Sorption of Copper, Zinc and Nickel on Ca-Bentonite

Document Type : Research Article

Authors

1 International Center for Science, High Technology & Environmental Sciences, Kerman, I.R. IRAN

2 Department of Chemical Engineering, Shahid Bahonar University, Kerman, I.R. IRAN

Abstract

Clays and clay minerals specially montmorillonite and bentonite are widely used for environmental pollution control. The heavy metals are important environmental pollutants. In this study the sorption of copper, zinc and nickel ions as heavy metals by bentonite samples was investigated. Sample 1 from Kheir Abad mine, sample 2 from Tange Ghoochan mine and sample 3 from the mine around the Ravari mosque were prepared.  The sorption tests of copper, zinc and nickel ions by Kheir Abad Ca- bentonite sample were done. The results showed that the sorption very fast and for doing all tests the appropriate time was obtained 5 minutes. Also the results showed that the reduction of pH causes the reduction of copper, zinc & nickel ions sorption and also appropriate conditions for sorption of each ions were achieved. The sorption tests by other samples in obtained appropriate conditions for sample 1 were done. The results showed that among these samples, sample 2 has the highest percentage of sorption and sample 3 has the lowest  percentage of sorption. Also the results showed that the increase of CEC causes the increase of copper, zinc & nickel ions sorption. and sorption of nickel is less than sorption of copper and zinc. Finally these samples can be an excellent and inexpensive sorbent for copper, zinc and nickel ions as heavy metal.

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[1] Murry H.H., "Applied Clay Mineralogy", Elsevier, p. 113 (2007).
[2] Bergaya F., Theng B.K.G., Lagaly G., "Handbook of Clay Science", Elsevier, (2006).
[3] Grim R.E., "Clay Mineralogy", McGraw-Hill, (1968).
[4] Brown G., Brindley G.W., "Crystal Structures of Clay Minerals and X-ray Identification", Mineralogical Society, London, (1980).
[5] Luckham P.F., Rossi S., The Colloidal and Rheological Properties of Bentonite Suspensions, Advances in colloid and Interface Science, 82, p. 43 (1999).
[6] Bergaya F., Vayer M., CEC of Clays: Measurement by Adsorption of a Copper Ethylenediamine Complex, Applied Clay Science, 12, p. 275 (1997).
[7] Hang P.T., Brindley G.W., Methylen Blue Absorption by Clay Minerals: Determination of Surface Area and Cation Exchange Capacity, Clay and Clay Mineral, 18, p. 203 (1970).
[8] Grim R.E., Guven N., "Bentonites: Geology, Mineralogy, Properties and Uses", Elsevier, (1978).
[9]- Malakul P., Srinivasan K.R.,Wang H.Y., Metal Adsorption and Desorption Characteristics of Surfactant-Modified Clay Complexes, Ind. Eng.Chem., 37, p. 4296 (1998).
[10] Abollino O., Aceto M., Malandrino M., Sarzanini C., Mentasti E., Adsorption of Heavy Metals on Na-Monmorillonite Effect of pH and Organic Substances, Water Research, 37, p. 1619 (2003).
[11] Maria G.da Fonseca, de Oliveira.M.M, Arakaki.L.N.H, Removal of Cadmium, Zinc, Manganese and Chromium Cations from Aqueous Solution by a Clay Mineral, Journal of Hazardous Materials, B137, p. 288 (2006).
[12] طهمورسی مجید؛ صرافی امیر؛ حسینی محمد صادق؛ منصوری عبدالرضا ایرج؛ میرزایی مرتضی؛ ارزیابی نمونه بنتونیت استان کرمان، نشریه شیمی مهندسی شیمی ایران، (2) 29، (1389).
[13] طهمورسی مجید؛ ابراهیمی عبدالهادی؛ صرافی امیر؛ منصوری عبدالرضا ایرج؛ میرزایی مرتضی؛ جداسازی مونتموریلونیت از بنتونیت نوع سدیمی و کلسیمی، نشریه علوم و مهندسی جداسازی، (2) 2، (1389).
[14] Treybal R.E., "Mass Transfer Operations", 3rd ed., McGraw-Hill, (1981).
[15] Zhenghua W., Zhimang G., Xiaorong W., Les E., Hongyan G., Effects of Organic Acids on Adsorption of Lead Onto Montmorillonite, Goethite and Humic Acid, Environmental Pollution, 121(3), p. 469 (2003).
[16] Liu Zhi-rong, Zhou Shao-qi, Adsorption of Copper and Nickel on Na-Bentonite, Process Safety and Environmental Protection, 88, p. 62 (2010).