Nashrieh Shimi va Mohandesi Shimi Iran

Nashrieh Shimi va Mohandesi Shimi Iran

Exploring the Use of Design of Experiments in the Removal of Methylene Blue Dye from Aqueous Solution Using Functionalized Activated Carbon of Rosa Canina-L

Document Type : Research Article

Authors
somaye mashhadi
maryam ghasemi
Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, I.R. IRAN
Abstract
This study aims is to assess the tetraethylenepentamine-functionalized Rosa Canina-L fruits activated carbon prepared by microwave-assisted technique for the removal of Methylene Blue dye from an aqueous solution. The morphological and anatomical characterization of the developed adsorbent was carried out using various analytical techniques such as Fourier Transform Infrared Spectroscopy and Field emission scanning electron microscopy. The surface morphology and physical condition of the absorbent surface show a porous morphology that contains numerous deep holes suitable for dye absorption. Taguchi design of the experiment was used to find the best conditions for the removal of MB dye from the aqueous solution. The effects of different parameters such as pH, adsorbent dose, reaction time, initial dye concentration, and temperature at 3 different levels were considered using an L27 Taguchi method. Analysis of data was performed using one- way variance and calculation of signal-to-noise rate. Based on signal- to- noise ratios, the optimum process conditions were pH 4, adsorbent dose 0.03 g, contact time 30 min, initial MB concentration 25 mg/L and temperature 298 K. According to one- way variance results, the influence of the controllable factors in descending order is pH > adsorbent dose > temperature > initial dye concentration > contact time. Moreover, the adsorption behavior of this adsorbent fits well with the Langmuir isotherm and pseudo-second-order kinetic model. The whole process of adsorption of Methylene Blue dye onto this adsorbent was found to be spontaneous and exothermic under standard conditions.
Keywords
Methylene blue
Removal
Active carbon
Design of Experiments
Rosa canina L

Subjects

[1] Sadegh H., Shahryari-Ghoshekandi R., Agarwal S., Tyagi I., Asif M., Gupta V.K., Microwave-Assisted Removal of Malachite Green by Carboxylate Functionalized Multi-Walled Carbon Nanotubes: Kinetics and Equilibrium Study, J. Mol. Liq., 206: 151-158 (2015).
]2[ قربانی م.، باقریان ع.،  بهینه‌سازی جذب سطحی با روش طراحی آزمایش پاسخ-سطح برای رنگ آسترازون آبی توسط رزین کوپلیمر استایرن- دی وینیل بنزن سولفونه شده، نشریه شیمی و مهندسی شیمی ایران، (1)35: 25 تا 37 (1395).
[3] Al-Amrani W.A., Lim P.E., Seng C. E., Wan Ngah W.S., Bioregeneration of Azo Dyes-Loaded Monoamine Modified Silica in Batch System: Effects of Particle Size and Biomass Acclimation Condition, Chem. Eng. J., 251: 175-182 (2014).
[4] Urgun-Demirtas M., Benda P.L., Gillenwater P.S., Negri M.C., Xiong H., Snyder S.W., Achieving Very Low Mercury Levels in Refinery Wastewater by Membrane Filtration, J. Hazard. Mater., 215-216: 98-107 (2012) 
[5] Khataee A.R., Dehghan G., Optimization of Biological Treatment of a Dye Solution by Macroalgae Cladophora sp. using Response Surface Methodology, J. Taiwan Inst, Chem. Eng., 42: 26-33 (2011)
]6[ نبوی س.ر.، عباسی م.، روحی م.، حذف رنگزای مستقیم آبی 71 (DB71) از محیط آبی در یک راکتور فوتوکاتالیستی بستر ثابت دارای دانه‌های لیکای پوشش داده شده با نانوذره‌هایTiO2-Ce، نشریه شیمی و مهندسی شیمی ایران، (2)39: ٧٥ تا ٨٨ (١٣٩٩).
]7[ انصاری ر.، محمودی ن.، استوار ف.، سنتز و کاربرد نانو رشته‌های منگنز دی اکسید برای حذف رنگزای کاتیونی از آب، نشریه شیمی و مهندسی شیمی ایران، (1)38: 17 تا 28 (1398).
