Synthesis of chromenes from benzyl alcohol derivatives using Schiff base cobalt (II) catalyst bonded to crown ether and supported on cellulose nanoparticles
Department of chemistry, Faculty of science, University of Birjan, Birjand, Iran
Abstract
In this research, a Schiff base-cobalt (II) catalyst containing crown ether, stabilized on cellulose nanoparticles (Crowned Imine-Co (II)@CNC) was prepared. This catalyst was identified by SEM, IR, TGA, XRD, EDX and TEM techniques. This compound was used as a heterogeneous catalyst in the synthesis of chromenes. Chromenes were synthesized with good efficiency (77% to 99%) and within a short time of 20 minutes through the reaction between diketones, malononitrile and various benzyl alcohol derivatives in water solvent. Reusing the recycled catalyst (up to 4 times) did not change the reaction efficiency. The difference between this method and other methods of synthesizing chromenes is by using benzyl alcohol derivatives instead of benzaldehyde.
sandaroos, R. (2023). Synthesis of chromenes from benzyl alcohol derivatives using Schiff base cobalt (II) catalyst bonded to crown ether and supported on cellulose nanoparticles. Nashrieh Shimi va Mohandesi Shimi Iran, (), -.
MLA
reza sandaroos. "Synthesis of chromenes from benzyl alcohol derivatives using Schiff base cobalt (II) catalyst bonded to crown ether and supported on cellulose nanoparticles". Nashrieh Shimi va Mohandesi Shimi Iran, , , 2023, -.
HARVARD
sandaroos, R. (2023). 'Synthesis of chromenes from benzyl alcohol derivatives using Schiff base cobalt (II) catalyst bonded to crown ether and supported on cellulose nanoparticles', Nashrieh Shimi va Mohandesi Shimi Iran, (), pp. -.
VANCOUVER
sandaroos, R. Synthesis of chromenes from benzyl alcohol derivatives using Schiff base cobalt (II) catalyst bonded to crown ether and supported on cellulose nanoparticles. Nashrieh Shimi va Mohandesi Shimi Iran, 2023; (): -.