membrane Science, 368: 134-143 (2011).
[12] Shaban M., AbdAllah H., Said L., Ahmed A.M., Water Desalination and Dyes Separation from Industrial Wastewater by PES/TiO2 NTs Mixed Matrix Membranes, Journal of Polymer Research, 26: 181-193 (2019).
[13] Zhao C., Xue J., Ran F., Sun S., Modification of Polyethersulfone Membranes–A Review of Methods, 58: 76-150 (2013).
[14] Bao Y., Lee W.J., Lim T.-T., Wang R., Hu X., Pore-Functionalized Ceramic Membrane with Isotropically Impregnated Cobalt Oxide for Sulfamethoxazole Degradation and Membrane Fouling Elimination: Synergistic Effect between Catalytic Oxidation and Membrane Separation, Applied Catalysis B: Environmental, 254: 37-46 (2019).
[15] Segev-Mark N., Vu A., Chen N., Qian X., Wickramasinghe S.R., Ramon G.Z., Colloidal Deposition on Polymer-Brush-Coated NF Membranes, Separation Purification Technology, 219: 208-215 (2019).
[16] Haan T.Y., Chean L.W., Mohammad A.W., Thermo-Responsive Antifouling Study of Commercial PolyCera® Membranes for POME Treatment, Membrane Water Treatment, 11: 97-109 (2020).
[17] Yi G., Fan X., Quan X., Zhang H., Chen S., Yu H., A pH-Responsive PAA-Grafted-CNT Intercalated RGO Membrane with Steady Separation Efficiency for Charged Contaminants over a Wide pH Range, Separation and Purification Technology, 215: 422-429 (2019).
[18] Ghandashtani M.B., Ashtiani F.Z., Karimi M., Fouladitajar A., A Novel Approach to Fabricate High Performance Nano-SiO2 Embedded PES Membranes for Microfiltration of Oil-in-Water Emulsion, Applied Surface Science, 349: 393-402 (2015).
[19] Rajabi H., Ghaemi N., Madaeni S.S., Daraei P., Astinchap B., Zinadini S., Razavizadeh S.H., Nano-ZnO Embedded Mixed Matrix Polyethersulfone (PES) Membrane: Influence of Nanofiller Shape on Characterization and Fouling Resistance., Applied Surface Science, 349: 66-77 (2015).
[20] Zinadini S., Zinatizadeh A., Rahimi M., Vatanpour V., Magnetic field-Augmented Coagulation bath during Phase Inversion for Preparation of ZnFe2O4/SiO2/PES Nanofiltration Membrane: A Novel Method for Flux Enhancement and Fouling Resistance., Journal of Industrial Engineering Chemistry, 46: 9-18 (2017).
[21] Sotto A., Boromand A., Zhang R., Luis P., J.M. Arsuaga, Kim J., Van der Bruggen B., Effect of Nanoparticle Aggregation at Low Concentrations of TiO2 on the Hydrophilicity, Morphology, and Fouling Resistance of PES–TiO2 Membranes, Journal of Colloid Interface Science, 363: 540-550 (2011).
[22] Madaeni S., Zinadini S., Vatanpour V., A New Approach to Improve Antifouling Property of PVDF Membrane using In Situ Polymerization of PAA Functionalized TiO2 Nanoparticles, Journal of Membrane Science, 380: 155-162 (2011).
[23] Mobarakabad P., Moghadassi A., Hosseini S., Fabrication and Characterization of Poly (Phenylene ether-ether Sulfone) based Nanofiltration Membranes Modified by Titanium Dioxide Nanoparticles for Water Desalination, Desalination, 365: 227-233 (2015).
[24] Rakhshan N., Pakizeh M., The Effect of Functionalized SiO2 Nanoparticles on the Morphology and Triazines Separation Properties of Cellulose Acetate Membranes., Journal of industrial Engineering Chemistry, 34: 51-60 (2016).