[8] Rafatullah M., Sulaiman O., Hashim R., Ahmad A., Adsorption of Methylene Blue on Low-Cost Adsorbents: A Review, J. Hazard. Mater., 177: 70-80 (2010).
[9] Acar I., Bal A., Güçlü G., Adsorption of Basic Dyes from Aqueous Solutions by Depolymerization Products of Post-Consumer PET Botles, Clean: Soil, Air, Water., 40: 325-333 (2012).
[10] Gundogdu A., Duran C., Senturk H.B., Soylak M., Ozdes D., Serencam H., Imamoglu M., Adsorption of Phenol from Aqueous Solution on a Low-Cost Activated Carbon Produced from Tea Industry Waste: Equilibrium, Kinetic, and Thermodynamic Study, J. Chem. Eng. Data., 57: 2733-2743 (2012).
[11] Ghaedi M., Hajjati S., Mahmudi Z., Tyagi I., Agarwal S., Maity A., Gupta V.K., Modeling of Competitive Ultrasonic Assisted Removal of the Dyes – Methylene Blue and Safranin-O using Fe3O4 Nanoparticles, Chem. Eng. J., 268: 28-37 (2015).
[12] Youcef R., Sabba N., Benhadji A., Djelal H., Fakhfakh N., Taleb Ahmed M., Nanofiltration Treatment of Industrial Wastewater Doped with Organic Dye: A Study of Hydrodynamics and Specific Energy, Proc., 10: 1-17 (2022).
[13] Robati D., Mirza B., Rajabi M., Moradi O., Tyagi I., Agarwal S., Gupta V.K., Removal of Hazardous Dyes-BR 12 and Methyl Orange Using Graphene Oxide as an Adsorbent from Aqueous Phase. Chem. Eng. J., 284: 687-697 (2016).
]14[ محمدی ر.، معصومی ب.، صادقی و.، بررسی میزان جذب سطحی متیل اورانژ با استفاده از نانوکامپوزیت Ag-TiO2/GO، نشریه شیمی و مهندسی شیمی ایران، (1)37: 113 تا 124 (1397).
]15[ قنادزاده گیلانی ح.، معصومی ح.، حقیقی پور ث.، بررسی جذب سطحی فسفریک اسید از محیط آبی توسط جاذب‌های طبیعی، نشریه شیمی و مهندسی شیمی ایران، (1)41: 175 تا 192 (1399).
 [16] Ghaedi M., Reza Rahimi M., Ghaedi A.M., Tyagi I., Agarwal S., Gupta V.K., Application of Least Squares Support Vector Regression and Linear Multiple Regression for Modeling Removal of Methyl Orange onto Tin Oxide Nanoparticles Loaded on Activated Carbon and Activated Carbon Prepared from Pistacia Atlantica Wood, J. Colloid Interface Sci., 461: 425-434 (2016).
[17] Najafi F., Moradi O., Rajabi M., Asif M., Tyagi I., Agarwal S., Gupta V.K., Thermodynamics of the Adsorption of Nickel Ions from Aqueous Phase Using Graphene Oxide and Glycine Functionalized Graphene Oxide, J. Mol. Liq., 208: 106-113 (2015).
]18[ قنادزاده گیلانی ح.، معصومی ح.، یحیی زاده ف.ص.، بررسی جذب نیکل از محیط آبی توسط کربن پوست پرتقال، نشریه شیمی و مهندسی شیمی ایران، (1400) ]آماده انتشار [.
[19] Mashhadi S., Sohrabi R., Javadian H., Ghasemi M., Tyagi I., Agarwal Sh., Gupta V.K., Rapid Removal of Hg (II) from Aqueous Solution by Rice Straw Activated Carbon Prepared by Microwave-assisted H2SO4 Activation: Kinetic, Isotherm and Thermodynamic Studies, J. Mol. Liq., 215: 144-153 (2016)
[20] Ghasemi M.,  Mashhadi S.,  Asif M.,  Tyagi I.,  Agarwal Sh.,  Gupta V.K., Microwave-Assisted Synthesis of Tetraethylenepentamine Functionalized Activated Carbon with High Adsorption Capacity for Malachite Green Dye. J. Mol. Liq., 213: 317-325 (2016).
