Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Fabrication of a Polymer Inclusion Membrane Containing Dicyclohexano-18-Crown-6 for Extraction of Cr(VI) from Aqueous Solutions

Document Type : Research Article

Authors
Meysam Ahmadi 1
Leila Dolatyari 2
Mohammad Reza Yaftian 1
1 Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan, I.R. IRAN
2 Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, I.R. IRAN
Abstract
A variety of polymer inclusion membranes (PIMs) based on the poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), cellulose triacetate (CTA) and poly(vinyl chloride) (PVC) polymers with different proportion of dicyclohexano-18-crown-6 (DC18C6) as extractant, 2-nitrophenyl octyl ether (NPOE) as plasticizer were fabricated. PIM containing 45% PVC, 20% DC18C6 and 35% NPOE was selected as the optimum PIM composition because of their satisfactory physical, mechanical and extraction properties. The effect of parameters affecting the extraction process such as pH, extraction time, type and concentration of electrolyte and initial concentration of Cr(VI) were investigated and its shown that the PIM were able to extract 57% of chromium ions from 50 mL solution containing 2×10-4 mol/L of chromium(VI) and 1.2 mol/L HCl in 22 h. The maximum capacity of the selected PIM for extraction of chromium ions was 7 mg of of Cr per 1 g of membrane. The selectivity of the PIM towards Cr(VI) was tested in the presence of Zn(II), Cu(II), Fe(II), Cd(II), Ni(II) and nitrate ions and indicated that the PIM can extract selectively V(V) from the mixtures containing these heavy metal ions. The PIMs were used successfully for extraction of Cr(VI) from various water samples. The isotherms and kinetics of the processes were well described by Dubinin Radushkevich and pseudo second order models, respectively. These analyses revealed the process might be chemical processes.
Keywords
Polymer Inclusion Membrane
Dicyclohexano-18-crown-6
Cr(VI)
Extraction
Kinetics
Isotherm

Subjects

[1] Tchounwou P.B., Yedjou C.G., Patlolla A.K., Sutton D.J., Heavy Metal Toxicity and the Environment. Molecul. Clin. Environ. Toxicol., 133: 133-164 (2012).
[2] Ahmed S.F., Kumar P.S., Rozbu M.R., Chowdhury A.T., Nuzhat S., Rafa N., Mahlia T.M., Ong H.C., Mofijur M., Heavy Metal Toxicity, Sources, and Remediation Techniques for Contaminated Water and Soil. Environ. Technol. Innov., 1: 102114 (2022).
[3] Sharma P., Singh S.P., Parakh S.K., Tong Y.W., Health Hazards of Hexavalent Chromium (Cr (VI)) and Its Microbial Reduction. Bioengineered, 1: 4923-38 (2022).
[4] Agency for Toxic Substances and Disease Registry (ATSDR), Priority List of Hazardous Substances, Division of Toxicology and Environmental Medicine, Atlanta (2019).
[5] Hami Dindar M., Yaftian M.R., Hajihasani M., Rostamnia S., Refinement of Contaminated Water by Cr(VI), As(V) and Hg(II) Using N-donor Ligands Arranged on SBA-15 Platform; Batch and Fixed-bed Column Methods. J. Taiwan Inst. Chem. Eng., 67: 325-337 (2016).
[6] Bahrami S., Yaftian M.R., Najvak P., Dolatyari L., Shayani-Jam H., Kolev S.D., PVDF-HFP Based Polymer Inclusion Membranes Containing Cyphos® IL 101 and Aliquat® 336 for the Removal of Cr(VI) from Sulfate Solutions. Sep. Purif. Technol., 250: 117251 (2020).
[7] Prasad S., Yadav K.K., Kumar S., Gupta N., Cabral-Pinto M.M., Rezania S., Radwan N., Alam J., Chromium Contamination and Effect on Environmental Health and Its Remediation: A Sustainable Approaches. J. Environ. Manag., 1(285): 112174 (2021).
[8] Shrestha R., Ban S., Devkota S., Sharma S., Joshi R., Tiwari A.P., Kim H.Y., Joshi M.K., Technological Trends in Heavy Metals Removal from Industrial Wastewater: A review. J. Environ. Chem. Eng., 9(4): 105688 (2021).
[9] Hussain S.T., Ali S.A.K., Removal of Heavy Metal by Ion Exchange Using Bentonite Clay. J. Ecological Eng., 22(1): 104-111 (2021).
[۱۰] اسدی، مهدی؛ آزرده، سهیلا؛ حذف یون فلزهای سنگین Cd2+ و  Pb2+از آب با نانو مواد متخلخل، نشریه شیمی و مهندسی شیمی ایران، 39(4): 13 تا 23 (1399).