[25] Rakhshan N., Pakizeh M., Removal of Triazines from Water using A Novel OA Modified SiO2/PA/PSf Nanocomposite Membrane, Separation Purification Technology, 147: 245-256 (2015).
[26] Pourjafar S., Rahimpour A., Jahanshahi M., Chemistry E., Synthesis and Characterization of PVA/PES Thin Film Composite Nanofiltration Membrane Modified with TiO2 Nanoparticles for Better Performance and Surface Properties, Journal of Industrial Engineering Chemistry, 18: 1398-1405 (2012).
[27] Hwang H.Y., Kim D.J., Yim W.J., Nam S.Y., PES/SPAES Blend Membranes for Nanofiltration: the Effects of Sulfonic Acid Groups and Thermal Treatment, Desalination, 289: 72-80 (2012).
[28] Lau W., Ismail A., Theoretical Studies on the Morphological and Electrical Properties of Blended PES/SPEEK Nanofiltration Membranes using Different Sulfonation Degree of SPEEK, Journal of Membrane Science, 334: 30-42 (2009).
[29] Hosseini S., Amini S., Khodabakhshi A., Bagheripour E., Van der Bruggen B., Activated Carbon Nanoparticles Entrapped Mixed Matrix Polyethersulfone based Nanofiltration Membrane for Sulfate and Copper Removal from Water, Journal of the Taiwan Institute of Chemical Engineers, 82: 169-178 (2018).
[30] Rakhshan N., Pakizeh M., The Effect of Functionalized SiO2 Nanoparticles on the Morphology and Triazines Separation Properties of Cellulose Acetate Membranes, Journal of Industrial and Engineering Chemistry, 34: 51-60 (2016).
[31] Bandehali S., Parvizian F., Moghadassi A.R., Hosseini S.M., Shen J.N., Fabrication of Thin Film-PEI Nanofiltration Membrane with Promoted Separation Performances: Cr, Pb and Cu Ions Removal from Water, Journal of Polymer Research, 27: 1-10 (2020).
[32] Van der Bruggen B., Everaert K., Wilms D., Vandecasteele C., Application of Nanofiltration for Removal of Pesticides, Nitrate and Hardness from Ground Water: Rejection Properties and Economic Evaluation, Journal of Membrane Science, 193: 239-248 (2001).
[33] Idris A., Mat Zain N., Noordin M., Synthesis Y., Characterization and Performance of Asymmetric Polyethersulfone (PES) Ultrafiltration Membranes with Polyethylene Glycol of Different Molecular Weights as Additives, Desalination, 207: 324-339 (2007).
[34] Ng L.Y., Mohammad A.W., Leo C.P., Hilal N., Polymeric Membranes Incorporated with Metal/Metal Oxide Nanoparticles: A Comprehensive Review, Desalination, 308: 15-33 (2013).
[35] Nemati M., Hosseini S., Thin Film Heterogeneous Ion Exchange Membranes Prepared by Interfacial Polymerization of Paa-Co-Iron-Nickel Oxide Nanoparticles on Polyvinylchloride based Substrate, International Journal of Engineering-Transactions C: Aspects., 29: 297-305 (2016).
[36] Nidal Hilal H.A.Z., Darwish N., Mohammad A., Nanofiltration of Magnesium Chloride, Sodium Carbonate, and Calcium Sulphate in Salt Solutions, Separation Science and Technology, 40: 3299-3321 (2005).
[37] Bagheripour E., Hosseini S., Hamidi A., Moghadassi A., Fabrication and Characterization of Novel Mixed Matrix Polyethersulfone Based Nanofiltration Membrane Modified by Ilmenite, International Journal of Engineering Transactions A: Basics, 30: 7-14 (2017).