[21] Wang M., Hao F., Li G., Huang J., Bao N., Huang L., Preparation of Enteromorpha Prolifera-Based Cetyl Trimethyl Ammonium Bromide-Doped Activated Carbon and its Application for Nickel (II) Removal Ecotoxicol, Environ. Saf., 104: 254-262 (2014).
[22] Mahmoodi N.M., Masrouri O., Arabi A.M., Synthesis of Porous Adsorbent Using Microwave Assisted Combustion Method and Dye Removal, J. Alloys. Compd., 602: 210-220 (2014).
[23] Ghasemi M., Khosroshahy M.Z., Abbasabadi A.B., Ghasemi N., Javadian H., Fattahi M., Microwave-assisted Functionalization of Rosa Canina-L Fruits Activated Carbon with Tetraethylenepentamine and its Adsorption Behavior Toward Ni (II) in Aqueous Solution: Kinetic, Equilibrium and Thermodynamic Studies, Powder. Technol., 274: 362-371 (2015).
[24] Ghasemi M., Ghasemi N., Zahedi G., Alwi S.R.W., Goodarzi M., Javadian H., Kinetic and Equilibrium Study of Ni(II) Sorption from Aqueous Solutions onto Peganum Harmala-L. Int. J. Environ. Sci. Technol., 11: 1835-1844 (2014).
[25] Dehghani M.H., Taher M.M., Bajpai A.K., Heibati B., Tyagi I., Asif M., Agarwal S., Gupta V.K., Removal of Noxious Cr (VI) Ions Using Single-Walled Carbon Nanotubes and Multi-Walled Carbon Nanotubes, Chem. Eng. J., 279: 344-352 (2015).
[26] Nekouei F., Nekouei S., Tyagi I., Gupta V.K., Kinetic, Thermodynamic and Isotherm Studies for Acid Blue 129 Removal from Liquids Using Copper Oxide Nanoparticle-Modified Activated Carbon as a Novel Adsorbent, J. Mol. Liq., 201: 124-133 (2015).
]27[ قنادزاده گیلانی ح.، معصومی ح.، یوسفی م.، مطالعه مقایسه حذف فلز روی با استفاده از ریزجلبک اسپیرولینا خام و اصلاح شده با نانو جاذب مغناطیسی، نشریه شیمی و مهندسی شیمی ایران، (2)41: 57 تا 70 (1401).
[28] Sadegh H., Shahryari-Ghoshekandi R., Agarwal S., Tyagi I., Asif M., Gupta V.K., Microwave-Assisted Removal of Malachite Green by Carboxylate Functionalized Multi-Walled Carbon Nanotubes: Kinetics and Equilibrium Study, J. Mol. Liq., 206: 151–158 (2015).
]29[ آقایی ح.، سیف ا.، منجمی م.، برمکی ز.، مطالعه سینتیکی و ترمودینامیکی جذب یون کروم (III) از فاز آبی توسط نانولوله کربنی عامل‌دار شده، نشریه شیمی و مهندسی شیمی ایران، (2)41: 37 تا 55 (1401).
]30[ رحیمی ک.، ریاحی س.، عباسی م.، فخروئیان ز.، عامل‌دار کردن نانولوله‌های کربنی چند دیواره با دی آمین به منظور افزایش جذب کربن دی اکسید، نشریه شیمی و مهندسی شیمی ایران، (2)40: 73 تا 81 (1400).
[31] Gupta V.K., Tyagi I., Agarwal S., Sadegh H., Shahryari-ghoshekandi R., Yari M., Yousefi-nejat O., Experimental Study of Surfaces of Hydrogel Polymers HEMA, HEMA–EEMA–MA, and PVA as Adsorbent for Removal of Azo Dyes from Liquid Phase. J. Mol. Liq., 206: 129-136 (2015).