[11] Dolatyari L., Yaftian M.R., Rostamnia S., Th(IV)/U(VI) Sorption on Modified SBA–15 Mesoporous Materials in Fixed–Bed Column. Iran. Chem. Chem. Eng. (IJCCE), 36(6): 115-125 (2017).
[12] Sun Q., Wang W., Yang L., Huang S., Xu Z., Ji Z., Li Y., Hu Y., Separation and Recovery of Heavy Metals From Concentrated Smelting Wastewater by Synergistic Solvent Extraction Using a Mixture of 2-hydroxy-5-nonylacetophenone Oxime and Bis (2, 4, 4-trimethylpentyl)-phosphinic Acid. Solv. Extr. Ion Exc., 36(2): 175-90 (2018).
[13] Imdad S., Dohare R.K., A Critical Review on Heavy Metals Removal Using Ionic Liquid Membranes From the Industrial Wastewater. Chem. Eng. Process -Process Intensif., 173: 108812 (2022).
[14] Chen L., Wu Y., Dong H., Meng M., Li C., Yan Y., Chen J., An Overview on Membrane Strategies for Rare Earths Extraction and Separation. Sep. Purif. Technol., 197: 70-85 (2018).
[15] Han A., Zhang H., Sun J., Chuah G.K., Jaenicke S., Investigation into Bulk Liquid Membranes for Removal of Chromium(VI) From Simulated Wastewater. J. Water Process Eng., 17: 63–69 (2017).
[16] Hajilou E., Yaftian M. R., Dolatyari, L., Selective Emulsion Liquid Membrane Extraction of Cu(II) Mediated by a Schiff Base Ligand, Iran. Chem. Chem. Eng., 40(6): 2008-2018 (2021).
[17] Zante G., Boltoeva M., Masmoudi A., Barillon R., Trébouet D., Supported Ionic Liquid and Polymer Inclusion Membranes for Metal Separation. Sep. Purif. Rev., 51(1): 100-16 (2022).
[18] Zulkefeli N.S.W., Weng S.K., Halim N.S.A., Removal of Heavy Metals by Polymer Inclusion Membranes. Curr. Pollut. Rep., 4: 84–92 (2018).
[19] Saik Su G., Morad N., Ismail N., Rafatullah M., Developments in Supported Liquid Membranes for Treatment of Metal-Bearing Wastewater. Sep. Purif. Rev., 51(1): 38-56 (2022).
[20] Keskin B., Zeytuncu-Gökoğlu B., Koyuncu I., Polymer Inclusion Membrane Applications for Transport of Metal Ions: A Critical Review. Chemosphere, 279: 130604 (2021).
[21] Nghiem L.D., Mornane P., Potter I.D., Perera J.M., Cattrall R.W., Kolev S.D., Extraction and Transport of Metal Ions and Small Organic Compounds Using Polymer Inclusion Membranes (PIMs). J. Membr. Sci., 281(1-2): 7-41 (2006).
[22] Almeida M.I.G.S., Cattrall R.W., Kolev S.D., Recent Trends in Extraction and Transport of Metal Ions Using Polymer Inclusion Membranes (PIMs). J. Membr. Sci., 415: 9-23 (2012).
[23] Almeida M.I.G.S., Cattrall R.W., Kolev S.D., Polymer Inclusion Membranes (PIMs) in Chemical Analysis - A Review. Anal. Chim. Acta, 987: 1-14 (2017).
[24] Özbek O., Isildak Ö., Gürdere M.B., Cetin A., The Use of Crown Ethers as Sensor Material in Potentiometry Technique. Org. Commun., 14(3):  228-239 (2021).
[25] Fan Y., Li Y., Shu X., Wu R., Chen S., Jin Y., Xu C., Chen J., Huang C., Xia C., Complexation and Separation of Trivalent Actinides and Lanthanides by a Novel DGA Derived from Macrocyclic Crown Ether: Synthesis, Extraction, and Spectroscopic and Density Functional Theory Studies. ACS Omega, 6(3): 2156-66 (2021).
[26] Golcs Á., Bezúr L., Huszthy P., Tóth T., Liquid-Liquid Extraction and Facilitated Membrane Transport of Pb2+ Using a Lipophilic Acridono-Crown Ether as Carrier. J. Incl. Phenom. Macro., 99(1): 117-29 (2021).
[27] Zouhri A., Ernst B., Burgard M., Bulk Liquid Membrane for the Recovery of Chromium(VI) From a Hydrochloric Acid Medium Using Dicyclohexano-18-crown-6 as Extractant-Carrier. Sep. Sci. Technol., 34: 1891-1905 (1999).