[38] Gholami A., Moghadassi A., Hosseini S., Shabani S., Gholami F., Preparation and Characterization of Polyvinyl Chloride based Nanocomposite Nanofiltration-Membrane Modified by Iron Oxide Nanoparticles for Lead Removal from Water, Journal of Industrial Engineering Chemistry, 20: 1517-1522 (2014).
[39] Sivakumar M., Mohanasundaram A., Mohan D., Balu K.,  Rangarajan R., Modification of Cellulose Acetate: Its Characterization and Application as An Ultrafiltration Membrane, Journal of applied polymer science, 67: 1939-1946 (1998).
[40] Rahimpour A., UV Photo-Grafting of Hydrophilic Monomers onto the Surface of Nano-Porous PES Membranes for Improving Surface Properties, Desalination, 265: 93-101 (2011).
[41] León A., Reuquen P., Garín C., Segura R., Vargas P., Zapata P., Orihuela P., FT-IR and Raman Characterization of TiO2 Nanoparticles Coated with Polyethylene Glycol as Carrier for 2-Methoxyestradiol, Applied Sciences, 7: 49 (2017).
[42] Plakas K.V., Karabelas A.J., Membrane Retention of Herbicides from Single and Multi-Solute Media: The Effect of Ionic Environment, Journal of Membrane Science, 320: 325-334 (2008).
[43] Heidary F., Kharat A.N., Khodabakhshi A.R., Preparation, Characterization and Transport Properties of Novel Cation-Exchange Nanocomposite Membrane Containing BaFe12O19 Nanoparticles, Journal of Membrane Science, 27: 193-211 (2016).
[44] Ghaemi N., Madaeni S.S., Alizadeh A., Daraei P., Vatanpour V., Falsafi M., Fabrication of Cellulose Acetate/Sodium Dodecyl Sulfate Nanofiltration Membrane: Characterization and Performance in Rejection of Pesticides, Desalination, 290: 99-106 (2012).
[45] Mansourpanah Y., Madaeni S., Rahimpour A., Adeli M., Hashemi M., Moradian M., Fabrication New PES-based Mixed Matrix Nanocomposite Membranes using Polycaprolactone Modified Carbon Nanotubes as the Additive: Property Changes and Morphological Studies, Desalination, 277: 171-177 (2011).
[46] Ghaemi N., Madaeni S.S., Alizadeh A., Daraei P., Zinatizadeh A.A., Rahimpour F., Separation of Nitrophenols using Cellulose Acetate Nanofiltration Membrane: Influence of Surfactant Additives, Separation Purification Technology, 85: 147-156 (2012).
[47] Ghaemi N., Madaeni S.S., Alizadeh A., Rajabi H., Daraei P., Preparation, Characterization and Performance of Polyethersulfone/Organically Modified Montmorillonite Nanocomposite Membranes in Removal of Pesticides, Journal of Membrane Science, 382: 135-147 (2011).
[48] Bagheripour E., Moghadassi A., Hosseini S., Fabrication of Polyvinyl Chloride based Nanocomposite Nanofiltration Membrane: Investigation of SDS/Al2O3 Nanoparticle Concentration and Solvent Ratio Effects, Korean Journal of Chemical Engineering, 10: 791-798  (2015).
[49] Peyravi M., Jahanshahi M., Rahimpour A., Javadi A., Hajavi S., Novel Thin Film Nanocomposite Membranes Incorporated with Functionalized TiO2 Nanoparticles for Organic Solvent Nanofiltration, Chemical Engineering Journal, 241: 155-166 (2014).
[50] Ghaemi N., Madaeni S.S., Daraei P., Rajabi H., Zinadini S., Alizadeh A., Heydari R., Beygzadeh M., Ghouzivand S., Polyethersulfone Membrane Enhanced with Iron Oxide Nanoparticles for Copper Removal from Water: Application of New Functionalized Fe3O4 Nanoparticles, Chemical Engineering Journal, 263: 101-112 (2015).
