Reaction of poly(methyl methacrylate / maleic anhydride) with phenylhydazine and 4- aminobenzoic acid and their use as mild steel (ST-37) corrosion inhibitor

Document Type : Research Article

Authors

Department of Chemistry, College of Science, Malek-ashtar University of Technology, Shahin-shahr, P.O. Box 83145/115, Islamic Republic of Iran

Abstract

In this study, phenylhydrazine and 4-aminobenzoic acid were reacted with co-polymer (methyl methacrylate / maleic anhydride) and in the following, used as a corrosion inhibitor of low carbon steel. The chemical structure of copolymers was identified by spectroscopy of FT-IR and H-NMR, also titration and viscosity test. the amount of thermal resistance synthesized copolymers was investigated by thermal analysis of TGA, DTG and DSC. the results indicated that the thermal resistance of P (MMA-MA) / PhH and P (MMA-MA) / ABA in comparison with the (MMA-MA) has increased. In the following, via electrochemical potentiodynamic polarization tests, EDX and FE-SEM, the effectiveness and inhibition capability of copolymers in hydrochloric acid of 0.5 mol was investigated. The results showed that corrosion rate of co-polymers are (MMA-MA) <P(MMA-MA) /PhH <(P(MMA-MA)/ABA respectively.

Keywords

Main Subjects

References

[1] پورستار مرجانی. احمد، محمودیان. مهدی، نوزاد. احسان، محمدی. هانیه، اصلاح گرافن اکسید به روش پلیمریزاسیون درجا و استفاده از آن به عنوان نانو کامپوزیت پلی متیل متاکریلات، نشریه شیمی و مهندسی شیمی ایران، (4)38:  43تا52 (1398).
 [2] Ali U., Karim K. J. B. A., Buang N. A., A Review of the Properties and Applications of Poly (Methyl Methacrylate)(PMMA), Polym. Rev., 55: 678-705 (2015)..
[3] Atabaki F., Abdolmaleki A., Barati A., Free Radical Copolymerization of Methyl Methacrylate and N-2-Methyl-4-Nitro-Phenylmaleimide: Improvement in the T g of PMMA, Colloid. Polym. Sci., 294: 455-462 (2016)..
[4] Tagaya A., Lou L., Ide Y., Koike Y., Okamoto Y., Improvement of the Physical Properties of Poly (Methyl Methacrylate) by Copolymerization with N-Pentafluorophenyl Maleimide; Zero-Orientational and Photoelastic Birefringence Polymers with High Glass Transition Temperatures, Sci. China. Chem., 55: 850-853 (2012)..
[5] Babazadeh M., Synthesis, Characterization, and Thermal Behavior Study of Methyl Methacrylate Polymers Containing 4‐Carbazole Substitutes, Journal of applied Polymer Science, 102: 4989-4995 (2006)..
[6] Sakurabayashi Y., Masaki T., Iwao T., Yumoto M., Surface Hardness Improvement of PMMA by Low‐Energy Ion Irradiation and Electron Irradiation, Electr. Commun. Jpn., 94: 19-26 (2011)..
[7] Jin W., Hao Q., Peng X., Chu P. K., Enhanced Corrosion Resistance and Biocompatibilty of PMMA-Coated ZK60 Magnesium Alloy, Mater. Lett., 173: 178-181 (2016)..
[8] Lou L., Koike Y., Okamoto Y., A Novel Copolymer of Methyl Methacrylate with Npentafluorophenyl Maleimide: High Glass Transition Temperature and Highly Transparent Polymer, Polym, 52: 3560-3564 (2011)..
