Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Fabrication of a New Magnetic Zeolite-Y Nanocatalyst Functionalized with N-methylimidazolium chloride Ionic Liquid and Its Application in the Three-Component and Green Synthesis of 2-amino-4H-benzo- and Naphtho- pyrans

Document Type : Research Article

Authors
Mehdi Kalhor
Pouria Nozare
Saeid Azimi
Esmail Vessally
Ezzatollah Najafi
Department of Chemistry, Faculty of Basic Sciences, Payam Noor University, Tehran, Iran
Abstract
In this research, at first, nanoporous zeolite-NaY was functionalized through reaction with 3-chloropropyltriethoxysilane (organic linker) and then with N-methylimidazole group. Then magnetic nanoparticles (Fe3O4) were formed and stabilized under ultrasonic energy conditions on the surface and internal pores of zeolite-Y (1-MeIm IL@ZY-Fe3O4). The structure of zeolite-ionic liquid prepared as a magnetic nanohybrid using the techniques of FTIR, FESEM, EDS, TGA, BET, XRD and VSM instrumental analyses were identified and confirmed. At the next step, its catalytic performance in the synthesis of a number of 4-aryl-2-amino benzopyran (chromene) or 4-aryl-2-amino naphthopyran (benzochromene) derivatives was investigated through the three-component condensation reaction of aromatic aldehydes, malononitrile and dimedone or β-naphthol, at ambient temperature and aqueous medium. The advantages of this method include the use of cheap, safe and reusable nanocatalyst, easy separation of the heterogeneous catalyst from the reaction medium with the using of a magnet, short reaction time, high yield, easy and fast separation of the product, and the use of non-toxic water solvent, that has made this method in simplicity, be in the scope of "green chemistry". 
Keywords
N-methylimidazolium ionic liquid
Magnetic zeolite-Y
Nanocatalyst
Green and three-component synthesis
4H-chromene and 4H-benzochromene

Subjects

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