Improving CMP Pulping Process of Eucalyptus by Using of Surfactants

Document Type : Research Note

Authors

1 Department of Wood and Paper Science and Technology, Faculty of Natural resources, University of Tehran, P.O. Box 31585-4314 Karaj, I.R. IRAN

2 Wood and Paper Science Research Division, Research Institute of Forests and Rangelands, Tehran, I.R. IRAN

Abstract

In this research the effect of three non-ionic surfactants named PEG-1000, KELA-2 and KECA-20 at four levels of 1, 2, 3 and 4 % on CMP pulping of Eucalyptus Camaldulensis, oxidative bleaching of selected pulps and strength of handsheet papers were investigated.The resulting pulps with higher screen yield and lower reject from application of each surfactant as well as the reference CMP pulps (without surfactant) were selected and bleached in two stages with H2O2. The pulping results showed that application of KECA-20 at the level of 1% increased accepted yield by about 2.5%. KECA-20 (1%) and PEG-1000 (4%) at the level of 1% lowered the consumption of bleaching agents and increased brightness and decreased opacity and yellowness of pulp. In addition, application of surfactants increased strength of handsheet papers compared to the paper obtained from the reference CMP pulp.

Keywords

Main Subjects


[1] Sei Hl, Ulkem N., Berk D., Kubes G.J. Neutral Sulphite Pulping with Surfactants, J. Pulp Pap. Sci., 31(4), p. 188 (2005)
[2] Sixta H., "Handbook of Pulp",Wiley-Vch, Germany, pp. 1098-1111, (2006).
[3] Khristova P., Kordsachia O., Patt R., Dafaala S., Alkaline Pulping of Some Eucalypts from Sudan, Biores. Techno., 97(4), p. 535 (2006).
[4] Miranda I., Almedia M.H., Pereira H., Provenance and Site Variation of Wood Density in Eucalyptus Globules Labill. At Harvest Age and its Relation to a Non-Destructive Early Assessment, Forest. Eco. Manage., 149(1-3), p. 235 (2001).
[5] Inalbon M.C., Mussati M.C., Znuttini M.A., Experimental and Theoretical Analysis of the Alkali Impregnation of Eucalyptus Wood, Ind. Eng. Chem. Res., 48(10), p. 4791 (2009).
[6] Malkov S., Tikka P., Gullichsen J., Towards Complete Impregnation of Wood Chips with Aqueous Solution- Part 2. Studies on Water Penetration into softwood chips, Pap. Puu., 83(6), p. 1 (2001)
[7] همزه، یحیی؛ ابیض، علی؛ میرفتاحی، مهسا السادات؛ عبدالخانی، علی؛ استفاده از سورفکتانت­ها برای بهبود خمیر کاغذسازی از باگاس به روش سودا، نشریه شییمی و مهندسی شیمی ایران، (2) 57، (1389)
[8] Baptista C., Belgacem N., Duarte A.P., The Effect of Surfactant on Kraft Pulpinf of Pinus pinaster, Appita J., 57(1), p. 35 (2004).
[9] Silva D.D.J., Gomide J.L., Colodette J.L., Surfactant Utilization in Kraft Pulping of Eucalyptus Wood to Improve Lipophilic Extractives Removal, R. Arvore Viçosa-MG., 28(6), p. 911 (2004).
[10] Shaw D.J., "Introduction to Colloid and Surface Chemistry",4th Ed. Elsevier Science Ltd., England, pp. 30-315, (1992).
[11] Mouyal P., Efficient Resin Removal, Paper Age, 121(6), p. 34 (2005).
[12] Hongmei W., Ulkem N., Berk D., Kubes G.J., The Role of Surfactants in Wood Deresination, Cellul. Chem. & Technol., 40(1), p. 71 (2006).
[13] Qin M., Holmbom B., Effect of Hydrophilic Substances in Spruce TMP Resin on its Physico-Chemical Characterization and Deposition Tendency, Colloids and surfaces. A, Physicochemical and Engineering Aspects, 312 (2-3), p. 226 (2008).
[14] Hubbe M.A., Flocculation and Redispersion of Cellulosic Fiber Suspensions: A Review of Effects of Hydrodynamic Shear and Polyelectrolytes, BioRes., 2(2), p. 296 (2007).