[9] Chopra D., Kontopoulou M., Vlassopoulos D., Hatzikiriakos S. G., Effect of Maleic Anhydride Content on the Rheology and Phase Behavior of Poly (Styrene-Co-Maleic Anhydride)/Poly (Methyl Methacrylate) Blends, Rheologica Acta, 41: 10-24 (2002).
[10] Atabaki F., Shokrolahi A., Pahnavar Z., Methyl Methacrylate Based Copolymers and Terpolymers: Preparation, Identification, and Plasticizing Capability for a Poly (Methyl Methacrylate) Used in Aviation, J. Appl. Polym. Sci., 135: 4660 (2018).
[11] Murillo E. A. López B. L., Effect of the Maleic Anhydride Content on the Structural, Thermal, Rheological and Film Properties of the N-Butyl Methacrylate–Maleic Anhydride Copolymers, Prog. Org. Coat., 78: 96-102 (2015)..
[12] Nasirtabrizi M. H, Ziaei Z. M., Jadid A. P., Fatin L. Z., Synthesis and Chemical Modification of Maleic Anhydride Copolymers with Phthalimide Groups, Int. J. Ind. Chem., 4: 11 (2013).
[13] Zhou J., Wang L., Wang C., Chen T., Yu H. Yang Q., Synthesis and Self-Assembly of Amphiphilic Maleic Anhydride–Stearyl Methacrylate Copolymer, Polym, 46: 11157-11164 (2005).
[14] Syed J. A., Tang S., Lu H., Meng X., Water-Soluble Polyaniline–Polyacrylic Acid Composites as Efficient Corrosion Inhibitors for 316SS, Ind. Eng. Chem. Res., 54: 2950-2959 (2015)..
. [15] Tiu B.D. B. Advincula R. C., Polymeric Corrosion Inhibitors for the Oil and Gas Industry: Design Principles and Mechanism ,React. Func. Polym., 95: 25-45 (2015)..
[16] Kumar S., Vashisht H., Olasunkanmi L. O., Bahadur I., Verma H., Singh G., et al.,Experimental and Theoretical Studies on Inhibition of Mild Steel Corrosion by Some Synthesized Polyurethane Tri-Block Co-Polymers, Sci. Rep., 6: 30937 (2016).
[17] Solomon M. M. Umoren S. A., Performance Evaluation of Poly (Methacrylic Acid) as Corrosion Inhibitor in the Presence of Iodide Ions for Mild Steel in H2SO4 Solution, J. Adhesion. Sci. Technol., 29: 1060-1080 (2015).
[18] Singh A., Lin Y.-h., Zhu C.-y., Wu Y.-p., Ebenso E. E., Use of HPHT Autoclave to Determine Corrosion Inhibition Effect of Poly (Methyl Methacrylate-Co-N-Vinyl-2-Pyrrolidone) on Carbon Steels in 3.5% NaCl Solution Saturated with CO2, Chinese J. Polym. Sci, 33: 339-348 (2015).
[19] Vinutha M. Venkatesha T., Review on Mechanistic Action of Inhibitors on Steel Corrosion in Acidic Media, Portugaliae Electrochimica Acta, 34: 157-184 (2016).
[20] Roy P., Karfa P., Adhikari U., Sukul D., Corrosion Inhibition of Mild Steel in Acidic Medium by Polyacrylamide Grafted Guar Gum with Various Grafting Percentage: Effect of Intramolecular Synergism, Corros. Sci., 88: 246-253 (2014).
[21] Umoren S. Solomon M., Effect of Halide Ions on the Corrosion Inhibition Efficiency of Different Organic Species–A Review, J. Ind. Eng. Chemi., 21: 81-100 (2015).
[22] عباسپور. سوگند، اشرفی. علی،صالحی. مهدی، سهیلی. راضیه، اثر مقدار میکروکپسول­ های اتیل سلولز بر مقاومت خوردگی پوشش خودترمیم شونده پایه پلی یورتان، نشریه شیمی و مهندسی شیمی ایران، (2)35: 121-130(1395).
 [23] Goyal M., Kumar S., Bahadur I., Verma C., Ebenso E. E., Organic Corrosion Inhibitors for Industrial Cleaning of Ferrous and Non-Ferrous Metals in Acidic Solutions: A Review, J. Mol. Liq, (2018).