[32] Ghaedi M., Hajjati S., Mahmudi Z., Tyagi I., Agarwal S., Maity A., Gupta V.K., Modeling of Competitive Ultrasonic Assisted Removal of the Dyes – Methylene Blue and Safranin-O Using Fe3O4 Nanoparticles, Chem. Eng. J., 268: 28-37 (2015).
[33] Asfaram A., Ghaedi M., Agarwal S., Tyagi I., Gupta V.K., Removal of Basic Dye Auramine-O by ZnS:Cu Nanoparticles Loaded on Activated Carbon: Optimization of Parameters Using Response Surface Methodology with Central Composite Design, RSC. Adv., 5(24): 18438-18450 (2015).
[34] Foo K.Y., Hameed B.H., Microwave-Assisted Preparation of Oil Palm Fiber Activated Carbon for Methylene Blue Adsorption, Chem. Eng. J., 166(2): 792-795 (2011).
[35] Gupta V.K., Nayak A., Agarwal S., Tyagi I., Potential of Activated Carbon from Waste Rubber Tire for the Adsorption of Phenolics: Effect of Pre-Treatment Conditions, J. Colloid Interface Sci., 417: 420-430 (2014).
[36] Robati D., Mirza B., Rajabi M., Moradi O., Tyagi I., Agarwal S., Gupta V.K., Removal of Hazardous Dyes-BR 12 and Methyl Orange using Graphene Oxide as an Adsorbent from Aqueous Phase, Chem. Eng. J., 284: 687-697 (2016).
[37] Gupta V.K., Nayak A., Agarwal S., Chaudhary M., Tyagi I., Removal of Ni (II) Ions from Water Using Scrap Tire, J. Mol. Liq., 190: 215-222 (2014).
[38] Agarwal S., Tyagi I., Gupta V.K., Mashhadi S., Ghasemi M., Kinetics and Thermodynamics of Malachite Green Dye Removal from Aqueous Phase using Iron Nanoparticles Loaded on Ash, J. Mol. Liq., 223: 1340-1347 (2016).
[39] Yeşilada E., “Biodiversity in Turkish Folk Medicine, in: B. Sener (Ed.), Biodiversity: Biomolecular Aspects of Biodiversity and Innovative Utilization, Kluwer Academic/ Plenum Publishers”, London, 119–135 (2002).
[40] Ghasemi M., Mashhadi S., Azimi-Amin J., Fe3O4 /AC Nanocomposite as a Novel Nano Adsorbent for Effective Removal of Cationic Dye: Process Optimization based on Taguchi Design Method, Kinetics, Equilibrium and Thermodynamics, J. Wat. Envi. Nanotec., 3(4): 321-336 (2018).
]41[ حسینی س.ق.، کاشی ا.، بذرافشان ا.، بررسی اثر عامل‌های تبلور سرمایشی بر ریخت‌شناسی بلورهای آمونیوم پرکلرات با روش طراحی آزمایش تاگوچی، نشریه شیمی و مهندسی شیمی ایران، (4)37: 223 تا 233 (1397).
[42] Agarwal S., Tyagi I., Gupta V.K., Ghasemi N., Shahivand M., Ghasemi M., Kinetics, Equilibrium Studies and Thermodynamics of Methylene Blue Adsorption on Ephedra Strobilacea Saw Dust and Modified Using Phosphoric Acid and Zinc Chloride, J. Mol. Liq., 218: 208-218 (2016).
]43[ کامرانی فر م.، رضایی ا.، طاهری ا.، منگلی زاده ن.ا.، پورزمانی  ح.ر.، کارایی حذف رنگ نساجی ریکازول بلک بی به وسیله جاذب کیتوزان از محلول‌های آبی، مجله دانشگاه علوم پزشکی رفسنجان، (10)15: ۹۴۲ تا ۹۲۹ (1395).
]44[ ملکوتیان م.، اسدی م.، محوی ا.ح.، حذف رنگ راکتیو بلو 19 از فاضلاب صنایع رنگرزی به وسیله فرآیند الکتروفتون، مجله علوم و تکنولوژی محیط زیست، (1)16: 159 تا 167 (1393).
