Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Investigation of the Electrical Field Effect on Silver Nanoparticles Stabilized by Sodium Citrate and Polyvinylpyrrolidone

Document Type : Research Article

Authors
Reza Faraji Yaychi
Mehrdad Manteghian
Nanotechnology Department, Faculty of Engineering, Tarbiat Modares University, Tehran, I.R. IRAN
Abstract
Investigation of electrical field effect on nanoparticles can be important in the electrochemical treatment of industrial and urban wastewaters contaminated by nanoparticles. Because the excessive presence of nanoparticles in the environment can be harmful to organisms and humans. The behavior of silver nanoparticles (AgNPs) under an applied electric field depends primarily on their stabilizing agent. This research is aimed at investigating the behavior of AgNPs and their stabilizers under the electric field, which called “electrocoagulation”. Silver nitrate and hydrazine hydrate were used as the sources of silver ion and reducing agent, respectively. In separate experiments, sodium citrate and polyvinylpyrrolidone (PVP) were used as nanoparticle stabilizers. The stability of the particles was studied when an electrical current was applied with different voltages. The efficiency of the EC process was investigated for different of AgNP sols. With sodium citrate for different voltages, after using the electric field for 90min, the plasmon resonance peak of the sample disappeared, reflecting the removal of the AgNPs in the sol by 99.91%. With PVP, by using different voltages of the EC, for10 min, the absorbance peaks disappeared,
and removal efficiency of the AgNPs reached 99.98%. Based on these results, it can be recognized that the AgNPs stabilized by citrate, are slightly more stable, whereas AgNPs solutions prepared by PVP showed better results on floc formation and, therefore, agglomerated more easily.
Keywords
Silver nanoparticles
Sodium citrate
PVP
Stabilizer
Electrical field
Subjects
[1] Kobya M., Ulu F., Gebologlu U., Demirbas E., Oncel M.S., Treatment of Potable Water Containing Low Concentration of Arsenic with Electrocoagulation: Different Connection Modes and Fe–Al Electrodes, Separation and Purification Technology, 77 (3): 283-293 (2011).
[2] Lu J., Li Y., Yin M., Ma X., Lin S., Removing Heavy Metal Ions with Continuous Aluminum Electrocoagulation: A Study on Back Mixing and Utilization Rate of Electro-Generated  Al Ions, Chemical Engineering Journal, 267: 86-92 (2015).
[3] Fadali O., Ebrahiem E., El-Gamil A., Altaher H., Investigation of the Electrocoagulation Treatment Technique for the Separation of Oil from Wastewater, Journal of Environmental Science and Technology, 9 (1): 62 (2016).
[4] Elabbas S., Ouazzani N., Mandi L., Berrekhis F., Perdicakis M., Pontvianne S., Pons M., Lapicque F., Leclerc J., Treatment of Highly Concentrated Tannery Wastewater Using Electrocoagulation: Influence of the Quality of Aluminium used for the Electrode, Journal of Hazardous Materials, 319: 69-77 (2016).
[5] Mansoorian H.J., Mahvi A.H., Jafari A.J., Removal of Lead and Zinc from Battery Industry Wastewater Using Electrocoagulation Process: Influence of Direct and Alternating Current by Using iron and Stainless Steel Rod Electrodes, Separation and Purification Technology, 135: 165-175 (2014).
[6] de Carvalho H.P., Huang J., Zhao M., Liu G., Dong L., Liu X., Improvement of Methylene Blue Removal by electrocoagulation/banana Peel Adsorption Coupling in a Batch System, Alexandria Engineering Journal, 54 (3): 777-786 (2015).
[7] García-García A., Martínez-Miranda V., Martínez-Cienfuegos I.G., Almazán-Sánchez P.T., Castañeda-Juárez M., Linares-Hernández I., Industrial Wastewater Treatment by Electrocoagulation–Electrooxidation Processes Powered by Solar Cells, Fuel, 149: 46-54 (2015).
[8] Elnenay A.M.H., Nassef E., Malash G.F., Magid M.H.A., Treatment of Drilling Fluids Wastewater by Electrocoagulation, Egyptian Journal of Petroleum, 26(1): 203-208 (2016).
[9] Millar G.J., Lin J., Arshad A., Couperthwaite S.J., Evaluation of Electrocoagulation for the Pre-Treatment of Coal Seam Water, Journal of Water Process Engineering, 4: 166-178 (2014).
[10] Kobya M., Demirbas E., Evaluations of Operating Parameters on Treatment of can Manufacturing Wastewater by Electrocoagulation, Journal of Water Process Engineering, 8:64-74 (2015).