[24] Raja P. B., Ismail M., Ghoreishiamiri S., Mirza J., Ismail M. C., Kakooei S., et al., Reviews on Corrosion Inhibitors: A Short View, Chem. Eng. Commun, 203: 1145-1156 (2016).
[25] Boztuğ A. Basan S., Modification and Characterization of Maleic Anhydride-Styrene-Methyl Metacrylate Terpolymer Using Various Alcohols, Des. Monomers. polym, 9: 617-626 (2006).
[26] Yousif E., Abdalla M., Ahmed A., Salimon J., Salih N., Photochemical Stability and Photostabilizing Efficiency of Poly (Methyl Methacrylate) Based on 2-Thioacetic Acid-5-Phenyl-1, 3, 4-Oxadiazole Complexes, Arab. J. Chem, 9: S595-S601 (2016).
[27] Yousif E., Yusop R. M., Ahmed A., Salimon J., Salih N., Photostabilizing Efficiency Of PVC Based On Epoxidized Oleic Acid, Malaysian .J. Anal. Sci, 19: 213-221 (2015).
[28] Yousif E., Salimon J., Salih N., Mechanism of Photostabilization of Poly (Methy Methacrylate) Films by 2-Thioacetic Acid Benzothiazol Complexes, Arab. J. Chem, 7: 306-311 (2014).
[29] Albuquerque M. C. C. d., Garcia O. P., Aquino K. A. d. S., Araujo P. L. B. d., Araujo E. S., Stibnite Nanoparticles as a New Stabilizer for Poly (Methyl Methacrylate) Exposed to Gamma Irradiation, Mate. Res ,18: 978-983 (2015).
[30] Xiao L., Li Z., Dong J., Liu L., Shang L., Zhang X., et al., Fabrication of Poly (Methyl Methacrylate-Co-Maleic Anhydride) Copolymers and Their Kinetic Analysis of the Thermal Degradation, Colloid. Polym. Sci, 293: 2807-2813 (2015).
[31] Becker D., Hage Jr E., Pessan L., Synthesis and Characterization of Poly (Methyl Methacrylate‐Co‐Maleic Anhydride) Copolymers and Its Potential as a Compatibilizer for Amorphous Polyamide Blends, J. appl. Polym. Sci, 106: 3248-3252 (2007).
[32] Pauline S. A., Sahila S., Gopalakrishnan C., Nanjundan S., Rajendran N., Synthesis, Characterization and Corrosion Protection Property of Terpolymers Derived from Poly (MAn-co-MMA) Containing Benzimidazole Derivative as Pendant Group, Prog. Org. Coat,72: 443-452 (2011).
[33] Yue W.-W., Xiang T., Zhao W.-F., Sun S.-D., Zhao C.-S., Preparation and Characterization of pH-Sensitive Polyethersulfone Membranes Blended with Poly (Methyl Methacrylate-Co-Maleic Anhydride) Copolymer, Sep. Sci.Technol ,48: 1941-1953 (2013).
[34] Kesim H., Rzaev Z. M., Dinçer S., Pişkin E., Functional Bioengineering Copolymers. II. Synthesis and Characterization of Amphiphilic Poly (N-Isopropyl Acrylamide-Co-Maleic Anhydride) and Its Macrobranched Derivatives, Polym, 44: 2897-2909 (2003).
[35] Menczel J. D. Prime R. B., Thermal Analysis of Polymers: Fundamentals and Applications, John Wiley & Sons, 2009.
[36] Nouri P. Attar M., An Imidazole-Based Antifungal Drug as a Corrosion Inhibitor for Steel in Hydrochloric Acid, Chem. Eng. Commun, 203: 505-515 (2016).
[37] Zhang Z., Chen S., Li Y., Li S., Wang L., A Study of the Inhibition of Iron Corrosion by Imidazole and Its Derivatives Self-Assembled Films, Corros. Sci, 51: 291-300 (2009).
Nashrieh Shimi va Mohandesi Shimi Iran
Volume 41, Issue 3 - Serial Number 105
September 2022
Pages 97-110

Files

Share

How to cite

Statistics