]45[ موسوی س.پ.، امام جمعه م.م.، بررسی هم دما و سینتیک جذب رنگ راکتیو آبی 19 از محلول‌های آبی توسط نانوتیوب‌های کربنی چند جداره، مجله دانشگاه علوم پزشکی شهرکرد، (1)16: 72 تا 80 (1393).
[46] Manna S., Roy D., Saha P., Gopakumar D., Thomas S., Rapid Methylene Blue Adsorption using Modified Lignocellulosic Materials, Proc. Saf. Enviro. Pro., 107: 346-356 (2017).
[47] Shao H., Li Y., Zheng L., Chen T., Liu J., Removal of Methylene Blue by Chemically Modified Defatted Brown Algae Laminaria Japonica, Jour. Tai. Ins. Chem. Eng., 80: 525-532 (2017).
[48] Mashhadi S., Javadian H., Ghasemi M., Saleh A.T., Gupta S.V.K., Microwave-Induced H2SO4 Activation of Activated Carbon Derived from Rice Agricultural Wastes for Sorption of Methylene Blue from Aqueous Solution, Des. Wat. Treat., 57: 21091-21104 (2016).
[49] Yakout S.M., Hassan M.R., El-Zaidy M.E., Shair O.H., Salih A.M., Kinetic Study of Methyl Orange Adsorption on Activated Carbon Derived from Pine (Pinus Strobus) Sawdust, Bio. Res., 14(2): 4560-4574 (2019).
[50] Ghasemi M., Naushad M., Ghasemi N., Khosravi-fard Y., Adsorption of Pb(II) from Aqueous Solution Using New adsorbents Prepared from Agricultural Waste: Adsorption Isotherm and Kinetic Studies, J. Ind. Eng. Chem., 20: 2193-2199 (2014).
[51] Ghasemi M., Naushad M., Ghasemi N., Khosravi-fard Y., A Novel Agricultural Waste Based Adsorbent for the Removal of Pb(II) from Aqueous Solution: Kinetics, Equilibrium and Thermodynamic Studies, J. Ind. Eng. Chem., 20: 454-461 (2014).
[52] Ghasemi M., Khosroshahy M.Z., Abbasabadi A.B., Ghasemi N., Javadian H., Fattahi M., Microwave-assisted functionalization of Rosa Canina-L fruits activated carbon with tetraethylenepentamine and its adsorption behavior toward Ni(II) in aqueous solution: Kinetic, equilibrium and thermodynamic studies. Pow.r Tec., 274: 362-371 (2015).
[53] Ghaedi M., Kokhdan S.N., Removal of Methylene Blue from Aqueous Solution by Wood Millet Carbon Optimization Using Response Surface Methodology, Spectro. Acta. Pa. A., 136: 141-148 (2015).
[54] Kumar P.S., Ramalingam S., Sathishkumar K., Removal of Methylene Blue Dye from Aqueous Solution by Activated Carbon Prepared from Cashew Nut Shell as a New Low-Cost Adsorbent, Korean J. Chem. Eng., 28: 149-155 (2011).
[55] Dehghani M.H., Dehghan A., Alidadi H., Dolatabadi M., Mehrabpour M., Converti A., Removal of Methylene Blue Dye from Aqueous Solutions by a New Chitosan/Zeolite Composite from shrimp waste: Kinetic and equilibrium study, Korean J. Chem. Eng., 34: 1699-1707 (2017).
[56] Nitayaphat W., Jintakosol T., Engkaseth K., Wanrakakit Y., Removal of Methylene Blue from Aqueous Solution by Coffee Residues. Chiang Mai J. Sci., 42: 407-416 (2015).
[57] Su C.X.H., Teng T.T., Alkarkhi A.F.M., Low L.W., Imperata Cylindrica (Cogongrass) as an Adsorbent for Methylene Blue Dye Removal: Process Optimization, Water. Air. Soil. Poll., 5: 225 (2014).