[11] Nguyen D.D., Ngo H.H., Guo W., Nguyen T.T., Chang S.W., Jang A., Yoon Y.S., Can Electrocoagulation Process be an Appropriate Technology for Phosphorus Removal from Municipal Wastewater?, Science of the Total Environment, 563: 549-556 (2016).
[12] El-Taweel Y.A., Nassef E.M., Elkheriany I., Sayed D., Removal of Cr (VI) Ions from Waste Water by Electrocoagulation Using Iron Electrode, Egyptian Journal of Petroleum, 24 (2): 183-192 (2015).
[13] Mahmad M.K.N., Rozainy M.M.R., Abustan I., Baharun N., Electrocoagulation Process by Using Aluminium and Stainless Steel Electrodes to Treat Total Chromium, Colour and Turbidity, Procedia Chemistry, 19: 681-686 (2016).
[14] Yazdanbakhsh A.R., Massoudinegad M.R., Eliasi S., Mohammadi A.S., The Influence of Operational Parameters on Reduce of Azithromyin COD from Wastewater Using the Peroxi-Electrocoagulation Process, Journal of Water Process Engineering, 6: 51-57 (2015).
[15] Manikandan P., Palanisamy P., Baskar R., Sakthisharmila P., Sivakumar P., A Comparative Study on the Competitiveness of Photo-Assisted Chemical Oxidation (PACO) with Electrocoagulation (EC) for the Effective Decolorization of Reactive Blue Dye, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 36 (1): 71-85 (2017).
[16] Fajardo A.S., Rodrigues R.F., Martins R.C., Castro L.M., Quinta-Ferreira R.M., Phenolic Wastewaters Treatment by Electrocoagulation Process Using Zn Anode, Chemical Engineering Journal, 275: 331-341 (2015).
[17] Naje A.S., Chelliapan S., Zakaria Z., Abbas S.A., Electrocoagulation Using a Rotated Anode: A Novel Reactor Design for Textile Wastewater Treatment, Journal of Environmental Management, 176: 34-44 (2016).
[18] Zhi S.-l., Zhang K.-q., Hardness Removal by a Novel Electrochemical Method, Desalination, 381: 8-14 (2016).
[19] Kuokkanen V., Kuokkanen T., Rämö J., Lassi U., Roininen J., Removal of Phosphate from Wastewaters for Further Utilization Using Electrocoagulation with Hybrid Electrodes–Techno-Economic Studies, Journal of Water Process Engineering, 8:e50-e57 (2015).
[20] Den W., Huang C., Electrocoagulation for Removal of Silica Nano-Particles from Chemical–Mechanical-Planarization Wastewater, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 254 (1): 81-89 (2005).
[21] Hou L., Xia J.,. Li K, Chen J., Wu X.,. Li X, Removal of ZnO Nanoparticles in Simulated Wastewater Treatment Processes and Its Effects on COD and NH4+-N Reduction, Water Science and Technology, 67 (2): 254-260 (2012).
[22] Sun Q., Li Y., Tang T., Yuan Z., Yu C.-P., Removal of Silver Nanoparticles by Coagulation Processes, Journal of Hazardous Materials, 261: 414-420 (2013).
[23] Matias M.S., Melegari S.P., Vicentini D.S., Matias W.G., Ricordel C., Hauchard D., Synthetic Wastewaters Treatment by Electrocoagulation to Remove Silver Nanoparticles Produced by Different Routes, Journal of Environmental Management 159: 147-157 (2015).
[24] Yehya T., Chafi M., Balla W., Vial C., Essadki A., Gourich B., Experimental Analysis and Modeling of Denitrification Using Electrocoagulation Process, Separation and Purification Technology, 132: 644-654 (2014).
[25] Al-Shannag M., Al-Qodah Z., Bani-Melhem K., Qtaishat M.R., Alkasrawi M., Heavy Metal Ions Removal from Metal Plating Wastewater Using Electrocoagulation: Kinetic Study and Process Performance, Chemical Engineering Journal, 260: 749-756 (2015).
[26] Kobya M., Demirbas E., Ulu F., Evaluation of Operating Parameters with Respect to Charge Loading on the Removal Efficiency of Arsenic from Potable Water by Electrocoagulation, Journal of Environmental Chemical Engineering, 4 (2):1484-1494 (2016).
[27] Prajapati A.K., Chaudhari P.K., Pal D., Chandrakar A., Choudhary R., Electrocoagulation Treatment of Rice Grain Based Distillery Effluent Using Copper Electrode, Journal of Water Process Engineering, 11: 1-7 (2016).