[28] Walkowiak W., Bartsch R., Kozlowski C., Gega J., Charewicz W., Amiri-Eliasi B., Separation and Removal of Metal Ionic species by Polymer Inclusion Membranes. J. Radioanal. Nucl. Chem., 246: 643-650 (2000).
[29] Ulewicz M., Walkowiak W., Removal of Zn(II), Cd(II) and Pb(II) Using Polymer Inclusion Membrane Transport with Proton Ionizable DB-16-C-5 crown Ethers. Physicochem. Probl Mi., 40: 185-194 (2006).
[30] Ulewicz M., Sadowska K., Biernat J.F., Facilitated Transport of Zn(II), Cd(II) and Pb(II) Across Polymer Inclusion Membranes Doped with Imidazole Azocrown Ethers. Desalination, 214: 352-364 (2007).
[31] Ulewicz M., Lesinska U., Bochenska M., Walkowiak W., Facilitated Transport of Zn(II), Cd(II) and Pb(II) Ions Through Polymer Inclusion Membranes with Calix [4]-Crown-6 Derivatives. Sep. Purif. Technol., 54: 299-305 (2007).
[32] Mohapatra P., Lakshmi D., Bhattacharyya A., Manchanda V., Evaluation of Polymer Inclusion Membranes Containing Crown Ethers for Selective Cesium Separation from Nuclear Waste Solution. J. Hazard. Mater., 169: 472-479 (2009).
[33] Yaftian M.R., Almeida M.I.G., Cattrall R.W., Kolev S.D., Selective Extraction of Vanadium(V) from Sulfate Solutions into a Polymer Inclusion Membrane Composed of Poly (Vinylidenefluoride-co-Hexafluoropropylene) and Cyphos® IL 101. J. Membr. Sci., 545: 57-65 (2018).
[34] Marczenko Z., Balcerzak M., “Separation, Preconcentration and Spectrophotometry in Inorganic Analysis”, Elsevier, 159-166 (2000).
[۳5] شعبانی، محسن، بررسی سینتیک جذب رنگدانه اسید آبی 260 روی نانو لوله‌های کربنی چند دیواره با استفاده از برازش خطی و غیرخطی و تعیین انرژی فعال‌سازی، نشریه شیمی و مهندسی شیمی ایران، 39(4): 25 تا 34 (1399).
[36] Dolatyari L., Yaftian M.R., Rostamnia S., Removal of Uranium(VI) Ions from Aqueous Solutions Using Schiff base Functionalized SBA–15 Mesoporous Silica Materials. J. Environ. Manag., 169: 8–17 (2016)
[37] Ghaderi N., Dolatyari L., Kazemi D., Sharafi H.R., Shayani-Jam H., Yaftian M.R., Application of a Polymer Inclusion Membrane Made of Cellulose Triacetate Base Polymer and Trioctylamine for the Selective Extraction of Bismuth(III) from Chloride Solutions. Appl. Polymer Sci., 139: 51480 (2021).
[38] Sena M.M., Scarminio I.S., Collins K.E., Collins C.H., Speciation of Aqueous Chromium(VI) Solutions with the Aid of Q-mode Factor Analysis Followed by Oblique Projection. Talanta, 53: 453–461 (2000)
[39] Onac C., Alpoguz H.K., Akceylan E., Yilmaz M., Facilitated Transport of Cr(VI) Through Polymer Inclusion Membrane System Containing Calix [4] Arene Derivative as Carrier Agent. J. Macromol. Sci. A, 50: 1013-1021 (2013).
[40] Parinejad M., Yaftian M.R., A Study on the Removal of Chromium(VI) Oxanions from Acid Solutions by Using Oxonium Ion-Crown Ether Complexes as Mobile Carrier Agents. Iran. Chem. Chem. Eng. (IJCCE), 26(4): 19-27 (2007).
[41] Bonggotgetsakul Y.N.N., Cattrall R.W., Kolev S.D., Extraction of Gold(III) from Hydrochloric Acid Solutions with a PVC-Based Polymer Inclusion Membrane (PIM) Containing Cyphos® IL 104. Membranes, 5: 903-914 (2015).
[42] Mahanty B., Mohapatra P., Raut D., Das D., Behere P., Afzal M., Polymer Inclusion Membranes Containing N, N, N′, N′-tetra (2-ethylhexyl) Diglycolamide: Uptake Isotherm and Actinide Ion Transport Studies. Ind. Eng. Chem. Res., 54: 3237-3246 (2015).
[43] Gherasim C.V., Bourceanu G., Removal of Chromium(VI) from Aqueous Solutions Using a Polyvinyl-Chloride Inclusion Membrane: Experimental Study and Modelling. Chem. Eng. J., 220: 24-34 (2013).