[51] Sivakumar M., Mohan D.R., Rangarajan R., Studies on Cellulose Acetate-Polysulfone Ultrafiltration Membranes: II. Effect of Additive Concentration, Journal of Membrane Science, 268: 208-219 (2006).
[52] Daraei P., Madaeni S.S., Ghaemi N., Salehi E., Khadivi M.A., Moradian R., Astinchap B., Novel Polyethersulfone Nanocomposite Membrane Prepared by PANI/Fe3O4 Nanoparticles with Enhanced Performance for Cu (II) Removal from Water., Journal of Membrane Science, 415: 250-259 (2012).
[53] Kingma A., Compatibility of Nonionic Surfactants with Membrane Materials and Their Cleaning Performance, Food Bioproducts Processing, 93: 304-309 (2015).
[54] Bagheripour E., Moghadassi A., Hosseini S.M., Preparation of Mixed Matrix PES-based Nanofiltration Membrane Filled with PANI-co-MWCNT Composite Nanoparticles, Korean Journal of Chemical Engineering, 33: 1462-1471 (2016).
[55] Hegab H.M., Zou L., Graphene Oxide-Assisted Membranes: Fabrication and Potential Applications in Desalination and Water Purification, Journal of Membrane Science, 484: 95-106 (2015).
[56] Bagheripour E., Moghadassi A., Hosseini S., Van der Bruggen B., Parvizian F., Novel Composite Graphene Oxide/Chitosan Nanoplates Incorporated into PES based Nanofiltration Membrane: Chromium Removal and Antifouling Enhancement, Journal of Industrial Engineering Chemistry, 62: 311-320 (2018).
[57] Lai G., Lau W., Goh P., Ismail A., Yusof N., Tan Y., Graphene Oxide Incorporated Thin Film Nanocomposite Nanofiltration Membrane for Enhanced Salt Removal Performance, Desalination, 387: 14-24 (2016).
[58] Yaser A.Z., "Development of Integrated Nanofiltration System for Highly Concentrated Dye Removal", Swansea University, (2011).
[59] Madaeni S., Zinadini S., Vatanpour V., Preparation of Superhydrophobic Nanofiltration Membrane by Embedding Multiwalled Carbon Nanotube and Polydimethylsiloxane in Pores of Microfiltration Membrane, Separation Purification Technology, 111: 98-107 (2013).
[60] Mansourpanah Y., Rahimpour A., Tabatabaei M., Bennett L., Self-Antifouling Properties of Magnetic Fe2O3/SiO2-Modified Poly (Piperazine Amide) Active Layer for Desalting of Water: Characterization and Performance, Desalination, 419: 79-87 (2017).
[61] Gholami N., Mahdavi H., Nanofiltration Composite Membranes of Polyethersulfone and Graphene Oxide and Sulfonated Graphene Oxide, Advances in Polymer Technology, 37(8): 3529-3541 (2018).
[62] Bandehali S., Parvizian F., Moghadassi A., Hosseini S.M., High Water Permeable PEI Nanofiltration Membrane Modified by L-Cysteine Functionalized POSS Nanoparticles with Promoted Antifouling/Separation Performance, Separation and Purification Technology, 237: 116361 (2020).
[63] Bandehali S., Moghadassi A., Parvizian F., Zhang Y., Hosseini S.M., Shen J., New Mixed Matrix PEI Nanofiltration Membrane Decorated by Glycidyl-POSS Functionalized Graphene Oxide Nanoplates with Enhanced Separation and Antifouling Behaviour: Heavy Metal Ions Removal, Separation and Purification Technology, 242: 116745 (2020).
[64] Zhang Q., Fan L., Yang Z., Zhang R., Liu Y.-n., He M., Su Y., Jiang Z., Loose Nanofiltration Membrane for Dye/Salt Separation Through Interfacial Polymerization with In-Situ Generated TiO2 Nanoparticles, Applied Surface Science, 410: 494-504 (2017).