[28] Gatsios E., Hahladakis J.N., Gidarakos E., Optimization of Electrocoagulation (EC) Process for the Purification of a Real Industrial Wastewater from Toxic Metals, Journal of Environmental Management, 154: 117-127 (2015).
[29] Lacasa E., Cañizares P., Sáez C., Fernández F.J., Rodrigo M.A., Removal of Nitrates from Groundwater by Electrocoagulation, Chemical Engineering Journal, 171 (3): 1012-1017 (2011).
[30] Kuokkanen V., Kuokkanen T., Rämö J., Lassi U., Electrocoagulation Treatment of Peat Bog Drainage Water Containing Humic Substances, Water Research, 79: 79-87 (2015).
[31] Yang B., Han Y., Yu G., Zhuo Q., Deng S., Wu J., Zhang P., Efficient Removal of Perfluoroalkyl Acids (PFAAs) from Aqueous Solution by Electrocoagulation Using Iron Electrode, Chemical Engineering Journal, 303: 384-390 (2016).
[32] Sahu O., Performance of Copper Compounds in Chemical and Electro 0xidation treatment 
of Sugar Industry Waste Water: Batch Reaction, Journal of the Taiwan Institute of Chemical Engineers: (2016).
[33] Liu Y.-H., Lin C.-Y., Huang J.-H., Yen S.-C., Particle Removal Performance and its Kinetic Behavior During Oxide-CMP Wastewater Treatment by Electrocoagulation, Journal of the Taiwan Institute of Chemical Engineers, 60:520-524 (2016).
[34] Govindan K., Raja M., Maheshwari S.U., Noel M., Oren Y., Comparison and Understanding of Fluoride Removal Mechanism in Ca2+, Mg2+ and Al3+ Ion Assisted Electrocoagulation Process Using Fe and Al Electrodes, Journal of Environmental Chemical Engineering, 3(3):1784-1793 (2015).
[35] Hou L., Li K., Ding Y., Li Y., Chen J., Wu X., Li X., Removal of Silver Nanoparticles in Simulated Wastewater Treatment Processes and its Impact on COD and NH4 Reduction, Chemosphere, 87 (3):248-252 (2012).
[36] Kaegi R., Voegelin A., Sinnet B., Zuleeg S., Hagendorfer H., Burkhardt M., Siegrist H., Behavior of Metallic Silver Nanoparticles in a Pilot Wastewater Treatment Plant, Environmental Science & Technology, 45 (9):3902-3908 (2011).
[37] Kamali M., Ghorashi S.A.A., Asadollahi M.A., Controllable Synthesis of Silver Nanoparticles Using Citrate as Complexing Agent: Characterization of Nanopartciles and Effect of pH on Size and Crystallinity, Iranian Journal of Chemistry and Chemical Engineering (IJCCE), 31 (4):21-28 (2012).
[38] Ghader S., Manteghian M., Kokabi M., Mamoory R.S., Induction Time of Reaction Crystallization of Silver Nanoparticles, Chemical Engineering & Technology, 30 (8):1129-1133 (2007).
[39] Ibarra-Hurtado J., Virgen-Ortiz A., Apolinar-Iribe A., Luna-Velasco A., Control and Stabilization of Silver Nanoparticles Size Using Polyvinylpyrrolidone at Room Temperature, Digest Journal of Nanomaterials & Biostructures (DJNB), 9 (2): 493-501 (2014).
[40] Paramelle D., Sadovoy A., Gorelik S., Free P., Hobley J., Fernig D.G., A Rapid Method to Estimate the Concentration of Citrate Capped Silver Nanoparticles from UV-Visible Light Spectra, Analyst, 139 (19):4855-4861 (2014).
[41] Akyol A., Can O.T., Bayramoglu M., Treatment of Hydroquinone by Photochemical Oxidation and Electrocoagulation Combined Process, Journal of Water Process Engineering, 8: 45-54 (2015).
[42] Yao Y., Wei Y., Chen S., Size Effect of the Surface Energy Density of Nanoparticles, Surface Science, 636:19-24 (2015).
[43] Aswathy P., Gandhimathi R., Ramesh S., Nidheesh P., Removal of Organics from Bilge Water by Batch Electrocoagulation Process, Separation and Purification Technology, 159:108-115 (2016).
[44] گلزاری، ابوعلی؛ عبدلی، محمد علی؛ خدادادی، عباسعلی؛ کرباسی، عبدالرضا؛ ایمانیان، سجاد، بررسی فرایندهای انعقاد الکتریکی و شیمیایی برای جداسازی میکروجلبک های آب شور، نشریه شیمی و مهندسی شیمی ایران، (1)35 : 39 تا 52 (1395).